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Gas-Solid Chromatography: Application, Uniqueness and Versatility

  • Robert L. Grob
Part of the Progress in Analytical Chemistry book series (PAC)

Abstract

Gas Solid Chromatography (GSC) has been applied to the separation of mixtures of hydrogen isotopes, isomers, proteins and viruses. This interest and development has been due to:
  1. 1)

    Control of Homogeneity and specificity of molecular sorbents, i.e., synthesis of absorbents or modification of their surfaces.

     
  2. 2)

    Expansion of temperature range of chromatographic columns (500°C).

     
  3. 3)

    Use of strongly adsorbable carrier gases which can be used at high pressures.

     
  4. 4)

    Control of the nature and degree of porosity of adsorbents.

     
  5. 5)

    Development of non-swelling molecular and macromo-lecular sieves.

     
  6. 6)

    Importance as a tool in physicochemical investigations of solid surfaces, studies of isotherms, determination of heat capacity of adsorption systems and determination of heats and entropies of adsorption.

     

Keywords

Boron Nitride Virial Coefficient Retention Volume Methyl Bromide Displacement Chromatography 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1976

Authors and Affiliations

  • Robert L. Grob
    • 1
  1. 1.Villanova UniversityVillanovaUSA

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