Abstract
The advanced dc-arc spectrochemical source discussed here was developed by William A. Gordon at N.A.S.A., Lewis Research Center, Cleveland, Ohio. It consists of a dc current arc in a static-argon gas chamber. Figure 1 is a photograph of a typical spectrochemical analysis system. This unit is in operation at the University of Colorado Medical Center in Denver, Colorado, under the direction of Michael Hambidge, M.D. It employs a standard Jarrell-Ash 1.5 meter Paschen-Runge mount direct reading spectrometer. The spectrometer offers a reciprocal linear dispersion of 5.5 Å/millimeter along the focal curve yielding a spectral band pass of 0.4 Å for typical exit slit widths. Photomultipliers are arranged behind the exit slits along the focal curve located in the rear of the spectrograph and each of the currents from these photomultiplier tubes is integrated by storing a charge on separate capacitors. After analysis each capacitor is discharged through an electronic measuring circuit and the signal is recorded. This is the same model spectrometer which is employed at N.A.S.A., Lewis Research Center with the static-argon arc at that location. The inert gas chamber itself is located in front of the entrance slit on the optical bar of the spectrometer. Some of the auxiliary equipment necessary to operate the system is visible on the right side of the photograph. A standard spectrochemical dc-arc supply source is located below the arc chamber. A manifold system containing gas flow valves and a pressure gauge is visible. The gas flow system which controls the argon pressure that is backfilled into the arc chamber is also connected to a vacuum pump located on the floor.
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References
Gordon, W.A.: N.A.S.A., T.N. D-2598. Use of temperature buffered argon arc in spectrochemical trace analysis. (1965)
Hambidge, K.M.: Use of static-argon atmosphere in emission spectrochemical determination of chromium in biological materials. Anal. Chem., 43: 103 (1971).
Mellichamp, J.W.: Cored cathodes for stabilization of the dc-arc. Appl. Spectros., 21: 23 (1967).
Gordon, W.A.: N.A.S.A., T.N. D-4236. Stabilization of dc-arcs in static-argon atmospheres for use in spectrochemical analysis (1967).
Stallwood, B.J.: Air cooled electrodes for the spectrochemical analysis of powders. J. Opt. Soc. Am., 44: 171 (1945).
Margoshes, M., Scribner, B.F.: The plasma jet as a spectroscopic source. Spectrochim. Acta., 15: 138 (1959).
Seeley, J., Ph.D.: Thesis, Dept. of Chem., Colorado State University, Fort Collins, Colorado (1973). ( Dr. R. Scogerboe, Director )
Gordon, W.A., Chapman, G.B.: N.A.S.A., T.N. D-6888. Determination of work functions near melting points of refractory metals by using a direct-current arc (1972).
Gordon, W.A.: N.A.S.A., T.N. D-4769. A servocontroller for programming sample vaporization in direct current arc spectrochemical analysis (1968).
Gordon, W.A., Chapman, G.B.: Quantitative direct-current arc analysis of random compositions of microgram residues in silver chloride common matrix. Spectrochim. Acta., 25. 123 (1969).
Franklin, M.L., Gordon, W.A.: N.A.S.A., T.N. D-6313. Use of incandescent lamps to measure optical and detector drifts in photoelectric spectrometers (1971).
Franklin, M.L., Gordon, W.A.: N.A.S.A., T.N. Operational feedback arc controller for atomic spectrochemical studies (in preparation).
Niedermeier, W., Griggs, J.H., Johnson, R.S.: Emission spectrometric determination of trace metals in biological fluids. Appl. Spectros., 25: 53 (1971).
Franklin, M.L., Hambidge, K.M.: Abstracts Rocky Mountain Regional Meeting, Am. Chem. Soc., Colorado State University, Fort Collins, Colorado, June 30, 1972. #2: Application of a photoelectric system for monitoring atomic emission line and spectral background intensities used for multi-element biological trace metal analysis.
Hambidge, K.M., Baum. J.D.: Hair chromium concentrations of human newborn and changes during infancy. Am. J. Clin. Nutr., 25: 376 (1972).
Hambidge, K.M., Franklin, M.L., Jacobs, M.A.: Changes in hair chromium concentrations with increasing distances from hair roots. Am. J. Clin. Nutr., 25: 380 (1972).
Hambidge, K.M., Franklin, M.L., Jacobs, M.A.: Hair chromium concentration: effect of sample washing and external environment. Am. J. Clin. Nutr., 25: 389 (1972).
Hambidge, K.M.: Chromium nutrition in the mother and growing child. In: Newer Trace Elements in Nutrition, edited by W. Mertz and W.E. Cornatzer, N.Y.; Marcel Dekker, 1971, chapter 9.
Hambidge, K.M., Hambidge, C., Jacobs, M.A., Baum, J.D.: Low levels of zinc in hair, anorexia, poor growth and hypogeusia in children. Pediat. Res., 6: 868 (1972).
Present address for M.L. Franklin: Dept. of Chemistry, University of Missouri, Columbia, Missouri 65201.
Supported by Public Health Service Grant 1-RO1-AM-12432 from the National Institute of Arthritis and Metabolic Diseases. Salary paid in part by grant RR-69 from the General Clinical Research Center’s Program of the Division of Research Resources, National Institutes of Health, Bethesda, Maryland.
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© 1973 Plenum Press, New York
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Gordon, W.A., Hambidge, K.M., Franklin, M.L. (1973). Advances in the Static-Argon, Dc-Arc Spectrochemical Source. In: Simmons, I.L., Ewing, G.W. (eds) Applications of the Newer Techniques of Analysis. Progress in Analytical Chemistry, vol 176. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-3318-0_3
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DOI: https://doi.org/10.1007/978-1-4684-3318-0_3
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