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Mixed Oxidation States and Averaged Electronic Environments in Iron Compounds

  • W. M. Reiff

Abstract

A survey of the iron-57 Mossbauer spectroscopy of a variety of mixed valence compounds is presented. The systems discussed are grouped into two broad categories: highly covalent iron-sulfur systems and coordination compounds exhibiting a range of covalency. Correlations of intermediate values of the chemical isomer shift as well as average ironligand bond distance with electron exchange and oxidation state averaging are considered.

Keywords

Isomer Shift Prussian Blue Iron Compound Mixed Valence Mossbauer Spectrum 
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References

  1. 1.
    W. Kundig and R.S. Hargrove, Solid State Commun. 7, 223 (1969).CrossRefGoogle Scholar
  2. 2.
    B.J. Evans and S.S. Hafner, J. Appl. Phys., 40, 1411 (1969).CrossRefGoogle Scholar
  3. 3.
    B.J. Evans, 17th AIP Conference on Magnetism and Magnetic Materials, Paper No. 1C-3, Nov. (1971).Google Scholar
  4. 4.
    R.S. Hargrove and W. Kundig, Solid State Commun. 8, 303 (1970).CrossRefGoogle Scholar
  5. 5.
    M.B. Robin and P. Day, “Advances in Inorganic Chemistry and Radiochemistry”, 10, 294 (1966) Academic Press (New York).Google Scholar
  6. 6.
    N.S. Hush, “Progress in Inorganic Chemistry”, 8, 391 (1967) Interscience (New York).CrossRefGoogle Scholar
  7. 7.
    M. Eckhause, R.J. Harris, Jr., W.B. Shuler, and R.W. Welsh, Proc. Phys. Soc. (London) 89, 187 (1966).CrossRefGoogle Scholar
  8. 8.
    E.J.W. Verwey, Nature, 144, 327 (1939).CrossRefGoogle Scholar
  9. 9.
    E.J.W. Verwey and P.W. Haaijam, Physica 8, 979 (1941).CrossRefGoogle Scholar
  10. 10.
    E.J.W. Verwey, P.W. Haaijman and F.C. Romeijn, J. Chem. Phys. 15, 181 (1947).CrossRefGoogle Scholar
  11. 11.
    N.E. Erickson, “Advances in Chemistry Series”, No. 68, 86 (1967), American Chemical Society, Washington, D.C.Google Scholar
  12. 12.
    E. Pfletschinger, Physik, 209, 119 (1968).CrossRefGoogle Scholar
  13. 13.
    P.R. Edwards and C.E. Johnson, J. Chem. Phys. 47, 2074 (1967).CrossRefGoogle Scholar
  14. 14.
    M.J. Rossiter, J. Phys. Chem. Solids, 26, 775 (1965).CrossRefGoogle Scholar
  15. 15.
    M.J. Rossiter, Phys. Letters, 21, 128 (1966).CrossRefGoogle Scholar
  16. 16.
    K. Ono, A. Ito, E. Hirahara, J. Phys. Soc. Japan, 17, 1615 (1962).CrossRefGoogle Scholar
  17. 17.
    O.C. Kistner and A.W. Sunyar, Phys. Rev. Letters, 4, 412 (1960).CrossRefGoogle Scholar
  18. 18.
    R.J. Armstrong, A.H. Morrish, and G.A. Sawatzky, Phys. Letters, 23, 414 (1966).CrossRefGoogle Scholar
  19. 19.
    C.B. Bargeron, M. Avinor and H.G. Drickamer, Inorganic Chem., 10, 1338 (1971).CrossRefGoogle Scholar
  20. 20.
    M. Eibschutz, E. Hermon and S. Shtrikman, Solid State Commun., 5, 529 (1967).CrossRefGoogle Scholar
  21. 20a.
    R.R. Eley, N.V. Duffy and D.L. Uhrich, J. Inorg. Nucl. Chem., 34, 3681 (1972).CrossRefGoogle Scholar
  22. 21.
    N.N. Greenwood and H.J. Whitfield, J. Chem. Soc., A, 1697 (1968).Google Scholar
  23. 22.
    M. Eibschutz, E. Hermon, S. Shtrikman, J. Phys. Chem. Solids, 28, 1633 (1967).CrossRefGoogle Scholar
  24. 23.
    U. Ganiel, E. Hermon, and S. Shtrikman, J. Phys. Chem. Solids, 33, 1873 (1972).CrossRefGoogle Scholar
  25. 24.
    C.M. Yagnik, and H.B. Mathur, Solid State Comm., 5, 841 (1967).CrossRefGoogle Scholar
  26. 25.
    E. Fluck, W. Kerler and W. Neuwirth, Angew. Chem. Internat. Edn. 2, 277 (1967).CrossRefGoogle Scholar
  27. 26.
    D. Raj and S.P. Puri, J. Chem. Phys., 50, 3184 (1969).CrossRefGoogle Scholar
  28. 27.
    M.J. Buerger, Amer. Minerologist, 32, 415 (1947).Google Scholar
  29. 28.
    M.J. Buerger, J. Amer. Chem. Soc., 67, 2056 (1945).CrossRefGoogle Scholar
  30. 29.
    M.R. Churchill and J. Wormald, Inorg. Chem., 10, 1778 (1971).CrossRefGoogle Scholar
  31. 30.
    L. Pauling and L.D. Brockway, Z. Krist, 82, 188 (1932).Google Scholar
  32. 31.
    J.W. Boon, Rec. Trav. Chim., 63 69 (1944).CrossRefGoogle Scholar
  33. 32.
    J.W. Boon and C.H. Mac. Gillavry, Rec. Trav. Chim., 61, 910 (1942).CrossRefGoogle Scholar
  34. 33.
    B.J. Skinner, R.C. Erd and F.S. Grimaldi, Am. Minerologist, 49, 543 (1964).Google Scholar
  35. 34.
    J.A. Morice, L.V.C. Rees, and D.T. Rickard, J. Inorg. Nucl. Chem., 31, 3797 (1969).CrossRefGoogle Scholar
  36. 35.
    D.J. Vaughan and M.S. Ridout, J. Inorg. Nucl. Chem. 33, 741 (1971).CrossRefGoogle Scholar
  37. 36.
    J.M.D. Coey, M.R. Spender and A.H. Morrish, Solid State Commun., 8, 1605 (1970).CrossRefGoogle Scholar
  38. 37.
    S. Hafner and M. Kalvius, Z. Kristallogr. 123, 443 (1966).CrossRefGoogle Scholar
  39. 38.
    L.M. Levinson and D.J. Treves, J. Phys. Chem. Solids, 29, 2227 (1968).CrossRefGoogle Scholar
  40. 39.
    D.J. Vaughan and M.S. Ridout, Solid State Commun., 8, 2165 (1970).CrossRefGoogle Scholar
  41. 40.
    E.F. Bertaut, C.R. Acad. Sci.(Paris) 234, 1295 (1952).Google Scholar
  42. 41.
    H. Hahn, Z. Anorg. Chem. 264, 184 (1951).CrossRefGoogle Scholar
  43. 42.
    F.K. Lotgering, Philips Res. Report, 11, 337 (1956).Google Scholar
  44. 43.
    G. Haacke and A.J. Nozik, Solid State Commun., 6, 363 (1968).CrossRefGoogle Scholar
  45. 44.
    I.E. Grey, H. Hong and H. Steinfink, Inorg. Chem., 10, 340 (1971).CrossRefGoogle Scholar
  46. 45.
    I.E. Grey and H. Steinfink, Inorg. Chem., 10, 691 (1971).CrossRefGoogle Scholar
  47. 46.
    H. Steinfink, H. Hong, and I.E. Grey, National Bureau of Standards Special Publication 364, Proceedings of 5th Materials Research Symposium, 681 (1972).Google Scholar
  48. 47.
    W.M. Reiff, 164th National A.C.S. Meeting, New York (1972), INOR. #37.Google Scholar
  49. 48.
    W.M. Reiff, I.E. Grey, H. Steinfink, to be published.Google Scholar
  50. 49.
    W. Kerler, W. Neuwirth, E. Fluck, P. Kuhn and B. Zimmerman; Z. Physik, 173, 321 (1963).CrossRefGoogle Scholar
  51. 50.
    J.F. Duncan and P.W.R. Wigley, J. Chem. Soc., 1120 (1963).Google Scholar
  52. 51.
    A. Ito, M. Suenga, and K. Ono., J. Chem. Phys., 48, 3597 (1968).CrossRefGoogle Scholar
  53. 52.
    G.K. Wertheim and A. Rosencwaig, J. Chem. Phys., 54, 3235 (1971).CrossRefGoogle Scholar
  54. 53.
    A.R. Champion and H.G. Drickamer, J. Chem. Phys., 47, 2591 (1967).CrossRefGoogle Scholar
  55. 54.
    D.O. Cowan, R.L. Collins and F. Kaufman, J. Phys. Chem., 75, 2026 (1971).CrossRefGoogle Scholar
  56. 55.
    F. Kaufman and D.O. Cowan, J. Amer. Chem. Soc., 92, 6198 (1970).CrossRefGoogle Scholar
  57. 56.
    R.L. Collins, J. Chem. Phys., 42, 1072 (1965).CrossRefGoogle Scholar
  58. 57.
    D.W. Cowan and C. LeVanda, J. Amer. Chem. Soc., 94, 9271 (1972).CrossRefGoogle Scholar
  59. 58.
    D.O. Cowan, C. LeVanda and R.L. Collins, to be submitted for publication.Google Scholar
  60. 59.
    R. Depape, C.R. Hebd. séanc. Acad. Sci., Paris, 260, 4527 (1965).Google Scholar
  61. 60.
    D.N.E. Buchanan, M. Robbins, H.J. Guggenheim, G.K. Wertheim and V.G. Lambrecht, Jr., Solid State Commun., 9, 583 (1971).CrossRefGoogle Scholar
  62. 61.
    D. Lupu., D. Barb., G. Filoti, M. Morariu and D. Tarina, J. Inorg. Nucl. Chem., 34, 2803 (1972).CrossRefGoogle Scholar
  63. 62.
    C.W. Carter, Jr., J. Kraut, S.T. Freer, R.A. Alden, L.C. Sieker, E. Adman and L.H. Jensen, Proc. Nat. Acad. Sci. USA, 69, 3526 (1972).CrossRefGoogle Scholar
  64. 63.
    T. Herskovitz, B.A. Averill, R.H. Holm, J.A. Ibers, W.D. Phillips and J.F. Weiher, Proc. Nat. Acad. Sci. USA, 69, 2437 (1972).CrossRefGoogle Scholar
  65. 64.
    A. Balch, J. Amer. Chem. Soc., 91, 6962 (1969).CrossRefGoogle Scholar
  66. 65.
    I. Bemal, B.R. Davis, M.L. Good, S. Chandra, J. Coord. Chem., 2, 61 (1972).CrossRefGoogle Scholar
  67. 66.
    M.C.W. Evans, D.O. Hall and C.E. Johnson, Biochem. J., 119, 289 (1970).Google Scholar
  68. 67.
    R. Frankel, W.M. Reiff, I. Bernai and M. Good, to be published.Google Scholar

Copyright information

© New England Nuclear Corporation 1973

Authors and Affiliations

  • W. M. Reiff
    • 1
  1. 1.Department of ChemistryNortheastern UniversityBostonUSA

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