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Some Unusual Oxidation States of Antimony. A Mössbauer Investigation

  • T. Birchall
  • J. G. Ballard
  • B. P. Della Valle
Conference paper

Abstract

Compounds of antimony normally contain the element In either the III or the V oxidation state. Compounds containing these oxidation states give rise to 121Sb Mössbauer spectra yielding parameters which fall within reasonably well defined limits for each oxidation state. It has been clearly demonstrated by Stevens and Bowen at a previous Symposium1 that antimony in the III oxidation state has a chemical Isomer shift at velocities more negative than IpSb, while Sb (V) has a more positive chemical Isomer shift. The shape of the 121Sb resonance can also yield valuable Information about the antimony environment and both parameters taken together can provide an insight into the nature of the bonding in the compound being studied. Some of the earliest demonstrations of the power of the technique have been in proving that Sb204 contains both Sb (111) and Sb(V) rather than Sb (IV), and in showing that “Sb2S5” does not contain Sb (v), but is rather a Sb (III) polysulphide.2–4

Keywords

Isomer Shift Quadrupole Coupling Constant Iron Foil Recoil Free Fraction Unusual Oxidation State 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© New England Nuclear Corporation 1973

Authors and Affiliations

  • T. Birchall
    • 1
  • J. G. Ballard
    • 1
  • B. P. Della Valle
    • 1
  1. 1.Department of ChemistryMcMaster UniversityHamiltonCanada

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