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The Dissolution Kinetics of Lithiated NiO in Aqueous Acid Solutions

  • Chin-Ho Lee
  • Alan Riga
  • Ernest Yeager
Part of the Materials Science Research book series (MSR, volume 9)

Abstract

Transition metal oxides are of major importance in a number of areas of electrochemistry, foremost of which are the corrosion of transition metals and their alloys, various battery systems, and electrochemical catalysis. A study of the mechanism of oxide dissolution and the factors which control the dissolution kinetics should lead to a better understanding of the role of oxides in these various areas of electrochemistry.

Keywords

Dissolution Rate Space Charge Region Anodic Potential Residual Current Dissolution Kinetic 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    J.W. Diggle, “Dissolution of Oxide Phases”, in “Oxide and Oxide Films”, J.W. Diggle, ed., Vol. 2, Chapt. 4, Marcel Dekkar, Inc., New York, 1973, pp. 269–386.Google Scholar
  2. 2.
    H.J. Engell, Z. Physik. Chem. N.F. 7, 158 (1956).CrossRefGoogle Scholar
  3. 3.
    D.A. Vermilyea, J. Electrochem. Soc. 113, 1067 (1966).Google Scholar
  4. 4.
    D. Yohe, E.B. Yeager, R. Greef, and A. Riga, Electrochim. Acta 13, 1351 (1968).CrossRefGoogle Scholar
  5. 5.
    D. Tench and E. Yeager, J. Electrochem. Soc. 120, 164 (1973).CrossRefGoogle Scholar
  6. 6.
    D. Tench and E. Yeager, J. Electrochem. Soc. 121, 318 (1974).CrossRefGoogle Scholar
  7. 7.
    E.B. Sandell, “Colorimetric Determination of Trace Metal”, 3rd Ed., Interscience, New York (1959).Google Scholar
  8. 8.
    M. Pourbaix, “Atlas of Electrochemical Equilibria in Aqueous Solutions”, Pergamon Press, Oxford, 1966 (English translation by J.A. Franklin).Google Scholar
  9. 9.
    C.H. Lee and E. Yeager, “The Dissolution Kinetics of Lithiated Nickel Oxide in Aqueous Solutions”, Tech. Report 5, Office of Naval Research Contract Nonr 1439(05), Case Western Reserve University, Cleveland, Ohio, 1969.Google Scholar
  10. 10.
    A. Riga, R. Greef, and E. Yeager, “The Electrochemical and Dissolution Properties of Nickel Oxide”, Tech. Report 2, , Office of Naval Research Contract Nonr 1439(05), Case Western Reserve University, Cleveland, Ohio, 1966.Google Scholar

Copyright information

© Plenum Press, New York 1975

Authors and Affiliations

  • Chin-Ho Lee
    • 2
    • 1
  • Alan Riga
    • 3
    • 1
  • Ernest Yeager
    • 1
  1. 1.Department of ChemistryCase Western Reserve UniversityClevelandUSA
  2. 2.Presently with Gould, Inc.ClevelandUSA
  3. 3.Presently with Lubrizol a CorporationClevelandUSA

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