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Correlation Factor and Nernst-Einstein Relation in Solid Electrolytes

  • Hiroshi Sato
  • Ryoichi Kikuchi
Part of the Materials Science Research book series (MSR, volume 9)

Abstract

It has been usual to resort to the value of the “correlation factor” when the mechanism of diffusion comes in question. In the area of solid electrolytes, similar efforts have been made in order to estimate the mechanism of ion transport. The main aim of this paper is to shew that this approach is not useful in the case of solid electrolytes. For the sake of simplicity, we limit our discussions here to the vacancy mechanism. However, similar arguments can be applied to any other mechanism as well.

Keywords

Solid Electrolyte Correlation Factor Path Probability Vacancy Mechanism Cooperative Phenomenon 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

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    A.P. LeClaire, Physical Chemistry (W. Jost, ed., Acadanic Press) Vol. 10 (1970).Google Scholar
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  4. 2b.
    R. Kikuchi and H. Sato, J. Chem. Phys. 57, 4962 (1972).CrossRefGoogle Scholar
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    H. Sato and R. Kikuchi, J. Chem. Phys. 55, 677 (1971);CrossRefGoogle Scholar
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    R. Kikuchi and H. Sato, J. Chem. Phys. 55, 702 (1971).CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1975

Authors and Affiliations

  • Hiroshi Sato
    • 1
  • Ryoichi Kikuchi
    • 2
  1. 1.Ford Motor CtompanyDearbornUSA
  2. 2.Highes Research Labs.MalibuUSA

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