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Phase Distribution in Solid-Liquid-Vapor Systems

  • Ilhan A. Aksay
  • Carl E. Hoge
  • Joseph A. Pask
Part of the Materials Science Research book series (MSR, volume 7)

Abstract

Spatial distribution of phases in a solid-liquid-vapor system are described by the classical Young’s equation1
$${\gamma _{sv}} - {\gamma _{s\ell }} = {\gamma _{\ell v}}\cos \theta ,$$
(1)
where γ is the interfacial tension between solid-vapor (sv), solid-liquid (sl), and liquid-vapor (lv) phases, γsvsl is the driving force for wetting, and θ is the contact angle at a solid-liquid-vapor triple point as measured through the liquid phase. Furthermore, in systems where the solid phase is polycrystalline
$${\gamma _{ss}} = 2{\gamma _{sf}}\cos \frac{\Phi }{2},$$
(2)
where γss is the interfacial tension at the solid-solid grain boundary, γsf is either γsl or γsv, and Φ is the dihedral angle2 at a solid-fluid-solid triple point measured through the fluid phase. Both of these equations have been extensively used in various fields to describe the conditions of mechanical equilibrium of a capillary system under chemical non-equilibrium conditions, without explicitly considering the effect of chemical reactions on the interfacial tensions. Recently, it has been shown3 that an interfacial reaction or diffusion of a component from one bulk phase to the other across an interface results in a transient decrease in the corresponding interfacial tension by an amount equal to the free energy of the effective chemical reaction per unit area at that interface.

Keywords

Contact Angle Dihedral Angle Interfacial Tension Interfacial Reaction Liquid Phase Sinter 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1974

Authors and Affiliations

  • Ilhan A. Aksay
    • 1
  • Carl E. Hoge
    • 1
  • Joseph A. Pask
    • 1
  1. 1.Lawrence Berkeley LaboratoryUniversity of CaliforniaBerkeleyUSA

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