Laser Raman Spectroscopy

  • J. A. Koningstein


At present, the low-pressure mercury light source is the most commonly used in Raman spectroscopy. Under normal operating conditions (2.5 kW) it can be calculated that up to 50 W of energy of such a light source is radiated in the 4358 Ǻ line of the mercury spectrum which is frequently used to excite Raman spectra. However, due to the geometry of the mercury light source, only a small fraction of the emitted radiation is utilized in illuminating the sample; in fact, a reasonable estimate is that about 1 W of power in the 4358 Ǻ line is responsible for the excitation of Raman spectra of liquid samples. Even less radiation is available for irradiating solid samples.


Raman Spectrum Raman Spectroscopy Laser Cavity Depolarization Ratio Laser Tube 


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  1. 1.
    A. L. Schawlow and C. H. Townes, Phys. Rev. 112: 1940 (1958).CrossRefGoogle Scholar
  2. 2.
    T. H. Maiman, Nature 107: 493 (1960);CrossRefGoogle Scholar
  3. T. H. Maiman, R. H. Hoskins, I. J. D’Haenens, C. K. Asawa, and V. Evtuhov, Phys. Rev. 123: 1151 (1961);Google Scholar
  4. R. J. Collins, D. F. Nelson, A. L. Schawlow, W. Bond, C. G. B. Garrett, and W. Kaiser, Phys. Rev. Letters 5: 303 (1960).CrossRefGoogle Scholar
  5. 3.
    A. Javan, W. R. Bennett, and D. R. Herriott, Phys. Rev. Letters 6: 106 (1961).CrossRefGoogle Scholar
  6. 4.
    See, for instance, A. J. Bevols and W. A. Barker, Appl. Opt. 4: 531 (1965).CrossRefGoogle Scholar
  7. 5.
    S. P. S. Porto and D. L. Wood, J. Opt. Soc. Am. 52: 251 (1962).CrossRefGoogle Scholar
  8. 6.
    B. P. Stoicheff, Tenth International Spectroscopy Colloquium, University of Maryland, June 1962, Spartan Books, Washington, 1963.Google Scholar
  9. 7.
    H. Kogelnik and S. P. S. Porto, J. Opt. Soc. Am. 53: 1446 (1963).CrossRefGoogle Scholar
  10. 8.
    R. C. C. Leite and S. P. S. Porto, J. Opt. Soc. Am. 54: 9011 (1964).Google Scholar
  11. 9.
    J. A. Koningstein and R. G. Smith, J. Opt. Soc. Am. 54: 1061 (1964).CrossRefGoogle Scholar
  12. 10.
    H. W. Schrötter, Z. Elektrochem. 64: 853 (1960).Google Scholar
  13. 11.
    T. C. Damen, R. C. C. Leite, and S. P. S. Porto, Phys. Rev. Letters 14: 1 (1965).CrossRefGoogle Scholar
  14. 12.
    H. W. Schrötter and H. J. Bernstein, J. Mol. Spectry. 12 (I): 1 (1964).CrossRefGoogle Scholar
  15. 13.
    J. A. Koningstein, Abstracts of Eighth Congress of Molecular Spectroscopy (Copenhagen), 1965.Google Scholar
  16. 14.
    M. V. Hobden and J. P. Russell, Phys. Letters 13: 39 (1964).CrossRefGoogle Scholar
  17. 15.
    J. A. Koningstein and S. Singh (unpublished results).Google Scholar
  18. 16.
    A. Weber and S. P. S. Porto, J. Opt. Soc. Am. (to be published).Google Scholar
  19. 17.
    Y.-H. Pao, R. N. Zittert, and J. E. Griffith, Symposium on Molecular Structure and Spectroscopy, Ohio State University, Columbus, Ohio June 1965.Google Scholar
  20. 18.
    S. O. Rice, in: Nelson Wax (ed.), Noise and Stochastic Processes, Dover Publications, Inc., New York, 1954.Google Scholar
  21. 19.
    R. Homburg Brown and R. Q. Tivios, Proc. Roy. Soc. (London) 242A: 300 (1957).CrossRefGoogle Scholar
  22. 20.
    D. H. Rank, J. Opt. Soc. Am. 37: 789 (1947).CrossRefGoogle Scholar
  23. 21.
    A. E. Douglas and D. H. Rank, J. Opt. Soc. Am. 38: 281 (1948).CrossRefGoogle Scholar
  24. 22.
    R. F. Stamm, C. F. Salzman, and Th. Mariner, J. Opt. Soc. Am. 43: 119 (1953).CrossRefGoogle Scholar
  25. 23.
    J. Cabannes and A. Rousset, Ann. Chim. Phys. 19: 233 (1933).Google Scholar
  26. 24.
    G. Allen and H. J. Bernstein, Can. J. Chem. 32: 1124 (1954).CrossRefGoogle Scholar
  27. 25.
    J. C. Evans and H. J. Bernstein, Can. J. Chem. 34: 1127 (1956).CrossRefGoogle Scholar
  28. 26.
    J. A. Koningstein and H. J. Bernstein, Spectrochim. Acta 18: 1249 (1962).Google Scholar
  29. 27.
    J. T. Edsall and E. B. Wilson, J. Chem. Phys. 6: 124 (1938).CrossRefGoogle Scholar

Copyright information

© Plenum Press 1967

Authors and Affiliations

  • J. A. Koningstein
    • 1
  1. 1.Carleton UniversityOttawaCanada

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