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A Review of the Electrical Properties and Microstructure of Vanadium Phosphate Glasses

  • D. L. Kinser
  • L. K. Wilson

Abstract

Studies of the electrical properties of glasses in the VO2-V2O5-P2O5 system are reviewed. Electron microstructural studies on glasses throughout the system revealed glass-glass immiscibility over a wide area. Correlation of the electrical properties and the corresponding micro structures indicates that the previously observed conductivity maxima in this system is a consequence of the microstructure as well as the electronic behavior of this system. There is evidence for the existence of a second conductivity maxima near the V4+=V5+ composition although glasses in this composition range are difficult to prepare. Of these two maxima one is the result of microstructural segregation while the second is a consequence of the hopping conduction mechanism. It is thus concluded that the anomalous behavior of this system is in fact not anomalous in an electronic sense, but is a consequence of microstructural features of the system.

Keywords

Electron Paramagnetic Resonance Seebeck Coefficient Phosphate Glass Vanadium Oxide Vanadium Phosphate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1974

Authors and Affiliations

  • D. L. Kinser
    • 1
  • L. K. Wilson
    • 1
  1. 1.Vanderbilt UniversityNashvilleUSA

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