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Critical Observations on Measurement of Adsorption at Electrodes

  • H. H. Bauer
  • P. J. Herman
  • P. J. Elving

Abstract

A great deal has been written that is relevant to the title of the present chapter; however, the subject has not by any means been exhaustively treated. The present chapter focuses on the operational aspects— How can adsorption at electrodes be studied and what information can be obtained?—and attempts to discuss these questions critically rather than to review comprehensively all of the detailed relevant work that has been done. Where topics have been well and recently reviewed, duplication has been avoided; as a result, much of the detailed discussion deals with selected matters that have not been satisfactorily treated, e.g., application of the Gibbs adsorption equation and use of capacity measurements at solid electrodes; in the remaining discussion, it is the aim to present information which clarifies the central issues concerning choice of methods that are available, how reliable they are, and how they are alike or differ. Adsorption at semiconductor electrodes and from fused salt media will not be explicitly considered.

Keywords

Surface Tension Adsorption Process Frequency Dispersion Surface Excess Drop Mercury Electrode 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1972

Authors and Affiliations

  • H. H. Bauer
    • 1
  • P. J. Herman
    • 2
  • P. J. Elving
    • 2
  1. 1.University of KentuckyLexingtonUSA
  2. 2.University of MichiganAnn ArborUSA

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