The Quantum Defect Theory Approach
The Quantum Defect Theory (QDT) is a method of using the analytically known properties of excited electrons moving in a pure Coulomb field to describe atomic photoabsorption and electron-ion scattering processes in terms of a few parameters. These parameters may be determined either from experimental data or from ab initio theoretical calculations. In addition, they are usually nearly independent of energy in the threshold energy region (i.e., within a few eV of the atomic ionization threshold). Thus the determination of these parameters at any single energy suffices to predict the variation with energy of numerous atomic properties in the threshold energy region such as total and partial photoionization or scattering cross sections, photoelectron asymmetry parameters, discrete line strengths, autoionization profiles, etc. These properties are often very strongly energy-dependent and difficult to measure or to calculate by other methods. Yet all these phenomena, according to the QDT, depend on only a few essential parameters which represent the proper interface between theory and experiment. The determination of these parameters should thus be the goal of both theory and experiment rather than the calculation or measurement of the various phenomena dependent on these parameters.
KeywordsOscillator Strength Inner Core Excited Electron Quantum Defect Rydberg Series
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