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Electronic Properties of Clean and Chemisorbed Metal Surfaces

  • Thor Rhodin
  • David Adams
Part of the NATO Advanced Study Institutes Series book series (NSSB, volume 16)

Abstract

The theory of chemisorption is based on an understanding of the atomic and electronic structure of clean metal surfaces and the extent to which the basic surface parameters are subsequently modified by adsorption or reaction processes resulting from both adsorbent-adsorbate and adsorbate-adsorbate interactions. Precise formulation of the electronic structure of metal surfaces in the clean state or with adsorbed atoms is complicated by the incomplete understanding of the nature of the metallic bond itself as well as by the lack of detailed experimental information on the electron structure specific to a metal surface and how this structure changes during a chemical transformation. At present major theoretical effort tends to be directed towards the modeling of rather simple molecular interactions on ideal atomically flat surfaces.

Keywords

Electron Spectroscopy Virtual State Electron Energy Level Photoelectron Emission Virtual Level 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1976

Authors and Affiliations

  • Thor Rhodin
    • 1
  • David Adams
    • 2
  1. 1.Cornell UniversityIthacaUSA
  2. 2.Xerox Research LaboratoryWebsterUSA

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