The Study of Electronic Spectra in Crystalline Solid Solutions

  • D. S. McClure
Part of the NATO Advanced Study Institutes Series book series (NSSB, volume 12)


Crystalline solid solutions are useful for obtaining electronic spectra of large molecules because the molecular environment is uniform for all solute molecules, thus forming one condition for obtaining narrow lines. At temperatures of 2°K linewidths under 1 cm−1 are often observed. In addition, single oriented crystals give polarization information. The spectra of pyridine, pyrazine, naphthalene, benzoic acid dimer and stilbene in suitable crystalline matrices are presented and analyzed as examples of this method.


Electronic Spectrum Quartic Term Solution Spectrum Vibronic Coupling Vibrational Assignment 
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Copyright information

© Plenum Press, New York 1976

Authors and Affiliations

  • D. S. McClure
    • 1
  1. 1.Department of ChemistryPrinceton UniversityPrincetonUSA

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