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Luminescence and Spectroscopy of Small Molecular Ions in Crystals

  • K. K. Rebane
  • L. A. Rebane
Part of the NATO Advanced Study Institutes Series book series (NSSB, volume 8)

Abstract

The light molecular ions O 2 - , S 2 - , NO 2 - , PO 2 - and their analogues, inserted into alkali halide crystals as impurities, form luminescence centres of a special molecular type having a number of remarkable properties (a clearly expressed structure of vibronic spectra, rotational-librational motion of the impurity, etc.). In the present paper the following problems are discussed: (1) features of the spectra of the centres formed by small molecular ions; (2) rotation and libration of the impurity ion N 2 - ; (3) luminescence study of the kinetics of the reorientation of the impurity ion S 2 - in the KI crystal.

Keywords

Luminescence Spectrum Excited Electronic State Impurity Molecule Raman Scattering Spectrum Vibronic Spectrum 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1975

Authors and Affiliations

  • K. K. Rebane
    • 1
  • L. A. Rebane
    • 1
  1. 1.Institute of PhysicsAcademy of Sciences of the Estonian SSRTartuUSSR

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