Abstract
The light molecular ions O -2 , S -2 , NO -2 , PO -2 and their analogues, inserted into alkali halide crystals as impurities, form luminescence centres of a special molecular type having a number of remarkable properties (a clearly expressed structure of vibronic spectra, rotational-librational motion of the impurity, etc.). In the present paper the following problems are discussed: (1) features of the spectra of the centres formed by small molecular ions; (2) rotation and libration of the impurity ion N -2 ; (3) luminescence study of the kinetics of the reorientation of the impurity ion S -2 in the KI crystal.
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© 1975 Plenum Press, New York
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Rebane, K.K., Rebane, L.A. (1975). Luminescence and Spectroscopy of Small Molecular Ions in Crystals. In: Di Bartolo, B. (eds) Optical Properties of Ions in Solids. NATO Advanced Study Institutes Series, vol 8. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2787-5_7
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