Abstract
The transfer of optical excitation energy between weakly coupled ions in solids is discussed. The most important coupling mechanisms are treated first from a microscopic point of view, and then statistical averages are taken over the volume of the sample to calculate observable quantities such as the yield of sensitizer luminescence and the time development of the sensitizer luminescence following pulse excitation. Three regimes are considered: negligible sensitizer → sensitizer transfer, transfer between sensitizers comparable in probability with sensitizer → activator transfer, and migration of excitation among sensitizers much more rapid than transfer to activators. The discussion is largely applied to rare earth ions.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
P. Kisliuk, N. C. Chang, P. L. Scott, and M. H. L. Pryce, Phys. Rev. 184, 367 (1969).
G. A. Prinz, Phys. Rev. 152, 474 (1966).
T. Förster, Ann. Physik 2, 55 (1948).
D. L. Dexter, J. Chem. Phys. 21, 836 (1953).
T. Förster in Modem Quantum Chemistry, Part III, ed. by O. Sinanoglu (Academic Press, N. Y., 1965), ch. B. 1.
B. C. Carlson and G. S. Rushbrooke, Proc. Camb. Phil. Soc. 46, 626 (1950).
R. J. Birgeneau, M. T. Hutchings, J. M. Baker, and J. D. Riley, J. Appl. Phys. 40, 1070 (1969).
T. Kushida, J. Phys. Soc. Japan 34, 1318 (1973).
K. Shinagawa, J. Phys. Soc. Japan 23, 1057 (1967).
C. W. Nielson and G. F. Koster, Spectroscopic Coefficients for the p n , d n and f n Configurations (M.I.T. Press, Cambridge, Mass., 1963).
G. H. Dieke, Spectra and Energy levels of Rare Earth Ions in Crystals (Wiley Interscience, N. Y., 1968).
A. J. Freeman and R. E. Watson, Phys. Rev. 127, 2058 (1962).
M. Rotenberg, R. Bivins, N. Metropolis, and J. K. Wooten, Jr., The 3j and 6j Symbols (Technology Press, Cambridge, Mass., 1959).
M. J. Weber, Phys. Rev. 157, 262 (1967).
P. M. Levy, Phys. Rev. 177, 509 (1969).
R. J. Birgeneau, J. Chem. Phys. 50, 4282 (1969).
N. L. Huang, Phys. Rev. B1, 945 (1970).
J. P. van der Ziel, Phys. Rev. B4, 2888 (1971).
R. L. Orbach in Optical Properties of Ions in Crystals, ed. by H. M. Crosswhite and H. W. Moos (Wiley Interscience, N. Y., 1967) p. 445.
T. Miyakawa and D. L. Dexter, Phys. Rev. B1, 2961 (1970).
L. A. Riseberg and H. W. Moos, Phys. Rev. 174, 429 (1968).
N. Yamada, S. Shionoya, and T. Kushida, J. Phys. Soc. Japan 32, 1577 (1972).
T. Förster, Z. Naturforsch. 4A, 321 (1949).
R. E. Kellogg, J. Luminescence 1, 435 (1970).
E. Nakazawa and S. Shionoya, J. Chem. Phys. 47, 3211 (1967).
M. Inokuti and H. Hirayama, J. Chem. Phys. 43, 1978 (1965).
M. Yokota and O. Tanimoto, J. Phys. Soc. Japan 22, 779 (1967).
A. I. Burshtein, Sov. Phys. JETP 35, 882 (1972).
M. Trlifaj, Czech. J. Phys. 8, 510 (1958).
M. J. Weber, Phys. Rev. B4, 2932 (1971).
J. P. van der Ziel, L. Kopf, and L. G. Van Uitert, Phys. Rev. B6, 615 (1972).
R. K. Watts and H. J. Richter, Phys. Rev. B6, 1584 (1972).
N. Krasutsky and H. W. Moos, Phys. Rev. B8, 1010 (1973).
W. B. Gandrud and H. W. Moos, J. Chem. Phys. 49, 2170 (1968).
For an alternate derivation of the rate equation see W. J. C. Grant, Phys. Rev. B4, 648 (1971).
See also F. K. Fong and D. J. Diestler, J. Chem. Phys. 56, 2875 (1972).
G. F. Imbusch, Phys. Rev. 153, 326 (1967).
J. M. Flaherty and B. Di Bartolo, Phys. Rev. B8, 5232 (1973).
T. P. J. Botden and F. A. Kröger, Physica 14, 553 (1948).
F. Williams, Phys. Stat. Sol. 25, 493 (1968).
K. Colbow, Phys. Rev. 139A, 274 (1965).
M. Kleinerman, J. Luminescence 1, 481 (1970).
R. K. Watts and W. C. Holton, J. Appl. Phys. 45, 873 (1974).
V. R. Belan, C. M. Briskina, V. V. Grigoryants, and M. E. Zhabotinskii, Sov. Phys. JETP 30, 627 (1970).
L. A. Riseberg, Phys. Rev. A7, 671 (1973).
S. K. Lyo, Phys. Rev. B3, 3331 (1971).
N. Motegi and S. Shionoya, J. Luminescence 8, 1 (1974).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1975 Plenum Press, New York
About this chapter
Cite this chapter
Watts, R.K. (1975). Energy Transfer Phenomena. In: Di Bartolo, B. (eds) Optical Properties of Ions in Solids. NATO Advanced Study Institutes Series, vol 8. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2787-5_10
Download citation
DOI: https://doi.org/10.1007/978-1-4684-2787-5_10
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-2789-9
Online ISBN: 978-1-4684-2787-5
eBook Packages: Springer Book Archive