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Possible Phase Diagrams for Mixtures of ‘Positive’ and ‘Negative’ Nematic Liquid Crystals

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Abstract

Common nematogenic materials consist of rod-like molecules whose longest axes tend to be parallel in the nematic phase. In addition to such ‘positive’ nematics, it is reasonable to expect that there might be ‘negative’ nematics with planar molecules aligned with their shortest axes parallel.1,2 We have studied a theoretical model which indicates that, if indeed such ‘negative’ nematics exist, then mixing them with suitable ‘positive’ nematics would produce some remarkable effects.3,4 We here describe our most significant findings. The details of our calculation may be found in Refs. 3 and 4.

Work supported under ONR Contract No. NOOO14-67-A-0097-0013.

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References

  1. L. Onsager, Ann, N.Y. Acad. Sci. 51, 627 (1948).

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  2. J.F. Dreyer in Liquid Crystals and Ordered Fluids (Plenum Press, 1970), p. 311.

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  3. R. Alben, Phys. Rev. Letters 30, 778 (1973).

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  4. C.S. Shih and R. Alben, J. Chem. Phys. 57, 3055 (1972); R. Alben (submitted to J. Chem. Phys.).

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  5. M.J. Frieser, Phys. Rev. Letters 24, 1041 (1970).

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  6. A.C. deKock, Z. Phys. Chem. (Leipzig) 48, 129 (1904).

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© 1974 Plenum Press, New York

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Alben, R. (1974). Possible Phase Diagrams for Mixtures of ‘Positive’ and ‘Negative’ Nematic Liquid Crystals. In: Johnson, J.F., Porter, R.S. (eds) Liquid Crystals and Ordered Fluids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2727-1_10

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  • DOI: https://doi.org/10.1007/978-1-4684-2727-1_10

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-2729-5

  • Online ISBN: 978-1-4684-2727-1

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