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Reactions of Atoms and Free Radicals Studied in Discharge-Flow Systems

  • Chapter
Physical Chemistry of Fast Reactions

Abstract

It has been known for many years that certain ground state atoms may be produced by the dissociation of the corresponding molecular gas in a high-voltage electric discharge; such atoms may persist for times up to several seconds at total pressures near 1 torr.1–3 The main emphasis of studies using the modern discharge-flow method is on quantitative measurements of rate constants of elementary reactions of atoms and small free radicals at temperatures from 200 to 800 K and total pressures between 0.1 and 10 torr. In this method, the time dependences of concentrations are determined by measurement at different distances along the axis of a tube, usually cylindrical; atoms are rapidly pumped along the length of this flow tube under steady state conditions. In the case of a velocity of gas flow which is constant with respect to both axial and radial displacement (plug flow), distance along the tube axis and time are in direct proportion, allowing a simple calculation of reaction rates.

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References

  1. Rayleigh (R. J. Strutt), Proc. Roy. Soc., A151, 567 (1935); ibid., Proc. Roy. Soc., A176, 1 (1940)

    Google Scholar 

  2. P. Harteck and U. Kopsch, Z. physik. Chem., B12, 327 (1931)

    CAS  Google Scholar 

  3. M. L. Spealman and W. H. Rodebush, J. Am. Chem. Soc., 57, 1474 (1935)

    CAS  Google Scholar 

  4. F. Kaufman, Proc. Roy. Soc., A247, 123 (1958)

    CAS  Google Scholar 

  5. F. P. Del Greco and F. K. Kaufman, Discussions Faraday Soc., 33, 128 (1962)

    Google Scholar 

  6. N. Cohen and J. Heicklen, Comprehensive Chemical Kinetics, Vol. 2., (Elsevier, 1969 )

    Google Scholar 

  7. a) F. Kaufman, Progr. Reaction Kinetics, 1, 1 (1961);

    CAS  Google Scholar 

  8. b) Ann. Geophysique,20 106 (1964);

    Google Scholar 

  9. c) Ann. Rev. Phys. Chem.,20 45 (1969)

    Google Scholar 

  10. I. M. Campbell and B. A. Thrush, Ann. Rept. Chem. Soc., 67, 17 (1965)

    Google Scholar 

  11. B. Brocklehurst and K. R. Jennings, Progr. Reaction Kinetics, 4, 1 (1967)

    Google Scholar 

  12. B. A. Thrush, Progr. Reaction Kinetics, 3, 65 (1965)

    Google Scholar 

  13. M. F. R. Mulcahy, J. B. Steven, J. C. Ward and D. J. Williams, 12th Symp. Combustion, 323 (1968); J. Phys. Chem., 71, 2124 (1967)

    CAS  Google Scholar 

  14. N. Jonathan and R. Petty, Trans. Faraday Soc., 64, 1240 (1968);

    CAS  Google Scholar 

  15. F. Kaufman and J. R. Kelso, Symp. Chemiluminescence, Duke University (1965)

    Google Scholar 

  16. A. M. Bass and H. P. Broida (Editors), Formation and Trapping of Free Radicals (Academic Press, New York, 1960). T. M. Shaw, J. Chem. Phys., 30, 593, 1366 (1959)

    Google Scholar 

  17. G. M. Schwab, Z. Physik. Chem., B27, 452 (1934)

    Google Scholar 

  18. E. A. Ogryzlo, Can. J. Chem., 39, 2556 (1961)

    CAS  Google Scholar 

  19. M. A. A. Clyne and D. H. Stedman, Trans. Faraday Soc., 64, 2698 (1968)

    CAS  Google Scholar 

  20. R. W. Fair and B. A. Thrush, Trans. Faraday Soc., 65, 1208 (1969)

    CAS  Google Scholar 

  21. A. Carrington and D. H. Levy, J. Chem. Phys., 44, 1298 (1966);

    CAS  Google Scholar 

  22. Ibid., J. Chem. Phys., 47, 3801 (1967);

    Google Scholar 

  23. Ibid., Chem. Commun. 641 (1967);

    Google Scholar 

  24. Ibid., Mol. Phys., 15, 187 (1968); ibid., J. Chem. Phys., 52, 309 (1970)

    Google Scholar 

  25. M. A. A. Clyne and H. W. Cruse, Trans. Faraday Soc., 66, 2214 (1970)

    CAS  Google Scholar 

  26. E. Wrede, Z. Instrumentenk., 48, 201 (1928);

    Google Scholar 

  27. P. Harteck, Z. Physik. Chem., A139, 98 (1928);

    CAS  Google Scholar 

  28. J. C. Greaves and J. W. Linnett, Trans. Faraday Soc., 55, 1338 (1959)

    CAS  Google Scholar 

  29. M. A. A. Clyne and B. A. Thrush, Proc. Roy. Soc., A275, 559 (1963);

    CAS  Google Scholar 

  30. A. A. Westenberg and N. de Haas, J. Chem. Phys., 46, 490 (1967);

    CAS  Google Scholar 

  31. K. Hoyermann, H. G. Wagner and J. Wolfrum, Berichte physik. Chem., 71, 599 (1967)

    CAS  Google Scholar 

  32. F. Kaufman and J. R. Kelso, J. Chem. Phys., 28, 510 (1958)

    CAS  Google Scholar 

  33. Recommended value from D. L. Baulch, D. D. Drysdale and D. G. Home, High Temperature Reaction Rate Data, No. 4, Dec. 1969, University of Leeds

    Google Scholar 

  34. J. E. Morgan and H. I. Schiff, J. Chem. Phys., 38, 1495 (1963)

    CAS  Google Scholar 

  35. G. J. Verbeke and C. A. Winkler, J. Phys. Chem., 64, 319 (1960)

    CAS  Google Scholar 

  36. K. D. Bayes and G. B. Kistiakowsky, J. Chem. Phys., 32, 992 (1960);

    Google Scholar 

  37. I. M. Campbell and B. A. Thrush, Proc. Roy. Soc., A296, 201 (1967)

    CAS  Google Scholar 

  38. M. A. A. Clyne and B. A. Thrush, Proc. Roy. Soc., A269, 404 (1962)

    CAS  Google Scholar 

  39. I. W. M. Smith, Discussions Faraday Soc., 44, 194 (1967); A. A. Westenberg and N. De Haas, J. Chem. Phys., 50, 707 (1969)

    Google Scholar 

  40. L. F. Phillips and H. I. Schiff, J. Chem. Phys., 37, 1233 (1962)

    CAS  Google Scholar 

  41. M. A. A. Clyne and B. A. Thrush, Trans. Faraday Soc., 57, 1305 (1961); ibid., Discussions Faraday Soc., 33, 139 (1962)

    Google Scholar 

  42. M. J. Y. Clement and D. A. Ramsay, Can. J. Phys., 39, 205 (1961)

    CAS  Google Scholar 

  43. A. A. Westenberg and N. de Haas, J. Chem. Phys., 50, 707 (1969);

    CAS  Google Scholar 

  44. J. M. Brown and B. A. Thrush, Trans. Faraday Soc., 63, 630 (1967)

    CAS  Google Scholar 

  45. a) J. V. Michael and R. E. Weston, J. Chem. Phys., 45, 3632 (1966);

    Google Scholar 

  46. J. R. Barker, D. G. Keil, J. V. Michael and D. T. Osborne, J. Chem. Phys., 52, 2079 (1970)

    CAS  Google Scholar 

  47. M. A. A. Clyne and D. H. Stedman, Trans. Faraday Soc., 62, 2164 (1966)

    CAS  Google Scholar 

  48. L. W. Bader and E. A. Ogryzlo, J. Chem. Phys., 41, 2926 (1964)

    CAS  Google Scholar 

  49. E. Hutton and M. Wright, Trans. Faraday Soc., 61, 78 (1965)

    CAS  Google Scholar 

  50. M. A. A. Clyne and D. H. Stedman, Trans. Faraday Soc., 64, 1816 (1968)

    CAS  Google Scholar 

  51. W. G. Burns and F. S. Dainton, Trans. Faraday Soc., 48, 52 (1952)

    CAS  Google Scholar 

  52. M. A. A. Clyne, J. A. Coxon and A. R. Woon-Fat, Disc. Faraday Div., 53, 82 (1972)

    Google Scholar 

  53. K. H. Homann, W. C. Solomon, J. Warnatz, H. G. Wagner and C. Zetzsch, Berichte physik. Chem., 74, 585 (1970)

    CAS  Google Scholar 

  54. Recommended value from D. L. Baulch, D. D. Drysdale and D. G. Home, High Temperature Reaction Rate Data, No. 2, Nov. 1968, University of Leeds

    Google Scholar 

  55. S. Krongelb and M. W. P. Strandberg, J. Chem. Phys., 31, 1196 (1959)

    CAS  Google Scholar 

  56. A. A. Westenberg and N. de Haas, J. Chem. Phys., 40, 3087 (1964)

    CAS  Google Scholar 

  57. A. A. Westenberg and N. de Haas, J. Chem. Phys., 51, 5215 (1969)

    CAS  Google Scholar 

  58. J. P. Wittke and R. H. Dicke, Phys. Rev., 103, 620 (1956)

    CAS  Google Scholar 

  59. A. A. Westenberg and N. de Haas, J. Chem. Phys., 48, 4405 (1968)

    CAS  Google Scholar 

  60. A. A. Westenberg and N. de Haas, J. Chem. Phys., 47, 4241 (1967); ibid., J. Chem. Phys., 50, 2512 (1969)

    Google Scholar 

  61. J. M. Brown and B. A. Thrush, Trans. Faraday Soc., 63, 630 (1967);

    CAS  Google Scholar 

  62. J. M. Brown, P. B. Coates and B. A. Thrush, Chem. Commun., 843 (1966)

    Google Scholar 

  63. A. A. Westenberg and N. de Haas, J. Chem. Phys., 46, 490 (1967)

    CAS  Google Scholar 

  64. E. A. Albers, K. Hoyermann, H. G. Wagner and J. Wolfrum, 12th Symp. Combustion, 313 (1968)

    Google Scholar 

  65. P. B. Davies, B. A. Thrush and A. F. Tuck, Trans. Faraday Soc., 66, 886 (1970)

    CAS  Google Scholar 

  66. A. A. Westenberg and N. de Haas, 12th Symp. Combustion, 289 (1968)

    Google Scholar 

  67. K. Hoyermann, H. G. Wagner and J. Wolfrum, Berichte physik. Chem., 71, 599 (1967)

    CAS  Google Scholar 

  68. J. E. Bennett and D. R. Blackmore, Proc. Roy. Soc., A305, 553 (1968)

    CAS  Google Scholar 

  69. a) A. A. Westenberg, J. Chem. Phys., 43, 1544 (1965);

    CAS  Google Scholar 

  70. A. A. Westenberg and N. de Haas, J. Chem. Phys., 43, 1550 (1965);

    CAS  Google Scholar 

  71. G. Dixon-Lewis, W. E. Wilson and A. A. Westenberg, J. Chem. Phys., 44, 2877 (1966);

    CAS  Google Scholar 

  72. A. A. Westenberg and W. E. Wilson, J. Chem. Phys., 45, 338 (1966)

    CAS  Google Scholar 

  73. A. Carrington, Proc. Roy. Soc., A302, 291 (1968)

    Google Scholar 

  74. J. C. Boden and B. A. Thrush, Proc. Roy. Soc., A305, 107 (1968)

    CAS  Google Scholar 

  75. J. U. White, J. Opt. Soc. Am., 32, 285 (1942)

    Google Scholar 

  76. T. C. Clark and M. A. A. Clyne, Trans. Faraday Soc.,65 2994 (1969);

    Google Scholar 

  77. Ibid., Trans. Faraday Soc., 66, 372 (1970)

    Google Scholar 

  78. M. A. A. Clyne and J. A. Coxon, Proc. Roy. Soc., A303, 207 (1968)

    CAS  Google Scholar 

  79. M. A. A. Clyne, J. A. Coxon and A. R. Woon-Fat, Trans. Faraday Soc., 67, 3351 (1971)

    Google Scholar 

  80. J. R. McNesby and H. Okabe, Advan. Photochem.,3 157 (1964); see also J. A. R. Samson, Techniques of Vacuum Ultraviolet Spectroscopy (Wiley, 1967), chapter 5

    Google Scholar 

  81. D. A. Parkes, L. F. Keyser and F. Kaufman, Astrophys. J., 149, 217 (1967)

    Google Scholar 

  82. W. Braun and T. Carrington, J. Quant. Spectry. Radiative Transfer, 9, 1133 (1969)

    CAS  Google Scholar 

  83. M. A. A. Clyne, J. A. Coxon and D. J. McKenney, to be published

    Google Scholar 

  84. A. A. Passchier, J. D. Christian and N. W. Gregory, J. Phys. Chem., 71, 937 (1967)

    CAS  Google Scholar 

  85. R. G. W. Norrish and B. A. Thrush, Quart. Rev., 10, 149 (1956)

    Google Scholar 

  86. G. Burns and J. K. K. Ip, J. Chem. Phys., 51, 3414 (1969);

    Google Scholar 

  87. J. A. Blake and G. Burns, J. Chem. Phys., 54, 1480 (1971)

    CAS  Google Scholar 

  88. S. N. Foner, Advan. At. Mol. Phys., 2, 385 (1966)

    Google Scholar 

  89. A. C. G. Mitchell and M. W. Zemansky, Resonance Radiation and Excited Atoms (Camb. Univ. Press 1934 )

    Google Scholar 

  90. G. B. Kistiakowsky and G. G. Volpi, J. Chem. Phys., 27, 1114 (1957)

    Google Scholar 

  91. D. S. Jackson and H. I. Schiff, J. Chem. Phys., 21, 2233 (1953)

    CAS  Google Scholar 

  92. S. N. Foner and R. L. Hudson, J. Chem. Phys., 21, 1608 (1953)

    CAS  Google Scholar 

  93. L. F. Phillips and H. I. Schiff, J. Chem. Phys., 37, 1233 (1962)

    CAS  Google Scholar 

  94. F. P. Lossing, chapter in Mass Spectrometry (Editor, McDowell), (McGraw-Hill, 1963 )

    Google Scholar 

  95. See, for example, a review by J. B. Anderson, R. P. Andres and J. B. Fenn, in Advan. At. Mol. Phys., 1, 345 (1965)

    Google Scholar 

  96. S. N. Foner and R. L. Hudson, J. Chem. Phys., 36, 2681 (1962)

    CAS  Google Scholar 

  97. M. Gehring, K. Hoyermann, H. G. Wagner and J. Wolfrum, Berichte physik Chem., 73, 956 (1969)

    CAS  Google Scholar 

  98. S. N. Foner, J. Chem. Phys., 49, 3724 (1968)

    CAS  Google Scholar 

  99. F. C. Fehsenfeld, K. M. Evenson and H. P. Broida, Rev. Sci. Instr., 36, 294 (1965)

    Google Scholar 

  100. J. M. Brown, B. A. Thrush and A. F. Tuck, Proc. Roy. Soc., A302, 311 (1968)

    Google Scholar 

  101. a) F. A. Morse and F. Kaufman, J. Chem. Phys., 42, 1785 (1965);

    Google Scholar 

  102. C-L. Lin and F. Kaufman, J. Chem. Phys., 55, 3760 (1971)

    CAS  Google Scholar 

  103. See, for example, I. M. Campbell and B. A. Thrush, Trans. Faraday Soc., 64, 1275 (1968)

    Google Scholar 

  104. R. P. Wayne, Advan. Photochem., 7, 311 (1969)

    CAS  Google Scholar 

  105. L. W. Bader and E. A. Ogryzlo, Discussions Faraday Soc., 37, 46 (1964);

    Google Scholar 

  106. M. A. A. Clyne, B. A. Thrush and R. P. Wayne, Nature, 199, 1057 (1963)

    CAS  Google Scholar 

  107. F. S. Klein and J. T. Herron, J. Chem. Phys., 41, 1285 (1964)

    CAS  Google Scholar 

  108. J. T. Herron, J. Chem. Phys., 45, 1854 (1966)

    CAS  Google Scholar 

  109. J. T. Herron and R. D. Penzhorn, J. Phys. Chem., 73, 191 (1969)

    CAS  Google Scholar 

  110. L. F. Phillips and H. I. Schiff, J. Chem. Phys., 36, 1509 (1962)

    CAS  Google Scholar 

  111. L. F. Phillips and H. I. Schiff, J. Chem. Phys., 41, 3171 (1965)

    Google Scholar 

  112. C. G. Freeman and L. F. Phillips, J. Phys. Chem., 72, 3025 (1968)

    CAS  Google Scholar 

  113. H. Niki, E. E. Daby and B. Weinstock, 12th Symp. Combustion, 277 (1968);

    Google Scholar 

  114. H. Niki and E. E. Daby, J. Chem. Phys., 51, 1255 (1969)

    Google Scholar 

  115. See, for example, J. W. Linnett and D. G. H. Marsden, Proc. Roy. Soc., A234, 489, 504 (1956)

    Google Scholar 

  116. W. V. Smith, J. Chem. Phys., 11, 110 (1943)

    CAS  Google Scholar 

  117. E. L. Tollefson and D. J. LeRoy, J. Chem. Phys., 16, 1057 (1948)

    CAS  Google Scholar 

  118. a) F. S. Larkin and B. A. Thrush, Discussions Faraday Soc., 37, 112 (1964); (b) F. S. Larkin, Can. J. Chem., 46, 1005 (1968)

    CAS  Google Scholar 

  119. L. Elias, E. A. Ogryzlo and H. I. Schiff, Can. J. Chem., 37, 1680 (1959)

    CAS  Google Scholar 

  120. L. W. Bader and E. A. Ogryzlo, Discussions Faraday Soc., 37, 46 (1964)

    Google Scholar 

  121. D. B. Gibbs and E. A. Ogryzlo, Can. J. Chem., 43, 1905 (1965)

    CAS  Google Scholar 

  122. M. A. A. Clyne and J. A. Coxon, J. Mol. Spectry, 23, 258 (1967)

    CAS  Google Scholar 

  123. R. A. Young and R. L. Sharpless, Discussions Faraday Soc., 33, 228 (1962)

    Google Scholar 

  124. S. Ticktin, G. Spindler and H. I. Schiff, Discussions Faraday Soc., 44, 218 (1967)

    Google Scholar 

  125. M. A. A. Clyne and J. A. Coxon, Proc. Roy. Soc., A298, 424 (1967)

    CAS  Google Scholar 

  126. Y. Tanaka, A. Jursa and F. LeBlanc, The Threshold of Space (Pergamon Press, 1957 ) p. 89

    Google Scholar 

  127. I. M. Campbell and B A. Thrush, Trans. Faraday Soc., 65, 32 (1969)

    CAS  Google Scholar 

  128. S. W. Benson, J. Chem. Phys., 48, 1765 (1968)

    Google Scholar 

  129. H. P. Broida, H. I. Schiff and T. M. Sugden, Trans. Faraday Soc., 57, 259 (1961)

    CAS  Google Scholar 

  130. R. R. Reeves, P. Harteck and W. H. Chace, J. Chem. Phys., 41, 764 (1964);

    CAS  Google Scholar 

  131. D. Applebaum, P. Harteck and R. R. Reeves, Photochem. Photobiol., 4, 1003 (1965)

    CAS  Google Scholar 

  132. A. McKenzie and B. A. Thrush, Chem. Phys. Lett., 1, 681 (1968)

    CAS  Google Scholar 

  133. D. B. Hartley and B. A. Thrush, Proc. Roy. Soc., A297, 520 (1967)

    CAS  Google Scholar 

  134. A. Fontijn, C. B. Meyer and H. I. Schiff, J. Chem. Phys., 40, 64 (1964)

    CAS  Google Scholar 

  135. P. N. Clough and B. A. Thrush, Trans. Faraday Soc., 63, 915 (1967);

    CAS  Google Scholar 

  136. M. A. A. Clyne, B. A. Thrush and R. P. Wayne, Trans. Faraday Soc., 60, 359 (1964)

    CAS  Google Scholar 

  137. C. J. Halstead and B. A. Thrush, Proc. Roy. Soc., A295, 380 (1965);

    Google Scholar 

  138. Ibid., Photochem. Photobiol., 4, 1007 (1965)

    Google Scholar 

  139. J. C. Polanyi, Appl. Opt. Suppl., 2, 109 (1965)

    Google Scholar 

  140. G. C. Pimentel and J. H. Parker, J. Chem. Phys., 51, 10 (1969)

    Google Scholar 

  141. J. C. Polanyi, Discussions Faraday Soc., 44, 293 (1967)

    Google Scholar 

  142. See, for example, K. G. Anlauf, P. J. Kuntz, D. H. Maylotte, P. D. Pacey and J. C. Polanyi, Discussions Faraday Soc., 44, 183 (1967)

    Google Scholar 

  143. P. E. Charters and J. C. Polanyi, Can. J. Chem., 38, 1742 (1960)

    CAS  Google Scholar 

  144. A. M. Bass and D. Garvin, J. Mol. Spectry, 9, 114 (1962)

    CAS  Google Scholar 

  145. D. Garvin, H. P. Broida and H. J. Kostkowski, J. Chem. Phys., 32, 880 (1960)

    CAS  Google Scholar 

  146. P. N. Clough and B. A. Thrush, Trans. Faraday Soc., 65. 23 (1969)

    CAS  Google Scholar 

  147. S. J. Arnold, M. Kubo and E. A. Ogryzlo, Advan. Chem. Ser., 77, 133 (1968)

    Google Scholar 

  148. a) R. E. March, S. G. Furnival and H. I. Schiff, Photochem. Photobiol., 4, 971 (1965);

    Google Scholar 

  149. S. J. Arnold, R. J. Browne, E. A. Ogryzlo and H. Witzke, J. Chem. Phys., 40, 1769 (1964)

    CAS  Google Scholar 

  150. A. M. Falick, B. H. Mahan and R. J. Myers, J. Chem. Phys., 42, 1837 (1965)

    CAS  Google Scholar 

  151. M. Jeunehomme and A. B. F. Duncan, J. Chem. Phys., 41, 1692 (1964)

    CAS  Google Scholar 

  152. B. A. Thrush, J. Chem. Phys., 47, 3691 (1967);

    Google Scholar 

  153. K. L. Wray, J. Chem. Phys., 44, 623 (1966)

    CAS  Google Scholar 

  154. I. D. Clark and R. P. Wayne, Proc. Roy. Soc., A316, 539 (1970)

    CAS  Google Scholar 

  155. S. J. Arnold and E. A. Ogryzlo, Can. J. Phys., 45, 2053 (1967);

    CAS  Google Scholar 

  156. S. H. Whitlow and F. D. Findlay, Can. J. Chem., 45, 2087 (1967)

    CAS  Google Scholar 

  157. R. J. Derwent, D. R. Kearns and B. A. Thrush, Chem. Phys. Lett., 6, 115 (1970);

    CAS  Google Scholar 

  158. M. A. A. Clyne, J. A. Coxon and H. W. Cruse, Chem. Phys. Lett., 6, 57 (1970)

    CAS  Google Scholar 

  159. P. N. Clough and B. A. Thrush, Proc. Roy. Soc., A309, 419 (1969)

    CAS  Google Scholar 

  160. A. M. Bass and K. G. Kessler, J. Opt. Soc. Am., 49, 1223 (1959)

    CAS  Google Scholar 

  161. See, for example, K. Schofield and H. P. Broida, Photochem. Photobiol., 4, 989 (1965)

    Google Scholar 

  162. M. A. A. Clyne and J. A. Coxon, J. Phys., B3, L9 (1970)

    CAS  Google Scholar 

  163. J. F. Prince, C. B. Collins and W. W. Robertson, J. Chem. Phys., 40, 2619 (1964);

    CAS  Google Scholar 

  164. C. B. Collins and W. W. Robertson, J. Chem. Phys., 40, 701 (1964)

    CAS  Google Scholar 

  165. D. W. Setser and D. H. Stedman, J. Chem. Phys., 49, 469 (1968); ibid., Chem. Phys. Lett., 4, 542 (1968);

    Google Scholar 

  166. D. H. Stedman, J. A. Meyer and D. W. Setser, J. Am. Chem. Soc., 90, 6856 (1968);

    CAS  Google Scholar 

  167. M. A. A. Clyne, J. A. Coxon, D. W. Setser and D. H. Stedman, Trans. Faraday Soc., 65, 1177 (1969)

    CAS  Google Scholar 

  168. D. W. Setser, D. H. Stedman and J. A. Coxon, J. Chem. Phys., 53, 1004 (1970)

    CAS  Google Scholar 

  169. See, for example, article by H. Wise and B. J. Wood in Advan. At. Mol. Phys., 3 (1968)

    Google Scholar 

  170. D. W. Setser and D. H. Stedman, J. Chem. Phys., 52, 3957 (1970); D. H. Stedman, J. Chem. Phys., 52, 3966 (1970)

    Google Scholar 

  171. J. A. Meyer, D. W. Setser and D. H. Stedman, J. Phys. Chem., 74, 2238 (1970)

    CAS  Google Scholar 

  172. R. L. Johnson, M. J. Perona and D. W. Setser, J. Chem. Phys., 52, 6372, 6384 (1970)

    Google Scholar 

  173. See, for example, references 7b, 8, 9, 10, 143, 165

    Google Scholar 

  174. M. A. A. Clyne,Ann. Rept. Chem. Soc. A65 165 (1968)

    Google Scholar 

  175. K. M. Evenson and D. S. Burch, J. Chem. Phys., 45, 2450 (1966)

    Google Scholar 

  176. I. M. Campbell and B. A. Thrush,Proc. Roy. Soc. A296 201 (1967); ibid. Trans. Faraday Soc.64 1275 (1968)

    Google Scholar 

  177. M. A. A. Clyne and D. H. Stedman, J. Phys. Chem., 71, 3071 (1967)

    CAS  Google Scholar 

  178. H. S. Johnston, Gas Phase Reaction Rate Theory ( Ronald Press, New York, 1966 )

    Google Scholar 

  179. J. C. Keck, J. Chem. Phys., 29, 410 (1958)

    CAS  Google Scholar 

  180. J. C. Light, J. Chem. Phys., 36, 1016 (1962)

    CAS  Google Scholar 

  181. J. T. Herron, J. L. Franklin, P. Bradt and V. H. Dibeler, J. Chem. Phys., 30, 879 (1959)

    Google Scholar 

  182. C. Mavroyannis and C. A. Winkler, Can. J. Chem., 39, 1601 (1961)

    CAS  Google Scholar 

  183. C. B. Kretschmer and H. L. Petersen, J. Chem. Phys., 39, 1772 (1963)

    CAS  Google Scholar 

  184. L. W. Bader and E. A. Ogryzlo, Nature, 201, 491 (1964)

    CAS  Google Scholar 

  185. R. J. Browne and E. A. Ogryzlo, J. Chem. Phys., 52, 5774 (1970)

    CAS  Google Scholar 

  186. H. B. Dunford, J. Phys. Chem., 67, 258 (1963)

    Google Scholar 

  187. T. C. Marshall, Phys. Fluids, 5, 743 (1962)

    CAS  Google Scholar 

  188. F. Kaufman and J. R. Kelso Discussions Faraday Soc., 37 26 (1964)

    Google Scholar 

  189. M. F. R. Mulcahy and D. J. Williams, Trans. Faraday Soc., 64 59 (1968)

    Google Scholar 

  190. M. A. A. Clyne, D. J. McKenney and B. A. Thrush, Trans. Faraday Soc., 61 2701 (1965)

    Google Scholar 

  191. F. Kaufman and J. R. Kelso, Symp. Chemiluminescence, Durham, North Carolina (1965)

    Google Scholar 

  192. T. C. Clark, M. A. A. Clyne and D. H. Stedman, Trans. Faraday Soc., 62 3354 (1966)

    Google Scholar 

  193. T. C. Clark and M. A. A. Clyne,Chem. Commun., 287 (1966)

    Google Scholar 

  194. C. J. Halstead and B. A. Thrush,Proc. Roy. Soc., A295 363 (1966)

    Google Scholar 

  195. M. A. A. Clyne and J. A. Coxon, Proc. Roy. Soc., A303 207 (1968)

    Google Scholar 

  196. J. A. Kerr, Ann. Rept. Chem. Soc., A64 73 (1967)

    Google Scholar 

  197. K. Schofield, Planetary Space Sci., 15, 643 (1967)

    CAS  Google Scholar 

  198. W. R. Schulz and D. J. Le Roy, J. Chem. Phys.,42, 3879 (1965); ibid., Can. J. Chem., 42, 2480 (1964); B. A. Ridley, W. R. Schulz and D. J. LeRoy, J. Chem. 44 3344 (1966); D. J. LeRoy, B. A. Ridley and K. A. Quickert, Discussions Faraday Soc., 44, 92 (1967)

    Google Scholar 

  199. A. A. Westenberg and N. de Haas, J. Chem. Phys., 47, 1393 (1967)

    CAS  Google Scholar 

  200. R. E. Weston, Jr., J. Chem. Phys., 31, 892 (1959)

    CAS  Google Scholar 

  201. E. L. Wong and A. E. Potter, J. Chem. Phys., 43, 3371 (1965)

    CAS  Google Scholar 

  202. A. A. Westenberg and N. de Haas, J. Chem. Phys., 50, 2512 (1969)

    CAS  Google Scholar 

  203. H. Steiner and E. K. Rideal, Proc. Roy. Soc., A173, 503 (1939); W. H. Rodebush and W. C. Klingelhoefer, J. Am. Chem. Soc. 55, 130 (1933); P. G. Ashmore and J. Chanmugam, Trans. Faraday Soc., 49, 254 (1953)

    Google Scholar 

  204. S. W. Benson, F. R. Cruickshank and R. Shaw, Int. J. Chem. Kinetics, 1, 29 (1969)

    CAS  Google Scholar 

  205. H. I. Schiff, Ann. Geophys., 20, 115 (1964)

    CAS  Google Scholar 

  206. O. R. Lundell, R. D. Ketcheson and H. I. Schiff, 12th Symp. Combustion, 307 (1968)

    Google Scholar 

  207. D. Garvin and H. P. Broida, 9th Symp. Combustion, 678 (1962)

    Google Scholar 

  208. See, for example, B. S. Rabinovitch and D. W. Setser, Advan. Photochem., 3, 1 (1964)

    Google Scholar 

  209. W. Braun and M. Lenzi,Discussions Faraday Soc., 44 252 (1967)

    Google Scholar 

  210. C. J. Halstead and B. A. Thrush, Proc. Roy. Soc., A295 363 (1966)

    Google Scholar 

  211. See reference 7b for recalculated value originally published in reference 5

    Google Scholar 

  212. M. A. A. Clyne and J. A. Coxon, Trans. Faraday Soc., 62 1175 (1966)

    Google Scholar 

  213. H. S. Johnston, E. D. Morris and J. Van den Bogaerde, J. Am. Chem. Soc., 91 7712 (1969)

    Google Scholar 

  214. M. A. A. Clyne and R. F. Walker, to be published

    Google Scholar 

  215. A. P. Modica and D. F. Hornig, J. Chem. Phys., 49, 629 (1968)

    CAS  Google Scholar 

  216. R. E. Walker, Phys. Fluids, 4, 1211 (1961)

    CAS  Google Scholar 

  217. R. V. Poirier and R. W. Carr, J. Phys. Chem., 75, 1593 (1971)

    Google Scholar 

  218. J. E. Breen and G. P. Glass, J. Chem. Phys., 52, 1082 (1970)

    CAS  Google Scholar 

  219. M. F. R. Mulcahy and R. H. Smith, J. Chem. Phys., 54 5212 1971

    Google Scholar 

  220. M. A. A. Clyne and H. W. Cruse, J.C.S. Faraday II, 68 1281 1972

    Google Scholar 

  221. M. A. A. Clyne and H. W. Cruse, J.C.S. Faraday II, 68 1377 1972

    Google Scholar 

  222. E. E. Ferguson, F. C. Fehsenfeld and A. L. Schmeltekopf, Adv. At. Mol. Phys., 5, 1 (1969)

    CAS  Google Scholar 

  223. K. H. Becher, E. H. Fink, W. Groth, W. Jud and D. Kley, Discuss. Faraday Div., 53 (1972)

    Google Scholar 

  224. M. A. A. Clyne, H. W. Cruse and R. T. Watson, J.C.S. Faraday I I, 68, 153 (1972)

    Google Scholar 

  225. M. A. A. Clyne and H. W. Cruse, Trans. Faraday Soc., 67, 2869 (1971)

    CAS  Google Scholar 

  226. P. P. Bemand and M. A. A. Clyne, to be published

    Google Scholar 

  227. D. D. Davis and W. Braun, Appl. Optics, 7, 2071 (1968)

    CAS  Google Scholar 

  228. M. A. A. Clyne and A. R. Woon-Fat, J.C.S. Faraday II, submitted

    Google Scholar 

  229. M. A. A. Clyne and R. T. Watson, to be published

    Google Scholar 

  230. J. R. Kanofsky, D. Lucas, F. Pruss and D. Gutman, 14th Symp. Combustion (1972), in press

    Google Scholar 

  231. I. T. N. Jones and K. D. Bayes, 14th Symp. Combustion (1972), in press

    Google Scholar 

  232. H. Gg. Wagner, C. Zetzsch and J. Warnatz, Ber. phys. Chem., 76, 526 (1972)

    CAS  Google Scholar 

  233. D. O. Ham, D. W. Trainor and F. Kaufman, J. Chem. Phys., 53, 4395 (1970)

    CAS  Google Scholar 

  234. I. M. Campbell and S. B. Neal, Discuss. Faraday Div. 53, 000 (1972)

    CAS  Google Scholar 

  235. I. M. Campbell and S. B. Neal, Discuss. Faraday Div. 53, 000 (1972)

    CAS  Google Scholar 

  236. N. Jonathan, A. Morris, K. J. Ross and D. J. Smith, J. Chem. Phys., 54, 4954 (1971)

    CAS  Google Scholar 

  237. N. Jonathan, A. Morris, K. J. Ross and D. J. Smith, J. Chem. Phys., 54, 4954 (1971)

    CAS  Google Scholar 

  238. M. J. Perona, J. Chem. Phys., 54, 4024 (1971)

    CAS  Google Scholar 

  239. H. W. Chang, D. W. Setser and M. J. Perona, Chem. Phys. Letts., 9, 587 (1971)

    Google Scholar 

  240. D. W. Setser and D. H. Stedman, Prog. Reaction Kinetics, 6, (1971)

    Google Scholar 

  241. J. Troe and H. G. Wagner, this volume, chapter 1

    Google Scholar 

  242. A. A. Westenberg and N. de Haas, J. Phys. Chem., 76, 1586 (1972)

    Google Scholar 

  243. W. C. Richardson, D. W. Setser, D. L. Allbritton and A. L. Schmeltekopf, Chem. Phys. Letts., 12, 349 (1971)

    CAS  Google Scholar 

  244. M. A. A. Clyne and J. Conner, J.C.S. Faraday I I, 68, 1220 (1972)

    Google Scholar 

  245. R. E. Huie, private communication (H + 02 -h M, O + O2 + M); H. Niki and F. Stuhl, J. Chem. Phys., 55, 3943 (1971)

    Google Scholar 

  246. T. Hikida, J. A. Eyre and L. M. Dorfman, J. Chem. Phys. 54 3422 (1971)(H+NO-}-M,H-+02-I-M)

    Google Scholar 

  247. I. Shavitt, J. Chem. Phys., 49, 4048 (1968);

    CAS  Google Scholar 

  248. K. A. Quickert and D. J. Le Roy, J. Chem. Phys., 53, 1325 (1970)

    CAS  Google Scholar 

  249. Since this section was written (July 1970), a somewhat similar interpretation has been advanced by N. S. Snider, J. Chem. Phys., 53, 4116 (1970)

    Google Scholar 

  250. Including the recent value of W. Braun, A. M. Bass and D. D. Davis, Int. J. Chem. Kin., 2, 101 (1970)

    Google Scholar 

  251. Ar 3P2 has been observed using e.p.r. spectrometry, by W. H. Breckenridge and T. A. Miller, Chem. Phys. Letts. 12 437 (1972)

    Google Scholar 

  252. M. A. A. Clyne and H. W. Cruse, to be published

    Google Scholar 

  253. H. G. Wagner, C. Zetzsch and J. Warnatz, Ber. phys. Chem., 76, 526 (1972)

    CAS  Google Scholar 

  254. D. Beck and H. J. Loesch, Ber. phys. Chem., 75, 736 (1971);

    Google Scholar 

  255. Y. T. Lee, J. D. McDonald, P. R. Le Breton and D. R. Herschbach, J. Chem. Phys., 49, 2447 (1968); 51, 455 (1969);

    CAS  Google Scholar 

  256. N. C. Biais and J. B. Cross, J. Chem. Phys., 50, 4108 (1969); 52, 3580 (1970)

    Google Scholar 

  257. M. 1. Christie, R. S. Roy and B. A. Thrush, Trans. Faraday Soc., 55, 1139 (1959); 55, 1149 (1959);

    Google Scholar 

  258. W. G. Burns and F. S. Dainton, Trans. Faraday Soc., 48, 52 (1952)

    CAS  Google Scholar 

  259. M. J. Kurylo, N. C. Peterson and W. Braun, J. Chem. Phys., 53, 2776 (1970)

    CAS  Google Scholar 

  260. a) A. A. Westenberg, private communication; (b) F. Kaufman, private communication; (c) M. A. A. Clyne and S. Down, to be published

    Google Scholar 

  261. However, N. Basco and Dogra, Proc. Roy. Soc. A, 323 401 (1971), using flash photoysis and photographic absorption spectrometry to follow [C1O], found no pressure effect on the rate constant k, in the same range of pressures as ref. 182

    Google Scholar 

  262. M. A. A. Clyne and R. T. Watson, Chem. Phys. Letts., 12, 344 (1971)

    CAS  Google Scholar 

  263. H. Gg. Wagner, C. Zetzsch and J. Warnatz, Angew. Chemie, 10, 564 (1971)

    Google Scholar 

  264. M. F. Golde and B. A. Thrush, Discuss. Faraday Div., 53 (1972)

    Google Scholar 

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  1. Department of Chemistry, Queen Mary College, Mile End Road, London, E.1, UK

    M. A. A. Clyne

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  1. Department of Chemistry, Imperial College of Science and Technology, University of London, London, SW7 2AY, UK

    B. P. Levitt

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Clyne, M.A.A. (1973). Reactions of Atoms and Free Radicals Studied in Discharge-Flow Systems. In: Levitt, B.P. (eds) Physical Chemistry of Fast Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2685-4_4

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  • DOI: https://doi.org/10.1007/978-1-4684-2685-4_4

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