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Unimolecular Dissociation of Small Molecules

  • J. Troe
  • H. Gg. Wagner

Abstract

The dissociation of molecules is one of the basic processes in chemistry; the study of the kinetics of these reactions is therefore of considerable theoretical and practical interest. A simple method of obtaining information about dissociation reactions is to heat the gas to a sufficiently high temperature and then look for thermal decomposition. However for rich mixtures bimolecular reactions may well contribute to the reaction: their influence must be separated out so that the unimolecular dissociation can be isolated. The rate of the primary dissociation is determined by elementary physical processes including both energy transfer between particles and internal energy flow. Dissociation reactions, isomerisation processes, photolytic reactions, dissociation of ions (e.g. in a mass spectrometer) and chemical activation experiments are closely related processes.

Keywords

Isotope Exchange Diatomic Molecule Dissociation Rate Polyatomic Molecule High Pressure Region 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Company Ltd. 1973

Authors and Affiliations

  • J. Troe
    • 1
    • 2
  • H. Gg. Wagner
    • 1
    • 2
  1. 1.Institut de Chimie-Physique de l’Ecole PolytechniqueFédérale de LausanneSwitzerland
  2. 2.Institut für Physikalische ChemieUniversität GöttingenGermany

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