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Inclusion Compounds

  • F. R. Gamble
  • T. H. Geballe

Abstract

The inclusion concept in crystal chemistry arises because there exist a large number of crystal classes in which one can clearly identify a host structure that contains guest atoms, ions, or molecules. In these, geometric and topological effects are of very great importance, and the concept of inclusion is useful not only in determining whether a compound will form but also in predicting properties. The host is a crystal that can provide a tunnel, planar, or cagelike accommodation for a guest species, depending on whether these are found in one-, two-, or three-dimensional arrays. The restricted dimensionality of some of these systems often substantially affects their properties. The presence of the guest, typically over a variable concentration range, has little effect on the structure and lattice constants of the host in at least two dimensions. In layered compounds the third dimension increases to accommodate the guest, which is termed the “intercalate.” In all cases important aspects of the identity of both host and guest are preserved. The strength of the interaction between host and guest varies greatly. In the noble gas clathrates it is weak. At the other extreme it will be so great that the whole concept of guest and host loses intuitive value. Thus, there is no profit in considering TiS in the NiAs structure to be TiS2 in the CdI2 structure with Ti intercalated. There is obviously a high degree of arbitrariness as to what to include in this chapter.

Keywords

Alkali Metal Inclusion Compound Intercalation Compound Tungsten Bronze Guest Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Bell Telephone Laboratories, Incorporated 1976

Authors and Affiliations

  • F. R. Gamble
    • 1
  • T. H. Geballe
    • 2
    • 3
  1. 1.Corporate Research LaboratoryEsso Research and Engineering Co.LindenUSA
  2. 2.Department of Applied PhysicsStanford UniversityStanfordUSA
  3. 3.Bell LaboratoriesMurray HillUSA

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