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Poly(Vinyl Chloride) Matrix Membrane Ion-Selective Electrodes

  • G. J. Moody
  • J. D. R. Thomas
Part of the Modern Analytical Chemistry book series

Abstract

A calcium ion-selective electrode based on a liquid membrane of calcium didecylphosphate sensor dissolved in dioctylphenylphosphonate solvent mediator(1) fulfilled a longstanding need for a reliable monitor of calcium ion activities in medicine and the life sciences. The wide interest in this ion-selective electrode was promoted by the commercial availability of a refined model although its general performance was matched by an electrode(2) with a sensing membrane comprising thenoyltrifluoroacetone sensor plus tributylphosphate plasticizer impregnated in poly(vinyl chloride) (PVC). The PVC matrix membrane was prepared by knife-coating a mixture of PVC with sensor and plasticizer components on a woven fabric and curing the applied coating at 140°C for 30 s.(2–5)

Keywords

Solvent Evaporation Vinyl Chloride Selectivity Coefficient Uranyl Nitrate Matrix Membrane 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1978

Authors and Affiliations

  • G. J. Moody
    • 1
  • J. D. R. Thomas
    • 1
  1. 1.UWISTCardiffWales, UK

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