Skip to main content

Chemiluminescence Techniques in Air Pollutant Monitoring

  • Chapter
Modern Fluorescence Spectroscopy

Part of the book series: Modern Analytical Chemistry ((MOAC,volume 1))

  • 127 Accesses

Abstract

A large number of measurement methods based on gas-phase chemiluminescence have found their way into science and engineering practice. Such methods have recently been summarized in a review by Fontijn, Golomb, and Hodgeson.(1) Air pollutant monitoring represents the newest, most rapidly growing, major area of chemiluminescence application. The introduction in about 1970 of chemiluminescence techniques for selective monitoring of air pollutants, in fact, precipitated a new era in monitoring instrumentation, in which continuous real-time data are obtained; as a result, older wet-chemical methods have largely become obsolete.† The analysis of gases in the gas phase rather than in the liquid phase was a preferred and logical step. Chemiluminescent reactions of several pollutant species were known(1,4–7) and available to be applied. As with the more recently introduced fluorescence techniques, a high sensitivity has become possible in chemiluminescence measurements, owing to advances in electro-optical measurement instrumentation (in particular, the availability of highly sensitive, low-noise photomultiplier tubes).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 74.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. A. Fontijn, D. Golomb, and J. A. Hodgeson, in Chemiluminescence and Bioluminescence, edited by M. J. Cormier, D. M. Hercules, and J. Lee (Plenum Press, New York, 1973), p. 393.

    Google Scholar 

  2. R. K. Stevens and A. E. O’Keeffe, Anal. Chem. 42(2), 143A (1970).

    Article  CAS  Google Scholar 

  3. R. K. Stevens and W. F. Herget, Analytical Methods Applied to Air Pollution Measurements (Ann Arbor Science Publishers, Ann Arbor, Mich., 1974).

    Google Scholar 

  4. Chemiluminescence and Bioluminescence, edited by M. J. Cormier, D. M. Hercules, and J. Lee (Plenum Press, New York, 1973).

    Google Scholar 

  5. T. Carrington and D. Garvin, in Comprehensive Chemical Kinetics, edited by C. H. Bamford and C. F. H. Tipper (Elsevier, New York, 1969), Vol. 3, p. 170.

    Google Scholar 

  6. V. Y. Shlyapintokh, O. N. Karpukhin, L. M. Postnikov, V. F. Tsepalov, A. A. Vichutinskii, and I. V. Zakharov, Chemiluminescence Techniques in Chemical Reactions (Consultants Bureau, New York, 1968).

    Google Scholar 

  7. A. G. Gaydon, The Spectroscopy of Flames (John Wiley, New York, 1957).

    Google Scholar 

  8. J. A. Hodgeson, W. A. McClenny, and P. L. Hanst. Science 182. 248 (1973).

    Article  CAS  Google Scholar 

  9. Analytical Flame Spectroscopy, edited by R. Mavrodineanu (Macmillan, London, 1970).

    Google Scholar 

  10. H. Draeger and B. Draeger, German Patent No. 1,133,918; Chem. Abstr. 57, 14443a (1962).

    Google Scholar 

  11. S. S. Brody and J. E. Chaney, J. Gas Chromatogr. 4, 42 (1966).

    CAS  Google Scholar 

  12. R. W. B. Pearse and A. G. Gaydon, The Identification of Molecular Spectra, 3rd. ed. (Chapman and Hall, London, 1963), p. 266.

    Google Scholar 

  13. R. W. Fair and B. A. Thrush, Trans. Faraday Soc. 65, 1208 (1969).

    Article  CAS  Google Scholar 

  14. J. F. Bott and T. A. Jacobs, J. Chem. Phys. 52, 3545 (1970).

    Article  CAS  Google Scholar 

  15. R. K. Stevens, A. E. O’Keeffe, and G. C. Ortman, Environ. Sci. Technol. 3, 652 (1969).

    Article  CAS  Google Scholar 

  16. J. A. Hodgeson, W. A. McClenny, and R. K. Stevens, in Ref. 3, Chap. 2.

    Google Scholar 

  17. R. K. Stevens, J. D. Mulik, A. E. O’Keeffe, and K. J. Krost, Anal. Chem. 43, 827 (1971).

    Article  CAS  Google Scholar 

  18. K. J. Krost, J. A. Hodgeson, and R. K. Stevens, Anal. Chem. 45, 1800 (1973).

    Article  CAS  Google Scholar 

  19. M. A. A. Clyne and B. A. Thrush, Discuss. Faraday Soc. 33, 139 (1962).

    Article  Google Scholar 

  20. R. S. Braman and E. S. Gordon, IEEE Trans. Instrum. Meas. IM-14, 11 (1965).

    Article  Google Scholar 

  21. M. A. A. Clyne, B. A. Thrush, and R. P. Wayne, Trans. Faraday Soc. 60, 359 (1964).

    Article  CAS  Google Scholar 

  22. P. N. Clough and B. A. Thrush, Trans. Faraday Soc. 63, 915 (1967).

    Article  CAS  Google Scholar 

  23. A. Fontijn, A. J. Sabadell, and R. J. Ronco, in Abstracts of Papers, 158th National Meeting, American Chemical Society, WATR 22 (1969).

    Google Scholar 

  24. A. Fontijn, A. J. Sabadell, and R. J. Ronco, Anal. Chem. 42, 575 (1970).

    Article  CAS  Google Scholar 

  25. A. Fontijn and R. J. Ronco, American Institute of Aeronautics and Astronautics Paper 71–1066 (1971).

    Google Scholar 

  26. H. Niki, A. Warnick, and R. R. Lord, Society of Automotive Engineers Paper 710072 (1971).

    Google Scholar 

  27. D. H. Stedman, E. E. Daby, F. Stuhl, and H. Niki, J. Air. Poll. Control Assoc. 22, 260 (1972).

    Article  CAS  Google Scholar 

  28. B. A. Ridley, H. I. Schiff, A. W. Shaw, L. R. Megill, L. Bates, L. C. Howlett, H. Levaux, and T. E. Ashenfelter, Planet. Space Sci. 22, 19 (1974).

    Article  CAS  Google Scholar 

  29. B. A. Ridley and L. C. Howlett, Rev. Sci. Instrum. 45, 742 (1974).

    Article  CAS  Google Scholar 

  30. M. Loewenstein, J. P. Paddock, I. G. Poppoff, and H. F. Savage, Nature 249, 817 (1974).

    Article  CAS  Google Scholar 

  31. H. I. Schiff and J. C. McConnell, Rev. Geophys. Space Phys. 11, 925 (1973).

    Article  Google Scholar 

  32. D. M. Steffenson and D. H. Stedman, Anal. Chem. 46, 1704 (1974).

    Article  CAS  Google Scholar 

  33. D. J. Patterson and N. A. Henein, Emissions from Combustion Engines and Their Control (Ann Arbor Science Publishers, Ann Arbor, Mich., 1972), Chap. 10.

    Google Scholar 

  34. J. E. Sigsby Jr., F. M. Black, T. A. Bellar, and D. L. Klosterman, Environ. Sci. Technol. 7, 51 (1973).

    Article  CAS  Google Scholar 

  35. M. Birnbaum, this Volume, Chap. 5.

    Google Scholar 

  36. J. A. Hodgeson, K. A. Rehme, B. E. Martin, and R. K. Stevens, Paper No. 72–12, 65th Annual Meeting, Air Pollution Control Association, Miami, Florida. (1972).

    Google Scholar 

  37. L. P. Breiten bach and M. Shelef, J. Air Poll. Control Assoc. 23, 128 (1973).

    Article  Google Scholar 

  38. Thermo Electron Corp., Instruction Sheet, model 300 Molybdenum Converter.

    Google Scholar 

  39. AeroChem Research Laboratories, Inc., “Instruction Manual for Chemiluminescence Monitors. AA Models,” AeroChem TP-286c (October 1974).

    Google Scholar 

  40. Federal Register 39(101), 18075, (May 23, 1974).

    Google Scholar 

  41. D. H. Stedman, University of Michigan (work in progress).

    Google Scholar 

  42. J. A. Hodgeson, R. E. Baumgardner, B. E. Martin, and K. A. Rehme, Anal. Chem. 43, 1123 (1971).

    Article  CAS  Google Scholar 

  43. K. A. Rehme, B. E. Martin, and J. A. Hodgeson, Environmental Protection Agency Report No. RT2–73–246 (March 1974).

    Google Scholar 

  44. J. A. Hodgeson, R. K. Stevens, and B. E. Martin, ISA Trans. 11, 161 (1972).

    CAS  Google Scholar 

  45. J. A. Hodgeson, K. J. Krost, A. E. O’Keeffe, and R. K. Stevens, Anal. Chem. 42, 1795 (1970).

    Article  CAS  Google Scholar 

  46. V. H. Regener, J. Geophys. Res. 65, 3975 (1960);

    Article  Google Scholar 

  47. V. H. Regener, J. Geophys. Res. 69, 3795 (1964).

    Article  CAS  Google Scholar 

  48. A. E. O’Keeffe and G. C. Ortman, Anal. Chem. 38, 760 (1966).

    Article  Google Scholar 

  49. Monitor Labs. Inc., San Diego, Calif., Product Release Brochure, model 8440.

    Google Scholar 

  50. Thermo Electron Corp., Product Release Brochure, model 14D.

    Google Scholar 

  51. G. W. Nederbragt, A. van der Horst, and J. van Duyn, Nature 206, 87 (1965).

    Article  CAS  Google Scholar 

  52. G. J. Warren and G. Babcock, Rev. Sci. Instrum. 41, 280 (1970).

    Article  CAS  Google Scholar 

  53. J. A. Hodgeson, B. E. Martin, and R. E. Baumgardner (unpublished work).

    Google Scholar 

  54. B. J. Finlayson, J. N. Pitts Jr., and R. Atkinson, J. Amer. Chem. Soc. 96, 5356 (1974).

    Article  CAS  Google Scholar 

  55. W. A. McClenny and B. E. Martin, Environmental Protection Agency, Research Triangle Park, N.C. (private communication, September 1974).

    Google Scholar 

  56. A. J. Bemanose and M. G. Rene, Advan. Chem. Ser. 21, 7 (1959).

    Article  Google Scholar 

  57. J. B. Tommerdahl, Research Triangle Institute, Research Triangle Park, N.C., National Air Pollution Control Administration, USDHEW-PHS, Final Report, Part I, Contract No. CPA-22–69–7 (1969).

    Google Scholar 

  58. R. Guicherit, Z. Anal. Chem. 256, 177 (1971).

    Article  CAS  Google Scholar 

  59. S. van Heusden, Chem. Weekbl. 70(27), 15 (1974).

    Google Scholar 

  60. A. M. Winer, J. W. Peters, J. P. Smith, and J. N. Pitts, Environ. Sci. Technol. 8, 1118 (1974).

    Article  CAS  Google Scholar 

  61. A. Fontijn, C. B. Meyer, and H. I. Schiff, J. Chem. Phys. 40, 64 (1964).

    Article  CAS  Google Scholar 

  62. M. F. Golde, A. E. Roche, and F. Kaufman, J. Chem. Phys. 59, 3953 (1973).

    Article  CAS  Google Scholar 

  63. F. Kaufman, Progr. React. Kinet. 1, 1 (1961).

    CAS  Google Scholar 

  64. A. D. Snyder and G. W. Wooten, Monsanto Research Corp., NTIS PB 188 103 (1969).

    Google Scholar 

  65. F. M. Black and J. E. Sigsby Jr., Environ. Sci. Technol. 8, 149 (1974).

    Article  CAS  Google Scholar 

  66. W. E. Jones, S. D. McKnight, and L. Teng, Chem. Rev. 73, 407 (1973).

    Article  CAS  Google Scholar 

  67. W. A. McClenny, J. A. Hodgeson, and J. P. Bell, Anal. Chem. 45, 1514 (1973).

    Article  CAS  Google Scholar 

  68. R. K. Gould and H. N. Volltrauer, AeroChem Research Laboratories, Inc., Princeton, N.J., Final Report, Environmental Protection Agency Contract 68–02–1218 (1974).

    Google Scholar 

  69. J. A. Hodgeson and W. A. McClenny, Abstracts of Papers, 164th National Meeting, American Chemical Society, WATR 61 (1972).

    Google Scholar 

  70. R. Guicherit, Atmos. Environ. 6, 807 (1972).

    Article  CAS  Google Scholar 

  71. H. Niki, E. E. Daby and B. Weinstock, Advan. Chem. Ser. 113, 16 (1972).

    Article  CAS  Google Scholar 

  72. P. A. Leighton, Photochemistry of Air Pollution (Academic Press, New York, 1961).

    Google Scholar 

  73. S. G. Coloff, M. Cooke, R. J. Drago, and S. F. Sleva, Amer. Lab. 5(7), 10 (1973).

    CAS  Google Scholar 

  74. “Proceedings of the Solvent Reactivity Conference,” Environmental Protection Agency Report 650/3–74–010, 5 November 1974.

    Google Scholar 

  75. B. Krieger, M. Malki, and R. Kummler, Environ. Sci. Technol. 6, 742 (1972).

    Article  CAS  Google Scholar 

  76. A. Fontijn and R. Ellison, Environ. Sci. Technol. 9, 1157 (1975).

    Article  CAS  Google Scholar 

  77. B. Dimitriades, Ref. 73, p. 13.

    Google Scholar 

  78. M. F. R. Mulcahy and O. J. Williams, Chem. Phys. Lett. 7, 455 (1970).

    Article  CAS  Google Scholar 

  79. A. Sharma, J. P. Padur, and P. Warneck, J. Chem. Phys. 43, 2155 (1965);

    Article  CAS  Google Scholar 

  80. A. Sharma, J. P. Padur, and P. Warneck, J. Phys. Chem. 71 1602 (1967).

    Article  CAS  Google Scholar 

  81. W. A. Kummer, J. N. Pitts Jr., and R. P. Steer, Environ. Sci. Technol. 5, 1045 (1971).

    Article  Google Scholar 

  82. J. N. Pitts Jr., H. Fuhr, J. S. Gaffney, and J. W. Peters, Env. Sci. Technol. 7, 550 (1973

    Article  CAS  Google Scholar 

  83. M. A. A. Clyne and B. A. Thrush, Discuss. Faraday Soc. 33, 139 (1962).

    Article  Google Scholar 

  84. J. Heicklen and N. Cohen, Advan. Photochem. 5, 157 (1968).

    Article  CAS  Google Scholar 

  85. T. G. Slanger, B. J. Wood, and G. Black, Int. J. Chem. Kinet. 5, 615 (1973).

    Article  CAS  Google Scholar 

  86. D. D. Davis, J. T. Herron, and R. E. Huie, J. Chem. Phys. 58, 530 (1973).

    Article  CAS  Google Scholar 

  87. K. Schofield, Planet. Space Sci. 15, 643 (1967).

    Article  CAS  Google Scholar 

  88. L. F. Phillips and H. I. Schiff, J. Chem. Phys. 37, 1233 (1962).

    Article  CAS  Google Scholar 

  89. M. A. A. Clyne and B. A. Thrush, Trans. Faraday Soc. 57, 1305 (1961).

    Article  CAS  Google Scholar 

  90. T. G. Slanger and G. Black, J. Chem. Phys. 53, 3717 (1970).

    Article  CAS  Google Scholar 

  91. R. E. Huie, J. T. Herron, and D. D. Davis, J. Phys. Chem. 76, 2653 (1972).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1976 Plenum Press, New York

About this chapter

Cite this chapter

Fontijn, A. (1976). Chemiluminescence Techniques in Air Pollutant Monitoring. In: Wehry, E.L. (eds) Modern Fluorescence Spectroscopy. Modern Analytical Chemistry, vol 1. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2583-3_6

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-2583-3_6

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-2585-7

  • Online ISBN: 978-1-4684-2583-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics