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Proton Transfer in Solution

  • John O’M. Bockris
  • Shahed U. M. Khan

Abstract

The theory of the mobility of protons has been discussed for many years, because protons have an abnormal mobility, being under a unit electric field some six times faster in their motion than other ions of the same size as a H3O+ ion. This effect has been discussed non-quantum-mechanic-ally, but since 1933 it has been discussed in a quantum mechanical way. Ideas and calculations of Bernai and Fowler1 and Conway, Bockris, and Linton,2 and the development of these ideas by Eigen and de Maeyer3 are well known.

Keywords

Proton Transfer Potential Energy Curve Proton Transfer Reaction Proton Mobility Mobility Ratio 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    J. D. Bernai and R. H. Fowler, J. Chem. Phys. 1, 515 (1933).CrossRefGoogle Scholar
  2. 2.
    B. E. Conway, J. O’M. Bockris, and H. Linton, J. Chem. Phys. 24, 834 (1956).CrossRefGoogle Scholar
  3. 3.
    M. Eigen and L. de Maeyer, Proc. Roy. Soc. (London) A247, 505 (1958); The Structure of Electrolytic Solutions (J. Hamer, ed.), Chapter 5, John Wiley and Sons, New York (1959); cf. Symposium on Hydrogen Bonding, Ljubjana, July 29-August 3, 1957 (Hadzi Dusan, ed., with the cooperation of H. W. Thomson), Pergamon Press, Oxford (1959).Google Scholar
  4. 4.
    E. Caldin and V. Gold (eds.), Proton-Transfer Reactions, Chapman and Hill, London (1975).Google Scholar
  5. 5.
    R. W. Gurney, Proc. Roy. Soc. (London) A134, 137 (1931).Google Scholar
  6. 6.
    G. N. Lewis and F. G. Doody, J. Electrochem. Soc. 55, 3504 (1933).Google Scholar
  7. 7.
    J. O’M. Bockris, Quart. Rev. Chem. Soc. London, 111, 173 (1949).CrossRefGoogle Scholar
  8. 8.
    N. Bjerrum, Science 115, 385 (1952); cf. K. Danske Vidensk. Selsk., 27, No. 1 (1951).CrossRefGoogle Scholar
  9. 9.
    B. E. Conway and J. O’M Bockris, J. Chem. Phys. 28, 354 (1958).CrossRefGoogle Scholar
  10. 10.
    B. E. Conway, Can. J. Chem. 37, 178 (1959); Symposium on Charge Transfer Processes, Preprint No. 7, Chemical Institute of Canada, Ottawa (1958).CrossRefGoogle Scholar
  11. 11.
    R. P. Bell, J. A. Fendley, and J. R. Hulett, Proc. Roy. Soc. (London) A235, 453 (1956).Google Scholar
  12. 12.
    M. L. Huggins, J. Phys. Chem. 40, 723 (1936).CrossRefGoogle Scholar
  13. 13.
    B. E. Conway, Can. J. Chem. 37, 613 (1959).CrossRefGoogle Scholar
  14. 14.
    E. Erdey-Gruz and P. Lengyal, Modem Aspects of Electrochemistry (B. E. Conway and J. O’M. Bockris, eds.), Volume 12, Plenum Press, New York (1977).Google Scholar
  15. 15.
    E. G. Weidermann and G. Zundel, Z. Naturforsch 25a, 627 (1970).Google Scholar
  16. 17.
    J. Brickmann and H. Zimmermann, Z. Naturforsch 23a, 11 (1968).Google Scholar
  17. 18.
    P. O. Löwdin, Advances in Quantum Chemistry, Volume 3, p. 216, Academic Press, New York (1965).Google Scholar
  18. 19.
    M. C. Flanigan and J. R. De la Vega, Chem. Phys. Lett. 21, 521 (1973).CrossRefGoogle Scholar
  19. 20.
    J. D. Swalen and J. A. Ibers, J. Chem. Phys. 36, 1914 (1962).CrossRefGoogle Scholar
  20. 21.
    R. G. Carbonell and M. D. Kostin, J. Chem. Phys. 60, 2047 (1974).CrossRefGoogle Scholar
  21. 22.
    E. A. Pshenichnov and N. D. Sokolov, Int. J. Quant. Chem. 1, 855 (1967).Google Scholar
  22. 23.
    R. L. Somarjai and D. F. Hornig, J. Chem. Phys. 36, 1980 (1962).CrossRefGoogle Scholar
  23. 24.
    A. J. Kresge, Proton Transfer Reaction (E. Caldin and V. Gold, eds.), Chapter 7, Chapman and Hill, London (1975).Google Scholar
  24. 25.
    G. W. Koeppl and A. J. Kresge, J. Chem. Soc, Chem. Commun., p. 371 (1973).Google Scholar
  25. 26.
    M. M. Kreevoy and S. W. Oh, J. Amer. Chem. Soc. 95, 4805 (1973).CrossRefGoogle Scholar
  26. 27.
    L. Böttcher, Theory of Electric Polarization, p. 181, Elsevier, New York (1952).Google Scholar
  27. 28.
    B. Levich, Theory of electrode processes, in Treatise on Physical Chemistry (H. Eyring, L. Henderson, and M. Justi, eds.), Volume 9, Academic Press, New York (1970).Google Scholar
  28. 29.
    P. George and J. Griffith, in The Enzymes, 1959 (P. D. Boyer, H. Lardy and K. Myrberg, eds.), Volume 1, Chapter 8, p. 347, Academic Press, New York (1959).Google Scholar
  29. 30.
    A. Despic and J. O’M. Bockris, J. Chem. Phys. 32, 389 (1960).CrossRefGoogle Scholar
  30. 31.
    J. O’M. Bockris, S. U. M. Khan, and D. B. Matthews, J. Res. Inst. Catal. Hokkaido Univ. 22, 1 (1974).Google Scholar

Copyright information

© Plenum Press, New York 1979

Authors and Affiliations

  • John O’M. Bockris
    • 1
  • Shahed U. M. Khan
    • 2
  1. 1.Texas A & M UniversityCollege StationUSA
  2. 2.University of BonnBonnWest Germany

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