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Electric Double Layers at Metals

  • John O’M. Bockris
  • Shahed U. M. Khan

Abstract

Gouy1 and Chapman2 gave equations for the excess net charge in a solution per unit area of an electrode as a function of the metal-solution potential difference, assuming only electrical interaction with the electrode, and for point ions. The corresponding equation that arises for the diffuse-layer capacitance is
$$C_{{\text{2 - b}}} = \left( {\frac{{z^2 e_0^2 n\varepsilon }} {{2\pi kT}}} \right)^{1/2} \cosh \frac{{ze_0 \varphi _{2 - b} }} {{2kT}}$$
(1.1)
φ2−b is the potential of the layer of ions in the outer Helmholtz plane (OHP) with respect to that of the solution, in which the concentration is n ions/cm3.

Keywords

Double Layer Diffuse Layer Electric Double Layer Zero Charge Electrode Charge 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1979

Authors and Affiliations

  • John O’M. Bockris
    • 1
  • Shahed U. M. Khan
    • 2
  1. 1.Texas A & M UniversityCollege StationUSA
  2. 2.University of BonnBonnWest Germany

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