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Electric Double Layers at Metals

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Quantum Electrochemistry

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Abstract

Gouy1 and Chapman2 gave equations for the excess net charge in a solution per unit area of an electrode as a function of the metal-solution potential difference, assuming only electrical interaction with the electrode, and for point ions. The corresponding equation that arises for the diffuse-layer capacitance is

$$C_{{\text{2 - b}}} = \left( {\frac{{z^2 e_0^2 n\varepsilon }} {{2\pi kT}}} \right)^{1/2} \cosh \frac{{ze_0 \varphi _{2 - b} }} {{2kT}}$$
(1.1)

φ2−b is the potential of the layer of ions in the outer Helmholtz plane (OHP) with respect to that of the solution, in which the concentration is n ions/cm3.

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References

  1. G. Gouy, J. Phys. 9, 457 (1910).

    CAS  Google Scholar 

  2. D. L. Chapman, Phil. Mag. 25, 475 (1913).

    Google Scholar 

  3. R. Parsons and S. Trasatti, Trans. Faraday Soc. 65, 3314 (1969).

    Article  CAS  Google Scholar 

  4. F. H. Stillinger and J. G. Kirkwood, J. Chem. Phys. 33, 1282 (1960).

    Article  CAS  Google Scholar 

  5. V. G. Levich, V. A. Kir’yanov, and V. S. Krylov, Dokl. Akad. Nauk. SSSR 135, 1425 (1960)

    CAS  Google Scholar 

  6. V. S. Krylov, Electrochim. Acta 9, 1247 (1964).

    Article  CAS  Google Scholar 

  7. F. P. Buff and F. H. Stillinger, J. Chem. Phys. 39, 1911 (1963).

    Article  CAS  Google Scholar 

  8. I. L. Cooper and J. A. Harrison, Electrochim. Acta 22, 519 (1977).

    Article  CAS  Google Scholar 

  9. O. Stern, Z Elektrochem. 30, 508 (1924).

    CAS  Google Scholar 

  10. D. C. Grahame, Chem. Rev. 41, 441 (1947).

    Article  CAS  Google Scholar 

  11. P. Holmquist, J. Electroanal. Chem. 78, 341 (1977).

    Article  Google Scholar 

  12. M. A. V. Devanathan, Trans. Faraday Soc. 50, 373 (1954).

    Article  CAS  Google Scholar 

  13. E. Lange and L. Miscenko, Z. Phys. Chem. 149, 1 (1930).

    CAS  Google Scholar 

  14. J. O’M. Bockris and E. C. Potter, J. Chem. Phys. 20, 614 (1952).

    Article  CAS  Google Scholar 

  15. J. R. Macdonald, J. Chem. Phys. 22, 1857 (1954).

    Article  CAS  Google Scholar 

  16. J. R. Macdonald and C. A. Barlow, J. Chem. Phys. 36, 3062 (1962).

    Article  CAS  Google Scholar 

  17. N. F. Mott and R. J. Watts-Tobin, Electrochim. Acta 4, 79 (1961).

    Article  CAS  Google Scholar 

  18. J. O’M. Bockris, M. A. V. Devanathan, and K. Muller, Proc. Roy. Soc. A274, 55 (1963).

    Google Scholar 

  19. T. Erdey-Gruz, Kinetics of Electrode Processes, Hilger, London (1973).

    Google Scholar 

  20. G. J. Hills, J. Phys. Chem. 73, 3591 (1969).

    Article  CAS  Google Scholar 

  21. R. Reeves, Modem Aspects of Electrochemistry, Volume 9 (B. E. Conway and J. O’M. Bockris, eds.), Plenum Press, New York (1973).

    Google Scholar 

  22. J. O’M. Bockris and M. A. Habib, Acta Electrochim. 22, 41 (1977).

    Article  CAS  Google Scholar 

  23. J. Gibbs, The Collected Works, Longmans, Green, New York (1928).

    Google Scholar 

  24. F. Koenig, J. Phys. Chem. 38, 339 (1934).

    Article  CAS  Google Scholar 

  25. R. Parsons and M. A. V. Devanathan, Trans. Faraday Soc. 49, 404 (1963).

    Article  Google Scholar 

  26. R. Parsons and F. G. R. Zobel, J. Electroanal. Chem. 9, 2978 (1965).

    Google Scholar 

  27. Z. Kovac, Ph.D. Thesis, University of Pennsylvania, Philadelphia (1964).

    Google Scholar 

  28. J. O’M. Bockris, K. Muller, H. Wroblowa, and Z. Kovac, J. Electroanal. Chem. 10, 416 (1965).

    CAS  Google Scholar 

  29. R. Payne, J. Electroanalyt. Chem. 15, 95 (1967).

    Article  CAS  Google Scholar 

  30. J. O’M. Bockris, H. Wroblowa, K. Muller, and Z. Kovac, J. Electroanal. Chem. 15, 101 (1967).

    Article  CAS  Google Scholar 

  31. L. G. M. Gordon, J. Halpern, and B. E. Conway, J. Electroanal. Chem. 21, 3 (1969).

    Article  Google Scholar 

  32. T. R. Beck, J. Phys. Chem. 73, 466 (1969).

    Article  CAS  Google Scholar 

  33. R. Fredlein, A. Damjanovic, and J. O’M. Bockris, Surface Science 25, 261 (1971).

    Article  CAS  Google Scholar 

  34. F. Schubert, Acta Electrochim. 16, 42 (1971).

    Google Scholar 

  35. R. Armstrong, W. P. Race, and H. R. Thirsk, Acta Electrochimica 13, 215 (1968).

    Article  CAS  Google Scholar 

  36. J. O’M. Bockris, E. Gileadi, and K. Muller, J. Chem. Phys. 44, 1445 (1966).

    Article  CAS  Google Scholar 

  37. J. O’M. Bockris, E. Gileadi, and K. Muller, J. Chem. Phys. 47, 250 (1967).

    Article  Google Scholar 

  38. R. de Levie, Advances in Electrochemistry, Volume 6 (P. Delahay and C. W. Tobias, eds.), p. 281, Interscience, New York (1967).

    Google Scholar 

  39. K. J. Vetter, Electrochemical Kinetics, Academic Press, New York (1967).

    Google Scholar 

  40. J. O’M. Bockris and H. Kita, J. Electrochem. Soc. 4, 108 (1961).

    Google Scholar 

  41. B. E. Conway and E. Gileadi, Modem Aspects of Electrochemistry, Volume 3 (J. O’M. Bockris and B. E. Conway, eds.), Plenum Press, New York (1964).

    Google Scholar 

  42. Y. C. Chiu and M. Genshaw, J. Phys. Chem. 51, 3148 (1969).

    Article  Google Scholar 

  43. W. N. Hansen, Anal. Chem. 39, 105 (1967).

    Google Scholar 

  44. W. K. Paik and J. O’M. Bockris, Surface Science 25, 61 (1970).

    Google Scholar 

  45. W. K. Paik, M. Genshaw, and J. O’M. Bockris, J. Phys. Chem. 74, 4266 (1970).

    Article  Google Scholar 

  46. G. Aniansson, J. Phys. Chem. 55, 1286 (1951).

    Article  CAS  Google Scholar 

  47. K. Schwabe, Chem. Tech. (Berlin) 10, 469 (1958).

    CAS  Google Scholar 

  48. E. A. Blomgren and J. O’M. Bockris, Nature 186, 305 (1960).

    Article  CAS  Google Scholar 

  49. N. A. Balshowa, Elektrokhim. 4, 871 (1968).

    Google Scholar 

  50. Y. Veber, D. Pirtshhalava, Y. V. Vasil’ev, and V. S. Bagotsky, Elektrokhim. 5, 1037 (1969).

    CAS  Google Scholar 

  51. W. Heiland, E. Gileadi, and J. O’M. Bockris, J. Phys. Chem. 70, 1207 (1966).

    Article  CAS  Google Scholar 

  52. B. T. Rubin, E. Gileadi, and J. O’M. Bockris, J. Phys. Chem. 69, 3335 (1965).

    Article  Google Scholar 

  53. H. Urbach, private communication (1971).

    Google Scholar 

  54. E. Gileadi, L. Duic, and J. O’M. Bockris, Acta Electrochim. 13, 1915 (1968).

    Article  CAS  Google Scholar 

  55. R. Parsons, “The determination of heats of adsorption of iodide on mercury,” Proc. 2nd Int. Conf. Surface Activity 3, 45 (1952).

    Google Scholar 

  56. E. Gileadi, Electrosorption, Chapter 3, Plenum Press, New York (1967).

    Book  Google Scholar 

  57. P. Delahay and C. T. Fike, J. Am. Chem. Soc. 80, 2628 (1958).

    Article  CAS  Google Scholar 

  58. J. O’M. Bockris, H. Wroblowa, E. Gileadi, and B. J. Piersma, Trans. Faraday Soc. 61, 2531 (1965).

    Article  CAS  Google Scholar 

  59. S. S. Sedova, Y. V. Vasil’ev, and V. S. Bagotskii, Elektrokhim. 4, 1221 (1968).

    CAS  Google Scholar 

  60. L. Griest, Trans. Symp. Electrode Processes, Phila., 1959, p. 294 (1961).

    Google Scholar 

  61. R. D. Armstrong, J. Electroanal. Chem. 20, 168 (1968).

    Article  Google Scholar 

  62. A. N. Frumkin, referred to on p. 265 of L. Antropov, Theoretical Electrochemistry, Mir, Moscow (1972).

    Google Scholar 

  63. L. Antropov, Theoretical Electrochemistry, Mir, Moscow (1972).

    Google Scholar 

  64. J. O’M. Bockris, Energy Conversion 10, 41 (1970).

    Article  CAS  Google Scholar 

  65. J. O’M. Bockris, E. Gileadi, and G. Stoner, J. Electrochem. Soc. 113, 585 (1966).

    Article  Google Scholar 

  66. J. O’M. Bockris, J. Electroanal Chem. 34, 1, 201 (1972).

    Article  CAS  Google Scholar 

  67. A. N. Frumkin and A. Gorodetskaya, Z. Physik. Chem. 136, 215, 415 (1928); Zhur. Fiz. Khim. 5, 240 (1934).

    CAS  Google Scholar 

  68. E. Gileadi and S. Argade, Electrosorption (E. Gileadi, ed.), pp. 94–96, Plenum Press, New York (1967).

    Chapter  Google Scholar 

  69. J. O’M. Bockris and S. Argade, J. Chem. Phys. 49, 5133 (1968).

    Article  CAS  Google Scholar 

  70. R. Parsons, in Modern Aspects of Electrochemistry, Volume 1, Chapter 3 (J. O’M. Bockris, ed.), Butterworths Publications, London (1954).

    Google Scholar 

  71. A. N. Frumkin, Svensk. Kern. Tidskr. 77, 300 (1965).

    CAS  Google Scholar 

  72. B. B. Damaskin, O. A. Petrii, and V. V. Batrakov, Adsorption of Organic Compounds on Electrodes, Chapter 9, Plenum Press, New York (1971).

    Book  Google Scholar 

  73. P. A. Rehbinder and E. K. Wenstrom, Acta Physiochim. 19, 36 (1944).

    Google Scholar 

  74. J. O’M. Bockris and R. Parry-Jones, Nature 171, 930 (1953).

    Article  CAS  Google Scholar 

  75. J. O’M. Bockris and R. K. Sen, Surface Science 30, 237 (1972).

    Article  CAS  Google Scholar 

  76. A. Ya. Gokhshtein, Electrokhim. 2, 1318 (1966); 7, 3 (1971); Electrochim. Acta 15, 219 (1970); Dokl Akad. Nauk. SSSR 200, 620 (1971).

    CAS  Google Scholar 

  77. J. O’M. Bockris, E. Gileadi, and S. Argade, Electrochim. Acta 14, 1259 (1969).

    Article  CAS  Google Scholar 

  78. A. H. Wilson, The Theory of Metals, Cambridge Univ. Press, Cambridge, England (1958).

    Google Scholar 

  79. S. Trasatti, J. Electroanal. Interfacial Chem. 52, 313 (1974).

    Article  CAS  Google Scholar 

  80. J. O’M. Bockris and M. A. Habib, J. Electroanal. Chem. 68, 367 (1976).

    Article  CAS  Google Scholar 

  81. T. Andersen and J. O’M. Bockris, Electrochim. Acta 9, 347 (1964).

    Article  CAS  Google Scholar 

  82. D. D. Bode, J. Phys. Chem. 76, 2915 (1972); Advan. Chem. Phys. 21, 362 (1971).

    Article  CAS  Google Scholar 

  83. D. J. Barclay and J. Caja, Croat. Chem. Acta 43, 221 (1971).

    CAS  Google Scholar 

  84. G. Blyholder, in Modem Aspects of Electrochemistry, Volume 7 (J. O’M. Bockris and B. E. Conway, eds.), Plenum Press, New York (1971).

    Google Scholar 

  85. S. Levine, G. M. Bell, and D. Calvert, Can. J. Chem. 40, 518 (1952).

    Article  Google Scholar 

  86. R. Parsons, Trans. Faraday Soc. 51, 1518 (1955).

    Article  CAS  Google Scholar 

  87. R. Parsons, J. Electroanal. Chem. 5, 397 (1963); Rev. Pure Appl. Chem. (Aust.) 18, 91 (1968).

    Google Scholar 

  88. H. Wroblowa and K. Muller, J. Phys. Chem. 73, 3528 (1969).

    Article  CAS  Google Scholar 

  89. S. Levine, J. Colloid Interface Sci. 37, 619 (1971).

    Article  CAS  Google Scholar 

  90. J. O’M. Bockris and M. A. Habib, Z. Phys. Chem., N.F. 98, 43 (1975).

    Article  CAS  Google Scholar 

  91. R. K. Sen, Ph.D. Thesis, University of Pennsylvania, Philadelphia (1972).

    Google Scholar 

  92. L. M. Baugh and R. Parsons, J. Electroanal. Chem. 40, 407 (1972).

    Article  CAS  Google Scholar 

  93. J. O’M. Bockris and M. A. Habib, J. Res. Inst. Catal., Hokkaido Univ. 23, 47 (1975).

    CAS  Google Scholar 

  94. H. Webb, J. Amer. Chem. Soc. 48, 2589 (1926).

    Article  CAS  Google Scholar 

  95. M. Maisch, Ann. Physik. 84, 841 (1927); Phys. Z. 29, 770 (1928).

    Google Scholar 

  96. B. E. Conway, J. O’M. Bockris, and I. A. Ammar, Trans. Faraday Soc. 47, 756 (1959).

    Article  Google Scholar 

  97. F. Booth, J. Chem. Phys. 19, 391 (1951).

    Article  CAS  Google Scholar 

  98. R. W. Rampolla, R. C. Miller, and C. P. Smyth, J. Chem. Phys. 30, 566 (1959).

    Article  CAS  Google Scholar 

  99. I. R. Miller, Acta Electrochim. 9, 1453 (1964).

    Article  CAS  Google Scholar 

  100. J. Lawrence and R. Parsons, Trans. Faraday Soc. 64, 751 (1968).

    Article  CAS  Google Scholar 

  101. V. A. Kiranov, A. Kuznetsov, and B. B. Damaskin, Elektrokhim. 3, 12 (1967).

    Google Scholar 

  102. J. O’M. Bockris, W. Mehl, B. E. Conway, and L. Young, J. Chem. Phys. 25, 776 (1956).

    Article  CAS  Google Scholar 

  103. K. Muller, Ph.D. Thesis, University of Pennsylvania, Philadelphia (1965).

    Google Scholar 

  104. K. S. Cole and R. H. Cole, J. Chem. Phys. 9, 341 (1941).

    Article  CAS  Google Scholar 

  105. D. C. Grahame, private communication (1955).

    Google Scholar 

  106. R. de Levie, J. Chem. Phys. 47, 2509 (1967).

    Article  Google Scholar 

  107. R. D. Armstrong, W. P. Race, and H. R. Thirsk, J. Electroanal. Chem. 14, 143 (1967).

    Article  CAS  Google Scholar 

  108. D. C. Grahame, J. Amer. Chem. Soc. 76, 4819 (1954).

    Article  CAS  Google Scholar 

  109. J. O’M. Bockris and B. E. Conway, J. Chem. Phys. 28, 707 (1958).

    Article  CAS  Google Scholar 

  110. J. O’M. Bockris and M. A. Habib, J. Electroanal. Chem. 65, 473 (1975).

    Article  CAS  Google Scholar 

  111. E. Blomgren and J. O’M. Bockris, J. Phys. Chem. 63, 1475 (1959).

    Article  CAS  Google Scholar 

  112. J. T. Law, Ph.D. Thesis, London University, London (1952).

    Google Scholar 

  113. A. N. Frumkin and B. B. Damaskin, Modern Aspects of Electrochemistry, Volume 3, Chapter 3 (J. O’M. Bockris and B. E. Conway, eds.), Plenum Press, New York (1964).

    Google Scholar 

  114. B. B. Damaskin, O. A. Petrii, and V. V. Battrokov, Adsorption of Organic Compounds on Electrodes, Plenum Press, New York (1971).

    Book  Google Scholar 

  115. E. A. Blomgren, J. O’M. Bockris, and C. Jesch, J. Phys. Chem. 75, 2000 (1961).

    Article  Google Scholar 

  116. B. B. Damaskin and A. N. Frumkin, Reactions of Molecules at Electrodes, (N. S. Hush, ed.), p. 1, Wiley (Interscience), London (1971).

    Google Scholar 

  117. E. A. Blomgren and J. O’M. Bockris, J. Phys. Chem. 63, 1475 (1959).

    Article  CAS  Google Scholar 

  118. J. O’M. Bockris, M. Green, and D. A. J. Swinkels, J. Electrochem. Soc. 111, 743 (1964)

    Article  CAS  Google Scholar 

  119. J. O’M. Bockris and D. A. J. Swinkels, J. Electrochem. Soc. 111, 736 (1964).

    Article  CAS  Google Scholar 

  120. B. B. Damaskin, J. Electroanal. Chem. 23, 431 (1969).

    Article  CAS  Google Scholar 

  121. J. O’M. Bockris, E. Gileadi, and K. Muller, Electrochim. Acta 12, 1301 (1967).

    Article  CAS  Google Scholar 

  122. E. Gileadi, J. Electroanal. Chem. 30, 123 (1971).

    Article  CAS  Google Scholar 

  123. E. Dukiewitz, J. D. Garnish, and R. Parsons, J. Electroanal Chem. 16, 505 (1968).

    Article  Google Scholar 

  124. R. Payne, J. Electroanal. Chem. 41, 277 (1973).

    Article  CAS  Google Scholar 

  125. M. Green, D. A. J. Swinkels, and J. O’M. Bockris, Rev. Sci. Instr. 33, 18 (1962).

    Article  CAS  Google Scholar 

  126. B. E. Conway and J. Gordon, J. Phys. Chem. 73, 3609 (1969).

    Article  CAS  Google Scholar 

  127. R. Barradas and R. Herman, J. Phys. Chem. 73, 3619 (1969).

    Article  CAS  Google Scholar 

  128. B. B. Damaskin, A. N. Frumkin, and A. Chizou, J. Electroanal. Chem. 28, 93 (1970).

    Article  CAS  Google Scholar 

  129. J. O’M. Bockris, E. Gileadi, and G. Stoner, J. Phys. Chem. 73, 427 (1969).

    Article  CAS  Google Scholar 

  130. R. Armstrong and J. A. V. Butler, Trans. Faraday Soc. 29, 1261 (1933).

    Article  CAS  Google Scholar 

  131. F. G. Will and C. A. Knorr, Z. Elektrochem. 64, 258 (1960).

    CAS  Google Scholar 

  132. M. W. Breiter, Electrochim. Acta 8, 925 (1963).

    Article  Google Scholar 

  133. M. A. V. Devanathan, J. O’M. Bockris, and W. Mehl, J. Electroanal. Chem. 1, 143 (1960).

    Google Scholar 

  134. W. Mehl and J. O’M. Bockris, J. Chem. Phys. 27, 817 (1957).

    Article  Google Scholar 

  135. B. I. Podlovchenko, V. F. Stenin, and V. E. Kazarinov, The Double Layer and Adsorption on Solid Electrodes, p. 121, Izd. Tartusk. Gos. Univ., Tartu, USSR (1968).

    Google Scholar 

  136. T. Biegler and D. F. A. Koch, J. Electrochem. Soc. 114, 904 (1967).

    Article  CAS  Google Scholar 

  137. B. I. Podlovchenko and E. P. Gorgonova, Dokl. Akad. Nauk SSSR 156, 673 (1964).

    CAS  Google Scholar 

  138. V. S. Bagotskii and Yu. B. Vasil’ev, Electrochim. Acta 11, 1439 (1966)

    Article  Google Scholar 

  139. V. S. Bagotskii and Yu. B. Vasil’ev, Advances in the Electrochemistry of Organic Compounds, p. 38, Izd. Nauka, Moscow (1966).

    Google Scholar 

  140. S. B. Brummer, Elektrokhim. 4, 243 (1968).

    Google Scholar 

  141. S. Schuldiner and B. J. Piersma, J. Am. Chem. Soc. 74, 2823 (1970).

    CAS  Google Scholar 

  142. M. Shisandaram, Y. B. Vasil’ev, and V. S. Bagotskii, Elektrokhim. 3, 193 (1967).

    Google Scholar 

  143. B. Cahan, private communication (1978).

    Google Scholar 

  144. A. A. Humffray, in Modem Aspects of Electrochemistry, Volume 8, p. 106 (J. O’M. Bockris and B. E. Conway, ed.), Plenum Press, New York (1972).

    Google Scholar 

  145. G. Harrison and R. Thirsk, A Guide to Electrode Kinetics, Academic Press, New York (1972).

    Google Scholar 

  146. A. N. Frumkin, O. A. Petrii, and B. B. Damaskin, J. Electroanal. Chem. 27, 81 (1970).

    Article  CAS  Google Scholar 

  147. A. N. Frumkin, O. A. Petry, A. Kossaya, V. Entina, and V. Topolev, J. Electroanal. Chem. 16, 175 (1968).

    Article  CAS  Google Scholar 

  148. D. J. Barclay and J. Caja, Croat. Chem. Acta 43, 221 (1971).

    CAS  Google Scholar 

  149. J. O’M. Bockris, A. Damjanovic, and M. L. B. Rao, J. Phys. Chem. 67, 2508 (1963).

    Article  Google Scholar 

  150. A. Damjanovic, in Modem Aspects of Electrochemistry, Volume 5 (J. O’M. Bockris and B. E. Conway, eds.), Plenum Press, New York (1969).

    Google Scholar 

  151. M. Genshaw, A. K. N. Reddy, and J. O’M. Bockris, J. Chem. Phys. 48, 671 (1968).

    Article  Google Scholar 

  152. R. Greef, J. Chem. Phys. 51, 3148 (1969).

    Article  CAS  Google Scholar 

  153. M. Genshaw and J. O’M. Bockris, J. Chem. Phys. 51, 3149 (1969).

    Article  CAS  Google Scholar 

  154. W. Paik and J. O’M. Bockris, Surface Science 28, 61 (1971).

    Article  CAS  Google Scholar 

  155. S. Kim, W. Paik, and J. O’M Bockris, Surface Science 33, 617 (1972).

    Article  CAS  Google Scholar 

  156. V. Brusic, H. Wroblowa, and J. O’M. Bockris, J. Phys. Chem. 75, 2823 (1971).

    Article  Google Scholar 

  157. H. L. von Heimholte, Wied. Ann 7, 337 (1879).

    Google Scholar 

  158. For a comprehensive discussion, see M. A. Habib, Comprehensive Treatise in Electrochemistry (J. O’M. Bockris, B. E. Conway, and E. Yeager, eds.), Plenum Press, New York (1979).

    Google Scholar 

  159. J. O’M. Bockris, S. Argade, and E. Gileadi, Electrochim. Acta 14, 1259 (1969).

    Article  CAS  Google Scholar 

  160. M. A. Habib, Ph.D. Thesis, Flinders University of South Australia (1976).

    Google Scholar 

  161. A. Hoffmann and B. Billings, J. Electroanal. Chem. 77, 97 (1977).

    Article  Google Scholar 

  162. E. A. Moelwyn Hughes, Physical Chemistry (2nd edition), p. 392, Pergamon, London (1961).

    Google Scholar 

  163. Handbook of Chemistry and Physics (35th edition), p. 2387, Chemical Rubber Publishing Co., Cleveland (1953).

    Google Scholar 

  164. J. A. A. Ketelaar, Chemical Constitution, p. 28, Elsevier, Amsterdam (1958).

    Google Scholar 

  165. W. Paik and J. O’M. Bockris, Surface Science 28, 557 (1971).

    Article  Google Scholar 

  166. V. Brusic, H. Wroblowa, and J. O’M. Bockris, J. Phys. Chem. 75, 91 (1971).

    Google Scholar 

  167. E. C. Stoner, Magnetism, p. 38, Methuen, London (1948).

    Google Scholar 

  168. M. A. V. Devanathan, Ph.D. Thesis, University of London,. London (1951).

    Google Scholar 

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  1. Texas A & M University, College Station, Texas, USA

    John O’M. Bockris

  2. University of Bonn, Bonn, West Germany

    Shahed U. M. Khan

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Bockris, J.O., Khan, S.U.M. (1979). Electric Double Layers at Metals. In: Quantum Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2493-5_1

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