Advertisement

Kinetic Aspects of Some Reactions between Metals and Gaseous Carbon Disulphide

  • A. Galerie
  • M. Caillet
  • J. Besson

Abstract

The problem of corrosion of metals by sulphur-containing gases has led for several years researchers to study on a theoretical basis the mechanisms of the phenomena which occur during this kind of reaction. But, if a lot of research has been carried out with hydrogen sulphide or sulphur vapour, there is no systematic study of corrosion by gaseous carbon disulphide, CS2. This compound, a product of big industry which possesses significant vapour pressure at room temperature, seems however very suitable for a theoretical study of the sulphidation of metals. That is the major reason why we have undertaken the study of its behaviour with metals, firstly from a qualitative point of view (thermodynamic diagrams and resulting products), secondly from a quantitative one (kinetics of sulphuration, influence of temperature and pressure).

Keywords

Hydrogen Sulphide Carbon Disulphide Sulphur Vapour Iron Sulphide Bolic Stage 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Copyright information

© Springer Science+Business Media New York 1977

Authors and Affiliations

  • A. Galerie
    • 1
  • M. Caillet
    • 1
  • J. Besson
    • 1
  1. 1.Laboratoire d’Adsorption et Reaction de Gaz sur Solides ERA CNRS n° 368 Ecole Nationale Superieure d’Electrochimie et d’ElectrometallurgieDomaine UniversitaireSaint Martin d’HeresFrance

Personalised recommendations