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Recent Developments in Chemistry of Organolanthanides and Organoactinides

  • Minoru Tsutsui
  • Carol Hyde
  • Alan Gebala
  • Neal Ely

Abstract

In contrast with pi-bonded organometallic compounds of the lanthanides1 and actinides2, which date to the mid 1950’s, encompass a large variety of ligands3 and culminate with the synthesis of bis-(cyclooctatetraenyl)uranium (“uranocene”),4 the preparation of sigma-bonded lanthanide and actinide organometallics is relatively recent. Early attempts to prepare simple oganometallic derivatives, such as U(CH3)4 5, Y(C2H5)3, and Sc(C2H5)3 6, often resulted in poorly characterized or irreproducible products. Sigma-bonded derivatives of both the lanthanide7,8 and actinide9 elements are now known and well characterized.10

Keywords

Mercuric Chloride Bonding Mode Sigma Bond Methyl Lithium Organometallic Derivative 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1975

Authors and Affiliations

  • Minoru Tsutsui
    • 1
  • Carol Hyde
    • 1
  • Alan Gebala
    • 1
  • Neal Ely
    • 1
  1. 1.Department of ChemistryTexas A&M UniversityCollege StationUSA

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