Advertisement

An Unusual Behavior of π-Vinyl Alcohol Complexes of Transition Metals

  • J. Frances
  • M. Ishaq
  • M. Tsutsui

Abstract

Although the usefulness of polyvinyl alcohol [PVA] polymer has long been recognized, no work has been reported on the vinyl alcohol moiety itself. This is due to the fact that the existence of free vinyl alcohol has not yet been shown. It has been postulated that a small percentage of this unstable specie, vinyl alcohol, exists in situ in an equilibrium with acetaldehyde.1 However, it has been claimed that vinyl alcohol forms stable organometallic complexes with transition metal ions. These vinyl alcohol complexes of transition metals have been proposed as being π-bonded to the metal.

Keywords

Iron Complex Vinyl Alcohol Trimethylsilyl Ether Silyl Ether Hydrogen Bromide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. Gero, J. Org. Chem., 19, 469 (1954).CrossRefGoogle Scholar
  2. 2.
    R. Criegee and G. Schroder, Angew Chem., 71, 70 (1959);CrossRefGoogle Scholar
  3. M. Avram, E. Mrica and C. D. Nenitzescu, Chem. Ber., 92, 1088 (1959);CrossRefGoogle Scholar
  4. A. Brown, E. H. Braye, A. Clauss, E. Weiss, U. Kruerke, W. HubelGoogle Scholar
  5. G. D. I. King and C. Hoogzand, J. Inorg. Nucl. Chem., 9, 204 (1959).CrossRefGoogle Scholar
  6. 3.
    E. W. Gowling, S. F. A. Kettle, and G. M. Sharples, Chem. Comm., 21 (1968).Google Scholar
  7. 4.
    E. O. Fischer and A. Massbol, Chem. Ber., 100, 2945 (1967).Google Scholar
  8. 5.
    J. K. P. Ariyaratne and M. L. G. Green, J. Chem. Soc., 2976 (1963).Google Scholar
  9. 6.
    R. Jira, J. Sedlmeier and J. Smidt, Liebigs., Ann. Chem. Internat. Edn., 1, 80 (1962).CrossRefGoogle Scholar
  10. 7.
    J. Smith, W. Hafner, R. Jira, L. Sedlmeier and A. Sabel, Angew. Chem. Internat. Ed., 1, 80 (1962).Google Scholar
  11. 8.
    J. K. P. Ariyaratne and M. L. H. Green, J. Chem. Soc., 1 (1964).Google Scholar
  12. 9.
    M. Rosemblum, A. Cutler and S. Raghu, J. Organometal. Chem. in press and personal comm. to Prof. M. Tsutsui.Google Scholar
  13. 10.
    Y. Wakatsuki, S. Nozakura and S. Murahashi, Bull. Chem. Soc. Japan, 42, 273 (1969).CrossRefGoogle Scholar
  14. 11.
    H. Thyret, Angew. Chem. Internat. Ed., 11, 520 (1972).CrossRefGoogle Scholar
  15. 12.
    M. Tsutsui, M. Ori and J. Francis, J. Chem. Soc., 94, 1414 (1972).CrossRefGoogle Scholar
  16. 13.
    F. A. Cotton, J. N. Francis, B. A. Frenz and M. Tsutsui, J. Am. Chem. Soc., 95, 2483 (1973).CrossRefGoogle Scholar
  17. 14.
    M. Tsutsui and J. N. Francis, Chem. Letters, 663 (1973).Google Scholar
  18. 15.
    J. Hillis and M. Tsutsui, J. Am. Chem. Soc., 95, 7907 (1973).CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1975

Authors and Affiliations

  • J. Frances
    • 1
  • M. Ishaq
    • 1
  • M. Tsutsui
    • 1
  1. 1.Chemistry DepartmentTexas A&M UniversityCollege StationUSA

Personalised recommendations