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Unusual Metalloporphyrins

  • Minoru Tsutsui
  • C. P. Hrung

Abstract

The use of metal carbonyls for the insertion of metal ions into porphyrins was first introduced by Tsutsui and co-workers2,3 in 1966. This method has developed itself to be a useful and unique technique in the synthesis of new metalloporphyrin complexes within the last decade. In addition to a number of previously reported metalloporphyrins, the reaction of metal carbonyls and metal carbonyl halides with neutral porphyrins has led to the syntheses of new metalloporphyrin complexes of chromium, molybdenum, technetium, ruthenium, rhodium, rhenium, and iridium.4 Except for the chromium and molybdenum porphyrin complexes, carbonyl groups are retained by the metals in the new metalloporphyrin complexes.

Keywords

Porphyrin Ring Metal Carbonyl Porphyrin Plane Triple Decker Alkyl Lithium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1975

Authors and Affiliations

  • Minoru Tsutsui
    • 1
  • C. P. Hrung
    • 1
  1. 1.Department of ChemistryTexas A&M UniversityCollege StationUSA

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