Abstract
The use of metal carbonyls for the insertion of metal ions into porphyrins was first introduced by Tsutsui and co-workers2,3 in 1966. This method has developed itself to be a useful and unique technique in the synthesis of new metalloporphyrin complexes within the last decade. In addition to a number of previously reported metalloporphyrins, the reaction of metal carbonyls and metal carbonyl halides with neutral porphyrins has led to the syntheses of new metalloporphyrin complexes of chromium, molybdenum, technetium, ruthenium, rhodium, rhenium, and iridium.4 Except for the chromium and molybdenum porphyrin complexes, carbonyl groups are retained by the metals in the new metalloporphyrin complexes.
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© 1975 Plenum Press, New York
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Tsutsui, M., Hrung, C.P. (1975). Unusual Metalloporphyrins. In: Ishii, Y., Tsutsui, M. (eds) Organotransition-Metal Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2142-2_33
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DOI: https://doi.org/10.1007/978-1-4684-2142-2_33
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