Conformational Equilibria and Stereospecific Synthesis

  • Jack Faller


Pi allyl-complexes have been used as reactants or have been postulated as intermediates in many of the reactions discussed at this symposium. Our studies of rearrangement mechanisms and conformational equilibria often provide a rationale for the product distributions and stereochemistry in these reactions. It appears that steric factors tend to control stereochemistry. Kinetic and thermodynamic parameters of some palladium complexes will be reviewed in the perspective of their implications in rearrangements, stereospecific reactions, and racemization processes.


Absolute Configuration Palladium Complex Conformational Equilibrium Terminal Carbon Atom Rearrangement Mechanism 


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  1. 1.
    J. W. Faller, M. E. Thomsen, and M. J. Mattina, J. Amer. Chem. Soc., 93, 2642 (1971).CrossRefGoogle Scholar
  2. 2.
    J. W. Faller, M. T. Tully and K. J. Laffey, J. Organometal. Chem., 37, 193 (1972).CrossRefGoogle Scholar
  3. 3.
    J. W. Faller and K. J. Laffey, Organometal. Chem. Syn., 1, 471 (1972).Google Scholar
  4. 4.
    P. Ganis, G. Maglio, A. Musco, and A. L. Segre, Inorg. Chim. Acta., 3, 266 (1969).CrossRefGoogle Scholar
  5. 5.
    J. W. Faller and M. T. Tully, J. Amer. Chem. Soc., 94, 2676 (1972).CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1975

Authors and Affiliations

  • Jack Faller
    • 1
  1. 1.Department of ChemistryYale UniversityNew HavenUSA

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