Summary
Allyloxycarbonylplatinum(II) complexes readily afforded π-allylplatinum(II) complexes by decarboxylation under several reaction conditions. The importance of olefin coordination to a platinum atom in the transition state is suggested. The other novel routes to π-allylplatinum(II) complexes which apparently involve a similar reaction intermediate are also described.
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References
See e.g., R. Baker, Chem. Rev., 73, 487 (1973).
Part of this work was reported; H, Kurosawa and R. Okawara, J. Organometal. Chem., 71, C35 (1974).
H. C. Clark and W. J. Jacobs, Inorg. Chem., 9, 1229 (1970) and references cited therein.
J. D. Ruddick and B. L. Shaw, J. Chem. Soc., (A) 2801 (1969).
H. C. Clark and H. Kurosawa, Inorg. Chem., 11, 1275 (1972).
R. Cramer and R. V. Lindsey, Jr., J. Amer. Chem. Soc., 88, 3534 (1966).
H. C. Clark and H. Kurosawa, Inorg. Chem., 12, 357 (1973).
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© 1975 Plenum Press, New York
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Kurosawa, H., Okawara, R. (1975). A Facile Formation of π-Allylplatinum Complexes by Decarboxylation of Allyloxycarbonylplatinum Complexes: Importance of π-Olefin Coordination in π-Allylplatinum Formation. In: Ishii, Y., Tsutsui, M. (eds) Organotransition-Metal Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-2142-2_28
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DOI: https://doi.org/10.1007/978-1-4684-2142-2_28
Publisher Name: Springer, Boston, MA
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