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Some Synthetic Reactions by Means of Nickel Carbonyl and Organic Halides

  • Membo Ryang
  • Ilsong Rhee
  • Shinji Murai
  • Noboru Sonoda

Abstract

During the last decade, various types of reactions of nickel carbonyl with organic halides have been extensively studied and some of them have been established as synthetically useful reactions1–4. Herein one of the serious problems in applying the reactions to synthetic organic chemistry was that the reactions were limited to the special types of organic halides, such as allyl halides, aryl iodides, benzyl halides and α-haloketones. The high reactivity of these halides was considered to be due to the stabilization of the intermediate nickel complexes by the coordination of organic moieties as π-allyl or pseudo π-allyl type ligands to nickels and hence to a lowering of the activation energy of the reaction between nickel carbonyl and the organic halides. The typical example is the reaction of nickel carbonyl with allyl halides, and the synthetic application of the intermediate complexes, π-allylnickel halides, have been up to now most systematically investigated.4

Keywords

Styrene Oxide Aryl Iodide Organic Halide Benzyl Halide Nickel Carbonyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1975

Authors and Affiliations

  • Membo Ryang
    • 1
  • Ilsong Rhee
    • 1
  • Shinji Murai
    • 1
  • Noboru Sonoda
    • 1
  1. 1.Department of Petroleum Chemistry, Faculty of EngineeringOsaka UniversityYamada-kami, Suita, OsakaJapan

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