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Observation of S-Band Heads in the Resonance Raman Spectrum of Iodine Vapor

  • W. Kiefer

Abstract

Resonance Raman scattering has been observed from iodine vapor excited by light above the dissociation limit. The spectra are characterized by a progression of vibrational lines observable through the 20th harmonic. These lines display complex structure, including peaks (distinct from that of the Q-branch) that can be regarded as band heads. Here we show how this spectral structure arises from vibration-rotation interactions and vibrational anharmonicity.

Keywords

Iodine Vapor Spectroscopic Constant Dissociation Limit Band Head Resonance Raman Spectrum 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

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Copyright information

© Springer Science+Business Media New York 1974

Authors and Affiliations

  • W. Kiefer
    • 1
  1. 1.Sektion PhysikUniversität MünchenMünchenGermany

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