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Sulfoxides and Sulfilimines

  • Shigeru Oae

Abstract

Sulfoxides are formed by partial oxidation of sulfides, which upon further oxidation are converted to sulfones, and hence may be considered as a very stable intermediate in the oxidation process. However, since the sulfur-oxygen linkage in sulfoxides is polarized and much weaker than that in sulfones, sulfoxides are relatively reactive and undergo many synthetically important reactions. Therefore, the chemistry involving this trivalent sulfur species has been growing rapidly in recent years.1

Keywords

Acetic Anhydride Dialkyl Sulfide Neighboring Group Participation Phenyl Sulfoxide Racemization Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1977

Authors and Affiliations

  • Shigeru Oae
    • 1
  1. 1.Department of ChemistryUniversity of TsukubaNiihari-gun Ibaraki-kenJapan

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