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Energy Transfer from Chemically Excited Carbonyl Compounds to Anthracence Derivatives and Oxygen

  • V. A. Belyakov
  • G. F. Fedorova
  • R. F. Vassil’ev
Conference paper

Abstract

The fates of triplet carbonyls formed by disproportionation of peroxy radical are considered. The measured rate constants for T-T and T-S energy transfer, and quenching by O2 are shown to be related to the probabilities of simple primary processes. The mechanisms of the latter are considered.

Keywords

Energy Transfer Peroxy Radical Anthracene Derivative Ethylbenzene Oxidation Excitation Yield 
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References

  1. 1.
    R. F. Vassil’ ev, Progr. Reaction Kinetics, 305 (1967).Google Scholar
  2. 2.
    V. A. Belyakov and R. F. Vassil’ev, Photochem. Photobiol., 11, 179 (1970).CrossRefGoogle Scholar
  3. 3.
    J. A. Howard and K. U. Ingold, J. Am. Chem. Soc., 90, 1056 (1968).CrossRefGoogle Scholar
  4. 4.
    V. A. Belyakov, R. F. Vassil’ev and G. F. Fedorova, Izv. Akad. Nauk SSSR, Ser. Fiz., 32, 1325 (1968).Google Scholar
  5. 5.
    V. A. Belyakov and R. F. Vassil’ev, in: Molekulyarnaya Fotonika, Nauka, Moscow, 70 (1970).Google Scholar
  6. 6.
    R. F. Vassil’ev and G. F. Fedorova, Optika I Spektroskopiya, 24, 419 (1968).Google Scholar
  7. 7.
    D. L. Dexter, J. Chem. Phys., 21,836 (1953).ADSCrossRefGoogle Scholar
  8. 8.
    R. F. Vassil’ev, Nature, 200, 773 (1963).ADSCrossRefGoogle Scholar
  9. 9.
    P. G. Bennett, P. J. McCartin, J. Chem. Phys., 44, 1969 (1966).ADSCrossRefGoogle Scholar
  10. 10.
    A. U. Khan and M. Kasha, J. Am. Chem. Soc., 88, 1574 (1966)CrossRefGoogle Scholar
  11. A. U. Khan and M. Kasha, J. Am. Chem. Soc., 92, 3293 (1970).CrossRefGoogle Scholar
  12. 11.
    R. E. Rehhert, P. Ausloos, J. Am. Chem. Soc., 87, I847 (1965)CrossRefGoogle Scholar
  13. R. E. Rehhert, P. Ausloos, 87, 5569 (1965)Google Scholar
  14. N. A. Borisevich, A. A. Kotov, G. B. Tolstorozhev, this conference.Google Scholar
  15. 12.
    P. J. Wagner and I. Kochevar, J. Am. Chem. Soc., 90, 2232 (1968).CrossRefGoogle Scholar
  16. 13.
    R. E. Kellogg, J. Am. Chem. Soc., 91, 5432 (1969).CrossRefGoogle Scholar
  17. 14.
    G. Porter and M. R. Windsor, Proc. Roy. Soc., A245, 238 (1958).ADSGoogle Scholar
  18. 15.
    H. L. J. Bakstrom and K. Sandros, Acta Chem. Scand., 12, 832 (1958).Google Scholar
  19. 16.
    G. Jackson, R. Livingston and A. C. Pugh, Trans. Faraday Soc., 56, 1635 (1960).CrossRefGoogle Scholar
  20. 17.
    W. R. Ware, J. Phys. Chem., 66, 455 (1962).CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1973

Authors and Affiliations

  • V. A. Belyakov
    • 1
  • G. F. Fedorova
    • 1
  • R. F. Vassil’ev
    • 1
  1. 1.Inst.of Chem. Phys.Academy of Sciences of the USSRMoscowUSSR

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