Recent Advances in the Chemistry of Micelles
During the last decade the study of micelle formation in detergent solutions, like many other areas of chemical science, has undergone almost explosive growth, promoted by technological advances which made possible substantial improvements in existing experimental methods and the introduction of altogether new techniques. An additional stimulus has been an upsurge of interest in the micellization phenomenon among chemists not primarily concerned with surfactant solutions for their own sake. This group consists principally of biochemists who have focussed attention on similarities between detergent micelles, monolayers, or bilayers and the phospholipid regions of biological membranes, and between micelles and globular proteins. Although micelles and proteins do not really have very much in common from a structural point of view beyond the fact that both are stabilized by hydrophobic interactions, it is now well established [1, 2] that micelles exert catalytic effects on assorted organic reactions which are at least reminiscent of the effects produced by enzymes. This discovery aroused the interest of physical organic chemists, and its ramifications form the subject matter of the major portion of this symposium.
KeywordsAlkyl Chain Guest Molecule Alkyl Chain Length Outer Core Dodecyl Sodium Sulfonate
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- 6.J. A. Pople, W. G. Schneider, and H. J. Bernstein, “High Resolution Nuclear Magnetic Resonance,” McGraw-Hill Book Co., New York, N. Y., 1959, p. 222.Google Scholar
- 12.N. Muller, J. H. Pellerin, and W. W. Chen., J. Phys. Chem., to be published.Google Scholar
- 21.J. Lang, J. J. Auburn, and E. M. Eyring, J. Colloid Interface Sci., submitted. The author is indebted to Professor Eyring for a prepublication copy of this article.Google Scholar
- 22.N. Muller, J. Phys. Chem., submitted.Google Scholar
- 37.J. M. Corkill, J. F. Goodman, and J. R. Tate, “Hydrogen Bonded Solvent Systems,” A. K. Covington and P. Jones, Eds., Taylor and Francis, Ltd., London, 1968, p. 181.Google Scholar
- 41.J. M. Corkill and J. F. Goodman, Advan. Colloid Interface Sci., 2, 297 (1969).Google Scholar
- 43.T. W. Johnson, Ph. D. Thesis, Purdue University, 1970.Google Scholar
- 44.N. Muller and J. H. Pellerin, Abstracts of the 162nd National Meeting, American Chemical Society, Washington, D. C. Sept. 1971.Google Scholar
- 50.D. N. Glew, H. D. Mak, and N. S. Rath, Chem. Commun., 264 (1968).Google Scholar
- 51.D. N. Glew, H. D. Mak, and N. S. Rath, “Hydrogen Bonded Solvent Systems,” A. K. Covington and P. Jones, Eds., Taylor and Francis, Ltd., London, 1968 p. 195.Google Scholar
- 52.H. G. Hertz and W. Spalthoff, Z. Elektrochem. 63, 1096 (1959).Google Scholar