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Polyelectrolytes in Aqueous Solutions—Filtration, Hyperfiltration, and Dynamic Membranes

  • James S. JohnsonJr.

Abstract

Filtration is one of the oldest separation techniques, apparently known to the Chinese and Hebrews in ancient times [l]. It remains one of the most important, and new methods of carrying it out, as well as new applications, continue to be devised. In the last century, it expanded beyond the separation of solid particulates from liquids or gases to separations of colloids from fluids, by ultrafiltration. In recent decades, filtration of low-molecular solutes has been found possible, by “reverse osmosis.” Thinking of removal of dissolved solids as a filtration process is helpful on occasion, and the alternate name “hyperfiltration” [2] is sometimes used.

Keywords

Dynamic Membrane Zirconium Content Circulation Velocity Flux Decline Methyl Ammonium Chloride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    George D. Dickey, Filtration, Reinhold Publishing Co., New York (1961).Google Scholar
  2. 2.
    K. S. Spiegler, Salt Water Purification, Wiley, New York (1962).Google Scholar
  3. 3.
    K. A. Kraus, H. O. Phillips, T. A. Carlson, and J. S. Johnson, Proc. Second Intern. Conf. Peaceful Uses of Atomic Energy, Geneva, 28, 3 (1958).Google Scholar
  4. 4.
    J. W. McBain and R. F. Stuewer, J. Phys. Chem., 40, 1157 (1936)CrossRefGoogle Scholar
  5. J. G. McKelvey, K. S. Spiegler, and M. R. J. Wyllie, Chem. Eng. Prog. Symp. Ser., 55, No. 24, 199 (1959).Google Scholar
  6. 5.
    C. E. Reid and E. J. Breton, J. Appl. Polymer Sci., 1, 133 (1959).CrossRefGoogle Scholar
  7. 6.
    T. Teorell, Proc. Soc. Expt. Biol. Med., 33, 282 (1935).Google Scholar
  8. 7.
    J. S. Johnson, L. Dresner, and K. A. Kraus, Chapter 8 in Principles of Desalination, K. S. Spiegler (Ed.), Academic Press, New York (1966).Google Scholar
  9. 8.
    L. Dresner and K. A. Kraus, J. Phys. Chem., 67, 990 (1963);CrossRefGoogle Scholar
  10. L. Dresner, J. Phys. Chem., 69, 2230 (1965).CrossRefGoogle Scholar
  11. 9.
    A. E. Marcinkowsky, K. A. Kraus, H. O. Phillips, J. S. Johnson, and A. J. Shor, J. Am. Chem. Soc., 88, 5744 (1966).CrossRefGoogle Scholar
  12. 10.
    A. J. Shor, K. A. Kraus, W. T. Smith, Jr., and J. S. Johnson, Jr., J. Phys. Chem., 72, 2200 (1968).CrossRefGoogle Scholar
  13. 11.
    K. A. Kraus, H. O. Phillips, A. E. Marcinkowsky, J. S. Johnson, and A. J. Shor, Desalination, 1, 225 (1966).CrossRefGoogle Scholar
  14. 12.
    K. A. Kraus, A. J. Shor, and J. S. Johnson, Desalination, 2, 243 (1967).CrossRefGoogle Scholar
  15. 13.
    S. B. Sachs, W. H. Baldwin, and J. S. Johnson, Jr., Desalination, 6, 215 (1969).CrossRefGoogle Scholar
  16. 14.
    J. J. Perona, F. H. Butt, S. M. Fleming, S. T. Mayr, R. A. Spitz, M. K. Brown, H. D. Cochran, K. A. Kraus, and J. S. Johnson, Environ. Sci. Technol., 1, 991 (1967).CrossRefGoogle Scholar
  17. 15.
    H. C. Savage, N. E. Bolton, H. O. Phillips, K. A. Kraus, and J. S. Johnson, Water and Sewage Works, 116, 102 (1969).Google Scholar
  18. 16.
    C. Aurich, C. A. Brandon, J. S. Johnson, Jr., R. E. Minturn, K. Turner, and P. A. Wadia, J. Water Pollution Control Federation (in press).Google Scholar
  19. 17.
    E. R. Brownscombe and L. R. Kern, U. S. Patent, 331, 772, 1967.Google Scholar
  20. 18.
    D. G. Thomas and J. S. Watson, Ind. Eng. Chem. Proc. Des. Develop., 7, 397 (1968).CrossRefGoogle Scholar
  21. 19.
    D. G. Thomas, P. H. Hayes, W. R. Mixon, J. D. Sheppard, W. L. Griffith, and R. M. Keller, Environ. Sci. Technol., 4 1129 (1970).CrossRefGoogle Scholar
  22. 20.
    Application of Hyperfiltration to Treatment of Municipal Sewage Effluents,“ Water Pollution Control Research Series ORD 17030 EOH 01/70, Federal Water Quality Administration, U. S. Department of the Interior.Google Scholar
  23. 21.
    T. K. Sherwood, P. L. T. Brian, R. E. Fisher, and L. Dresner, Ind. Eng. Chem. Fundamentals, 4, 113 (1965).CrossRefGoogle Scholar
  24. 22.
    A. J. Shor, K. A. Kraus, J. S. Johnson, Jr., and W. T. Smith, Jr., Ind. Eng. Chem. Fundamentals, 7, 44 (1968).CrossRefGoogle Scholar
  25. 23.
    J. S. Johnson, Jr., R. E. Minturn, and P. H. Wadia, submitted to J. Electroanal. and Interfacial Chemistry.Google Scholar
  26. 24.
    W. R. Mixon, M. S. Thesis, University of Tennessee, ORNL-TM2150 (1969), p. 22Google Scholar
  27. D. G. Thomas, ORNL, private communication.Google Scholar
  28. 25.
    J. B. Cabellon, A. K. Padia, and L. E. Whitesides, Jr., Mass. Inst. of Technol. School of Chemical Engineering Practice, Oak Ridge Station, Report ORNL-MIT-124 (1971).Google Scholar
  29. 26.
    W. R. Mixon and D. G. Thomas, ORNL, unpublished results.Google Scholar
  30. 27.
    J. M. Ganzer and A. K. Mehta, Mass. Inst. of Technol. School of Chemical Engineering Practice, Oak Ridge Station, Report ORNL-MIT-100 (1970).Google Scholar
  31. 28.
    I. Onal, C. S. Goff, and J. M. Aslam, Mass. Inst. of Technol. School of Chemical Engineering Practice, Oak Ridge Station, Report ORNL-MIT-104 (1970).Google Scholar
  32. 29.
    Mason-Rust, Office of Saline Water Research and Development Progress Report No. 134, U. S. Department of the Interior (1966). Foss Reservoir water, H. E. Podall, private communication.Google Scholar
  33. 30.
    S. B. Sachs and H. K. Lonsdale, J. Appl. Polymer Sci., 15, 797 (1971).CrossRefGoogle Scholar
  34. 31.
    J. S. Johnson, Jr., K. A. Kraus, S. M. Fleming, H. D. Cochran, Jr., and J. J. Perona, Desalination, 5, 359 (1968).CrossRefGoogle Scholar
  35. 32.
    U. Merten, H. K. Lonsdale, R. L. Riley, and K. D. Vos, Office of Saline Water Research and Development Progress Report No. 208, U. S. Department of the Interior (1966).Google Scholar
  36. 33.
    J. R. Kuppers, A. E. Marcinkowsky, K. A. Kraus, and J. S. Johnson, Jr., Separ. Sci., 2, 617 (1967).CrossRefGoogle Scholar
  37. 34.
    A. J. Heman and J. C. Bronfenbrenner, M.I.T. School of Chemical Engineering Practice, Oak Ridge Station, Report ORNL-MIT-112 (1970).Google Scholar
  38. 35.
    J. Acosta, J. P. Jacks, and S. H. Rubin, M.I.T. School of Chemical Engineering Practice, Oak Ridge Station, Report ORNL-MIT-127 (1971).Google Scholar
  39. 36.
    C. A. Brandon, J. S. Johnson, R. E. Minturn, and J. J. Porter, to appear in Proceedings of New Orleans Meeting of the American Society of Mechanical Engineers, March 27–29, 1972.Google Scholar
  40. 37.
    J. D. Sheppard and D. G. Thomas, Applied Polymer Symposia, No. 13, “Membranes from Cellulose and Cellulose Derivatives,” A. F. Turbak (Ed.), (1970), p. 121.Google Scholar
  41. 38.
    J. D. Sheppard and D. G. Thomas, Desalination, 8, 1 (1970).CrossRefGoogle Scholar
  42. 39.
    J. A. Dahlheimer, D. G. Thomas, and K. A. Kraus, Ind. Eng. Chem., Proc. Des. Develop., 9, 565 (1970).CrossRefGoogle Scholar
  43. 40.
    Shriver Continuous Thickener,“ T. Shriver & Co., Inc., Harrison, N. J.; C. A. Jahreis, U. S. Patent 2, 364, 366 (1944).Google Scholar
  44. 41.
    A. I. Zhevnovatyi, Int. Chem. Eng., 4, 124 (1964).Google Scholar
  45. 42.
    C. W. Desaulniers and R. W. Hausslein, “Ultrafiltrative Dewatering of Spent Powdered Carbon,” Federal Water Quality Administration WPCRS 17020DA03/70 (PB-197865) (1970).Google Scholar
  46. 43.
    H. A. Mahlman and K. A. Kraus, ORNL, unpublished results.Google Scholar
  47. 44.
    P. H. Wadia, K. A. Kraus, A. J. Shor, and L. Dresner, Oak Ridge National Laboratory Report, ORNL-4729 (1971).Google Scholar

Copyright information

© Plenum Press, New York 1972

Authors and Affiliations

  • James S. JohnsonJr.
    • 1
  1. 1.Chemistry DivisionOak Ridge National LaboratoryOak RidgeUSA

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