Abstract
In an age of increasing pressures placed on the earth’s resources, there is great concern for the atmosphere’s ability to cleanse itself of anthropogenically generated material. Indeed, the earth’s atmosphere has been overloaded locally with pollution, particularly over cities, to create rather unhealthy and aesthetically unpleasant living conditions. On larger scales, there is conflicting evidence of man’s intrusion into the natural composition of the atmosphere. Perhaps the best evidence for anthropogenically stimulated imbalances between production and removal of trace constituents are the data on the continuing increase of carbon dioxide in the air. A variety of different observations has indicated that the atmospheric CO2 concentration has increased at a rate of about 0.2% per year during the period between 1958 and 1969 [1]. Other evidence such as that reported for global decreases in visibility is less well documented, and independent evidence of emission surveys does not confirm a serious increase in global haze development by anthropogenic sources [1,6].
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References
Study of Critical Environmental Problems (SCEP), “Man’s Impact on the Global Environment,” MIT Press, Cambridge, Mass., 1970, Chapter 2.
Hidy, G. Mand Brock, J. R., “The Dynamics of Aerocolloidal Systems,” Pergamon Press, New York, 1970.
Junge, C. E., “Atmospheric Chemistry and Radioactivity,” Academic Press, New York, 1963.
Bird, R. B., Stewart, W. E., and Lightfoot, E. N., “Transport Phenomena,” Wiley, New York, 1960.
Renzetti, N. A., and Doyle, G. J., The chemical nature of the particulate in irradiated automobile exhaust, J. Air Poll. Contr. Assoc. 8, 293–296 (1959).
Hidy, G. M., and Brock, J. R., An assessment of the global sources of aerosols, in “Proc. 2nd IUAPPA Clean Air Congress, Washington, D.C., December 1970,” Academic Press, New York, 1971, pp. 1088–1097.
Hidy, G. M., and Friedlander, S. K., The nature of the Los Angeles aerosol, in “Proc. of 2nd IUAPPA Clean Air Congress, Washington, D.C.,” Academic Press, New York, 1971, pp. 391–404.
Robinson, E., and Robbins, R., Sources, abundance, and fate of gaseous atmospheric pollutants, Stanford Research Institute Final Rept. Proj. PR-6755, Menlo Park, Calif., 1968; also supplemental report, 1969.
Brock, J. R., Attachment of trace substances on atmospheric aerosols, in AEC Symposium Series No. 22, U. S. Atomic Energy Commission, Oak Ridge, Tenn., 1971, pp. 373–380.
Souilleux, P. J., The measurement of the size spectrum and charge to total ratio of condensation nuclei having naturally occurring radon daughter products attached to them, Health Phys. 18, 245–254 (1970).
Corn, M, Montgomery, T. L., and Esmen, N. A., Suspended particulate matter: seasonal variation in specific surface areas and densities, Environ. Sci. and Technol. 5, 155–157 (1971).
Rabinowitch, E. I., “Photosynthesis and Related Processes,” Interscience, New York, 1945.
Chamberlain, A. C., Transport of gases to and from grass and grasslike surfaces, Proc. Royal Soc. (London) A290, 236–265 (1966).
Levich, V. G., “Physicochemical Hydrodynamics” (English transl.), Prentice-Hall, Engle- wood Cliffs, N.J., 1962, pp. 166–171.
Seiler, W., and Junge, C. E., Carbon monoxide in the atmosphere, J. Geophys. Res. 75, 2217–2226 (1970).
Leighton, P. A., “Photochemistry of Air Pollution,” Academic Press, New York, 1961.
Lemke, E. E., Thomas, G., and Zwiacker, W. E. Profile of air pollution control in Los Angeles County, Los Angeles County Air Pollution Control District, 1969.
Koyoma, T., Gaseous metabolism in lake sediments and paddy soils and the production of atmospheric methane and hydrogen, J. Geophys. Res. 68, 3971–3974 (1963).
Bainbridge, A. E., and Heidt, L. E., Measurements of methane in the troposphere and lower stratosphere, Tellus 18, 221–225 (1966).
Schütz, K., Junge, C., Beck, R., and Albrecht, B., Studies of Atmospheric N20, J. Geophys. Res. 75, 2230–2246 (1970).
Bates, D. R., and Hayes, P. B., Atmospheric nitrous oxide, Planet. Space Sci. 15, 189 (1967).
Georgii, H. W., Geofis. pura e appl. 47, 155–171 (1960).
Acrivos, A., and Taylor, T. D., Heat and mass transfer for single spheres in stokes flow, Phys. Fluids 5, 387–394 (1962).
Frössling, N., Gerlands Beitr. Geophys. 52, 1970 (1938).
Dankwerts, P. V., Absorption by simultaneous diffusion and chemical reaction into particles of various shapes and into falling drops, Trans. Faraday Soc. 47, 1014–1023 (1951).
Postma, A. K., Effect of solubilities of gases on their scavenging by raindrops, in U.S. AEC Symposium Series No. 22, U.S. Atomic Energy Commission, Oak Ridge, Tenn., 1970, pp. 247–259.
Beilke, S., and Georgii, H., Investigation on the incorporation of S02 into fog and rain droplets, Tellus 20, 435–441 (1968).
Summers, P. W., Scavenging of S02 by convective storms, in AEC Symposium Series No. 22, U. S. Atomic Energy Commission, Oak Ridge, Tenn., 1970, pp. 305–318.
Andersson, T., Small-scale variations of the contamination of rain caused by washout from the low layers of the atmosphere, Tellus 21, 685–692 (1967).
Georgii, H., and Wötzel, D., On the relation between droplet size and concentration of trace elements in rainwater, J. Geophys. Res. 75, 1727–1731 (1967).
Urone, P., and Schroeder, W. H., S02 in the atmosphere: a wealth of monitoring data, but few reaction rate studies, Environ. Sci. and Technol. 3, 436–445 (1969).
Schuck, E. A., and Doyle, G. J., Photooxidation of hydrocarbons in mixtures containing oxides of nitrogen and sulfur dioxide, Air Pollution Foundation (Los Angeles), Report No. 29, 1959.
Ogata, Y., Izawa, Y., and Tsuda, T., The photochemical sulfoxidation of n-hexane, Tetrahedron 21, 1349–1356 (1965).
Doyle, G. J., Self-nucleation in the sulfuric acid-water system, J. Chem. Phys. 35, 795–9 (1961).
Quon, J. E., Siegel, R. P., and Mulburt, H. M., Particle formation from photolysis of sulfur dioxide in air, in “Proc. 2nd IUAPPA Clean Air Congress, Washington, D.C., December 1970,” Academic Press, New York, 1971, pp. 330–335.
Katz, M., and Gale, S. B., Mechanism of photooxidation of sulfur dioxide in the atmosphere, in “Proc. 2nd IUAPPA Clean Air Congress, Washington, D.C., December 1970,” Academic Press, New York, 1970, pp. 336–343.
Harkins, J., and Nicksic, S. W., Studies in the role of sulfur dioxide in visibility reduction, J. Air Poll. Control Assoc. 15, 218–221 (1965).
Stephens, E., Smog aerosol: Infrared spectra, Science 168, 584–1586 (1970).
Johnston, H. F., and Conghanowr, D. R., Absorption of sulfur dioxide from air oxidation in drops containing dissolved catalyst, Ind. Eng. Chem. 50, 1169–72 (1958).
Junge, C. E., and Ryan, T. G., Study of the S02 oxidation in solution and its role in atmospheric chemistry, Quart. J. Roy. Meteor. Soc. 84, 46–56 (1958).
Van den Heuvel, A. P., and Mason, B. J., The formation of ammonium sulfate in water droplets exposed to gaseous sulfur dioxide and ammonia, Quart. J. Roy. Meteor. Soc. 89, 271–275 (1963).
Scott, W. D., and Hobbs, P. V., The formation of sulfate in water droplets, J. Atmos. Sci. 24, 54–57(1967).
Terraglio, F. P., and Manganelli, R. M., The absorption of atmospheric sulfur dioxide by water solutions, J. Air Poll. Control Assoc. 17, 403–406 (1967).
Miller, J. M., and de Pena, R. G., The rate of sulfate ion formation in water droplets in atmospheres with differential partial pressures of S02, in “Proc. of the 2nd IUAPPA Clean Air Congress, Washington, D.C., December 1970,” Academic Press, New York, 1971, pp. 375–378.
Georgii, H. W., Contribution to the atmospheric sulfur budget, J. Geophys. Res. 75, 2365– 2372(1970).
Urone, P., Schroeder, W. H., and Miller, S. R., Reactions of sulfur dioxide in air, in “Proc. 2nd IUAPPA Clean Air Congress, Washington, D.C., December 1970,” Academic Press, New York, 1971, pp. 370–374.
Friedlander, S. K., The characterization of aerosols distributed with respect to size and chemical composition, Aerosol Science 1, 295–307 (1970).
Hidy, G. M., The Dynamics of aerosols in the lower troposphere in assessment of airborne particles, The Dynamics of aerosols in the lower troposphere in assessment of airborne particles, “Proc. 3rd Univ. of Rochester Conf. on Environ. Toxicology,” C. C. Thomas, Springfield, 111., 1972, pp. 81–115.
Chamberlain, A. C., Radioactive aerosols and vapors, Contemporary Phys. 8, 561–581 (1967).
Langer, G., Particle deposition and reentrainment from coniferous trees, Part II, Kolloid Z. 204, 119–124(1965).
Rosinski, J., and Nagamoto, C. T., Particle deposition on and reentrainment from coniferous trees, Part I, Kolloid Z. 204, 111–119 (1965).
Neuberger, H., Hosier, C. L., and Kocmond, W. C., Vegetation as an aerosols filter, in “Biometeorology,” Proc. 3rd Int. Biometeor. Congr., Pau, France, S. W. Tramp, and W. H. Weike, ed., 1967, part 2, pp. 693–702.
Saffman, P. G., and Turner, J. S., On the collision of drops in turbulent clouds, J. Fluid Mech. 1, 16–30 (1956).
Friedlander, S. K., The similarity theory of the particle size distribution of the atmospheric aerosols, in “Aerosols, Phys. Chemistry and Appl.” K. Spurny, ed., Czechoslovak Acad. Sci., Prague, 1964, pp. 115–130.
Davis, M. H., and Sartor, J. D., Theoretical collision efficiencies for small cloud droplets in stokes flow, Nature 215, 1371–1372 (1967).
Sartor, J. D., Accretion rates of cloud drops, raindrops, and small hail in mature thunderstorms, J. Geophys. Res. 75, 7547–7558 (1970).
Rosinski, J., and Kerrigan, T. C., The role of aerosol particles in the formation of raindrops and hailstones in severe thunderstorms, J. Atmos. Sci. 26, 695–715 (1969).
Zebel, G., Capture of small particles by drops falling in electric fields, J. Colloid and Interface Sci. 27, 294–304 (1968).
Slinn, W. G. N., and Hales, J. M., Thermophoretic influences, in “Precipitation Scavenging,” AEC Symposium Series No. 22 U. S. Atomic Energy Commission, Oak Ridge, Tenn., 1970, pp. 411–424.
Slinn, W. G. N., Precipitation scavenging of submicron particles. Part A—Theory, in “Proc. USAEC Meteorological Information Meeting,” AECL-2787, 527–520, Chalk River Laboratories, Chalk River, Ontario, 1967.
Lumley, J., and Panofsky, H., “The Structure of Atmospheric Turbulence,” Wiley-Interscience, New York, 1964, p. 123.
Fletcher, N. H., “The Physics of Rainclouds,” Cambridge Univ. Press, 1966.
Brock, J. R., On size distributions of atmospheric aerosol, Atmos. Environment 5, 833–842 (1971).
Hidy, G. M., On the theory of the coagulation of noninteracting particles in Brownian motion, J. Colloid Sci. 20, 123 (1965).
Friedlander, S. K., and Wang, C. S., The self-preserving particle size distribution for coagulation by Brownian motion, J. Colloid and Interface Sci. 22, 126–132 (1966).
Lai, F., Friedlander, S. K., Pich, J., and Hidy, G. M. The self-preserving particle size distribution for Brownian coagulation in the free-molecule regime, submitted to J. Colloid and Interface Sci. 39, 395–405 (1972).
Pich, J., Friedlander, S. K., and Lai F. S. The self-preserving particle size distribution for coagulation by Brownian motion. III. Smoluchowski coagulation and simultaneous Maxwellian condensation, Aerosol Sci. 1, 115–126 (1970).
Junge, C. E., Comments on “Concentration and size distribution measurements of atmospheric aerosols and a test of the theory of self-preserving size distributions,” J. Atmos. Sci. 26, 603–607 (1969).
Thiele, E. W., Relation between catalytic activity and size of particle, Industr. Eng. Chem. 31,916–920(1939).
Moller, U., and Schumann, G., Mechanisms of transport from the atmosphere to the Earth’s surface, J. Geophys. Res. 75, 3013–3019 (1970).
Wagman, J., Lee, R. E., and Axt, C. J., Influence of some atmospheric variables on the concentration and particle size distribution of sulfate in urban air, Atmos. Environ. 1, 479– 489(1967).
Ludwig, F. L., and Robinson, E., Variations in the size distributions of sulfur-containing compounds in ruban aerosols, Atmos. Environ. 2, 13–23 (1968).
Lee, R. E., and Patterson, R. K., Size determination of atmospheric phosphate, nitrate, chloride, and ammonium particulate in several urban areas, Atmos. Environ. 3, 249–255 (1969).
Blifford, I. H., Jr., and Ringer, L., The size and number distribution of aerosols in the continental troposphere, J. Atmos. Sci. 26, 716–726 (1969).
Weickmann, H., Recent measurements of the vertical distribution of Aitken nuclei, in “Artificial Stimulation of Rain,” Proc. 1 st Conf. Phys. of Clouds and Precipitation Particles, H. Weickmann and W. Smith, eds., Pergamon Press, New York, 1955, pp. 81–88.
Selezneva, E. S., The main features of condensation nuclei distribution in the free atmosphere over the European territory of the USSR, Tellus 18, 525–531 (1966).
Meszaros, A., Vertical profile of large and giant particles in the lower troposphere, in “Proc. 7th Intl. Conf. Condensation and Ice Nuclei,” Prague-Vienna, 1969, pp. 364–368.
Sood, S. K., and Jackson, Y. M. R., Scavenging by snow and ice crystals, in “Precipitation Scavenging” AEC Symposium Series No. 22, U.S. Atomic Energy Commission, Oak Ridge, Tenn., 1970, pp. 121–136.
Hidy, G. M., and Brock, J. R., Some remarks about the coagulation of aerosol particles by Brownian motion, J. Colloid Sci. 20, 477–491 (1965).
Hidy, G. M., “The Wind: The Origin and Behavior of Atmospheric Motion,” Van Nostrand, New York, 1967.
Munn, R. E., “Descriptive Micrometeorology,” Academic Press, New York, 1966.
Niki, H., Daby, E. E., and Weinstock, B., Mechanisms of smog reactions, to be published in “Advances in Chemistry,” American Chemical Society, Washington, D.C., 1972.
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Hidy, G.M. (1973). Removal Processes of Gaseous and Particulate Pollutants. In: Rasool, S.I. (eds) Chemistry of the Lower Atmosphere. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1986-3_3
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DOI: https://doi.org/10.1007/978-1-4684-1986-3_3
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