Advertisement

Characterization of Diene Polymer Microstructure by Olefin-Polymer Metathesis

  • Lubomir Michajlov
  • H. James Harwood
Conference paper

Abstract

The classical approach for elucidating structures of organic substances involves degradation followed by separation and quantitative analysis of the degradation products. Quantitative evaluation of degradation fragments obtained from the selective degradation of copolymers provides valuable information about their structures (1–3).

Keywords

Copolymer Composition Anionic Polymerization Metathesis Reaction Relative Response Factor Styrene Content 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    J. Schaefer, R. J. Kern and R. S. Katnik, Macromolecules, 1, 107 (1968).CrossRefGoogle Scholar
  2. 2.
    K. Tada, T. Saegusa, and J. Furukawa, Makromol. Chem., 102, 47 (1967).CrossRefGoogle Scholar
  3. 3.
    C. S. Marvel and H. E. Baumgarten, in “Synthetic Rubber,” Chapter 9, edited by G. S. Whitby, Wiley, New York, 1954.Google Scholar
  4. 4.
    N. Calderon, H. Y. Chen, and K. W. Scott, (a) Tetrahedron Letters, 34, 3327 (1967): (b) Chem. Eng. News, 45, 51 (1967).Google Scholar
  5. 5.
    N. Calderon, E. A. Ofstead, J. P. Ward, W. A. Judy, and K. W. Scott, J. Amer. Chem. Soc., 90, 4133 (1968).CrossRefGoogle Scholar
  6. 6.
    J. L. Wang and H. R. Menapace, J. Org. Chem., 33, 3794 (1968).Google Scholar
  7. 7.
    E. A. Zuech, W. B. Hughes, D. H. Kubicek, and E. T. Kittleman, J. Amer. Chem. Soc., 92, 528 (1970).CrossRefGoogle Scholar
  8. 8.
    W. B. Hughes, J. Amer. Chem. Soc., 92, 532 (1970).CrossRefGoogle Scholar
  9. 9.
    M. Fineman and S. D. Ross, J. Polym. Sci., 259 (1950).Google Scholar
  10. 10.
    W. L. Senn, Anal. Chim. Acta, 29, 505 (1963).CrossRefGoogle Scholar
  11. 11.
    R. Kaiser, in “Chromatographie in der Gasphase, IV,” B-I-Hochschultaschenbuecher-Verlag, Mannheim, 1965.Google Scholar

Copyright information

© Plenum Press, New York 1971

Authors and Affiliations

  • Lubomir Michajlov
    • 1
  • H. James Harwood
    • 1
  1. 1.Institute of Polymer ScienceThe University of AkronAkronUSA

Personalised recommendations