Abstract
It has been a little over 5 years since the first pulsed chemical laser was developed by Kasper and Pimentel (1). During this time, important advances have been made contributing to our understanding of the kinetic mechanisms by which population inversions can be created in chemically reacting gases. Much of this information comes to us from the pulsed chemical laser experiments of Airey, Gross, Moore, Pimentel, and others (2–10), and from the pioneering experimental and theoretical studies of infrared chemiluminescence by Polanyi and co-workers (11–13).
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References
J. V. V. Kasper and G. C. Pimentel, Phys. Rev. Letters, 14, 352 (1965).
J. Richard Airey, IEEE J. Quantum Electron, QE-3 208 (1967).
J. Richard Airey, J. Chem. Phys., 52, 156 (1970).
Rolf W. F. Gross, J. Chem. Phys., 50, 1889 (1969).
H. L. Chen, J. C. Stephenson, and C. Bradley Moore, Chem. Phys. Letters, 2, 593 (1968).
C. Bradley Moore, IEEE J. Quantum Electron, QE-4, 52 (1968).
P. H. Cornell and G. C. Pimentel, J. Chem. Phys., 49, 1379 (1968).
K. L. Kompa, J. H. Parker, and G. C. Pimentel, J. Chem. Phys., 49, 4257 (1968).
J. H. Parker and G. C. Pimentel, J. Chem. Phys., 51, 91 (1969).
The atom exchange reaction, O + CS → CO + S, is believed to be responsible for the chemical laser emission from CO observed with the O2/CS2 system. See, for example: G. Hancock and I. W. M. Smith, Chem. Phys. Letters, 3, 573 (1969)
C. Wittig, J. C. Hassler, and P. C. Coleman, Appl. Phys. Letters, 16, 117 (1970).
K. G. Anlauf, P. J. Kuntz, D. H. Maylotte, P. D. Pacey, and J. C. Polanyi, Discussions Faraday Soc., 44, 183 (1967).
J. C. Polanyi and W. H. Wong, J. Chem. Phys., 51, 1439 (1969).
M. H. Mok and J. C. Polanyi, J. Chem. Phys., 51, 1451 (1969).
D. J. Spencer, T. A. Jacobs, H. Mirels, and R. W. F. Gross, Int. J. Chem. Kinetics, 1, 493 (1969).
T. A. Cool, R. R. Stephens, and T. J. Falk, Int. J. of Chem. Kinetics, 1, 495 (1969).
J. R. Airey and S. F. McKay, Appl. Phys. Letters, 15, 401 (1969).
D. J. Spencer, H. Mirels, and T. A. Jacobs, Appl. Phys. Letters 16, 384 (1970)
M. A. Kwok, R. R. Giedt and R. W. F. Gross, Appl. Phys. Letters, l6, 386 (1970).
T. A. Cool, J. A. Shirley, and R. R. Stephens, “Operating Characteristics of a Transverse Flow DF-CO2 Purely Chemical Laser” (to be published) Appl. Phys. Letters.
T. A. Cool and R. R. Stephens, J. Chem. Phys., 51, 5175 (1969)
T. A. Cool and R. R. Stephens, Appl. Phys. Letters, 16, 55 (1970).
T. A. Cool, T. J. Falk, and R. R. Stephens, Appl. Phys. Letters, 15, 318 (1969).
T. A. Cool and R. R. Stephens, J. Chem. Phys., 52, 3304 (1970).
T. A. Cool, R. R. Stephens, and J. A. Shirley, “HCl, HF, and DF Partially Inverted cw Chemical Lasers” (to be published) J. Appl. Phys. The HCl cw Chemical Laser was also reported at the 1970 A.P.S. Meeting, see Bull. Am. Phys. Soc, 15, 355 (1970).
D. Naegli and C. J. Ultee, “A cw HCl Chemical Laser” (to be published) Chem. Phys. Letters.
C. Wittig, J. C. Hassler, and P. D. Coleman, “CW Laser Oscillation in a Carbon Monoxide Chemical Laser”, Nature, 226, 845 (1970).
R. D. Suart, G. H. Kimbell, and S. J. Arnold, Chem. Phys. Letters, 5, 519 (1970).
See for example, M. J. Berry and G. C. Pimentel, J. Chem. Phys. 51, 2274 (1968).
J. C. Polanyi, Appl. Opt. Suppl. 2, Chemical Lasers, pp. 109–127 (1965).
K. G. Anlauf, D. H. Maylotte, P. D. Pacey, and J. C. Polanyi, Phys. Letters, 24A, 208 (1967).
T. A. Cool, Appl. Phys. Letters, 9, 418 (1966).
T. A. Cool and J. A. Shirley, Appl. Phys. Letters, 14, 70 (1969).
The HCl-CO2, HF-CO2, DF-CO2 and HBr-CO2 chemical lasers operated on the P(l8) transition at 10.57 μ. The HF, DF, and HCl chemical lasers operated on a variety of P-branch transitions, see ref. 22. A large amount of helium vas needed for the HF, DF, and HCl lasers (Table III) to keep the rotational temperature low (300°K).
C. K. Rhodes, M. J. Kelley, and A. Javan, J. Chem. Phys., 48, 5730 (1968).
C Bradley Moore, Accounts of Chem. Research, 2, 103 (1969).
W. A. Rosser, A. D. Wood, and E. T. Gerry, J. Chem. Phys., 50, 4996 (1969).
V. Daneu, D. Sokoloff, A. Sanchez, and A. Javan, Appl. Phys. Letters, 15, (1969).
R. A. Meinzer, “A Continuous-wave Combustion Laser”, to be published, Int. J. of Chem. Kinetics.
O. M. Batovskii, G. K. Vasil’ev, E. F. Makarov, and V. L. Tal’roze, ZhETF Pis. Red., 9, 341, (1969)
O. M. Batovskii, G. K. Vasil’ev, E. F. Makarov, and V. L. Tal’roze Sov. Phys. — JETP Lett., 9, 375 (1969).
N. G. Basov, L. V. Kulakov, E. P. Markin, A. I. Nikitin, and A. N. Oraevskii, ZhETF Pis, Red., 9, 6l3 (1969)
N. G. Basov, L. V. Kulakov, E. P. Markin, A. I. Nikitin, and A. N. Oraevskii Sov. Phys. -JETP Lett., 9, 375 (1969).
J. R. Bowen and K. A. Overholser, Astronautica Acta, 14, 475 (1969).
T. A. Cool, “Fluid Mixing Lasers”, NASA Conference on Gas Lasers, NASA Hdqts., Washington D. C. 15–16 July 1968.
R. W. F. Gross, R. R. Geidt, and T. A. Jacobs, J. Chem. Phys., 51, 1250 (1969).
R. A. Gross, and J. A. Nicholls, “Stationary Detonation Waves”, Combustion and Propulsion, 169–177, Fourth AGARD Coll. London: Pergamon, (1961).
R. A. Gross and W. Chinitz, “A Study of Supersonic Combustion”, J. Aerospace Sciences, 27, 517–524, 534, (1960).
J. A. Nicholls, E. K. Dabora, and R. L. Gealer, “Studies in Connection with Stabilized Gaseous Detonation Waves”, Seventh Symposium on Combustion, 144–150, Butterworth, London,(1958).
G. A. Kapralova, E. M. Trofimova, and A. E. Shilov, Kinetika i Kataliz, 6, 977 (1965)
G. A. Kapralova, E. M. Trofimova, and A. E. Shilov Sov, Chem. Kinetics and Catalysis, 6, 884 (1965).
D. W. Gregg, B. Krawetz, R. K. Pearson, B. R. Schleicher, S. J. Thomas, E. B. Huss, K, J. Pettipiece, and R. E. Niver, “Electron Beam Initiation of a Pulsed Chemical Laser” (to be published) Appl. Phys. Letters.
T. V. Jacobson and G. H. Kimbell, “A Transversely Spark Initiated Chemical Laser with High Pulse Energies”, (to be published) Appl. Phys. Letters.
See, for example, Physics Today, July, (1970), p. 55.
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Cool, T.A. (1971). A Summary of Recent Research on Continuous-Wave Chemical Lasers. In: Dosanjh, D.S. (eds) Modern Optical Methods in Gas Dynamic Research. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1923-8_12
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DOI: https://doi.org/10.1007/978-1-4684-1923-8_12
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