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Abstract

The most suitable method for the detection and identification of alcohols is the utilization of the reaction with 3,5-dinitrobenzoyl chloride; the reaction has been very thoroughly studied and it can be used in combination with paper chromatography for simultaneous detection and identification. As they serve for identification purposes, the esters of 3,5-dinitrobenzoic acid were prepared from a maximum number of alcohols. Another advantage consists in the possibility of preparing these derivatives even when the alcohols are available only in the form of their aqueous solutions.

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References

  1. Michalski E., Turowska, M.: Chem. Anal. (Warsaw) 5, 625 (1960).

    CAS  Google Scholar 

  2. Kartnig, T., and Kren, G.: Sci. Pharm. 31, 128 (1963).

    CAS  Google Scholar 

  3. Severin, M.: Bull. Reck. Agron. Gembloux 1, 298 (1966).

    Google Scholar 

  4. Spassow, A.: Ber. 70, 1926 (1937)

    Google Scholar 

  5. Spassow, A.: Ber. 75, 779 (1942).

    Google Scholar 

  6. Garska, K. J., Douthit, R. C., and Yarborough, V. A.: Anal. Chem. 33, 392 (1961).

    Article  CAS  Google Scholar 

  7. Douthit, R. C., Garska, K. J., and Yarborough, V. A.: Appl. Spectroscopy 17, 85 (1963).

    Article  CAS  Google Scholar 

  8. Saunders, B. C., Stacey G. J., and Wilding, I. G. W.: Biochem. J. 36, 368 (1942).

    CAS  Google Scholar 

  9. Gasparic, J., and Boreckÿ, J.: J. Chromatog. 5, 466 (1961).

    Article  CAS  Google Scholar 

  10. Severin, M.: J. Chromatog. 26, 101 (1967).

    Article  CAS  Google Scholar 

  11. Norris, J. F., and Haines, E. C.: J. Am. Chem. Soc. 57, 1425 (1935).

    Article  CAS  Google Scholar 

  12. Norris, J. F., Ashdown, A. A., and Cortese, F.: J. Am. Chem. Soc. 47, 837 (1925)

    Article  CAS  Google Scholar 

  13. Norris, J. F., Ashdown, A. A., and Cortese, F.: J. Am. Chem. Soc. 49, 2640 (1927).

    Article  CAS  Google Scholar 

  14. Pickard, R. H., and Kenyon, J.: J. Chem. Soc. 99, 45 (1911).

    Article  CAS  Google Scholar 

  15. Nicolet, B. H., and Sacks, J.: J. Am. Chem. Soc. 47, 2348 (1925).

    Article  CAS  Google Scholar 

  16. Dickinson, G. M., Crosson, L. H., and Copenhaver, J. E.: J. Am. Chem. Soc. 59, 1094 (1937).

    Article  CAS  Google Scholar 

  17. Teterin, V. K., and Zonis, S. A.: Zhur. Obshch. Khim. 6, 658 (1936).

    CAS  Google Scholar 

  18. Fessier, W. A., and Shriner, R. L.: J. Am. Chem. Soc. 58, 1384 (1936).

    Article  Google Scholar 

  19. Lefebvre, G., Berthelin, J., Maugras, M., Gay, R., and Urion, E.: Bull. Soc. chim. France 1966, 56, 266.

    Google Scholar 

  20. Dieckmann, W., Hoppe, J., and Stein, R.: Ber. 37, 4627 (1904).

    CAS  Google Scholar 

  21. Claisen, L.: Ann. 418, 69 (1919).

    CAS  Google Scholar 

  22. Neuberg, C., and Kansky, E.: Biochem. Z. 20, 445 (1909).

    Google Scholar 

  23. Shriner, R. L., and Cox, R. F. B.: J. Am. Chem. Soc. 53, 1601 (1931).

    Article  CAS  Google Scholar 

  24. Johnson, H. W., Jr. Day R. J., and Tinti, D. S.: J. Org. Chem. 28, 1416 (1963).

    Article  CAS  Google Scholar 

  25. Veibel, S., Lillelund, H., and Wangel, J.: Dansk. Tidskr. Farm. 17, 183 (1943).

    CAS  Google Scholar 

  26. Dubskÿ, J. V.: J. prakt. Chem. 93, (2) 142 (1916)

    Article  Google Scholar 

  27. Dubskÿ, J. V.: J. prakt. Chem. 103, 109 (1921).

    Article  Google Scholar 

  28. Lieser, T., and Nagel, W.: Ann. 495, 235 (1932).

    CAS  Google Scholar 

  29. Berger, J., and Uldall, I.: Acta Chem. Scand. 18, 1353 (1964).

    Article  CAS  Google Scholar 

  30. Seikel, M. K., and Huntress, E. H.: J. Am. Chem. Soc. 63, 593 (1941).

    Article  CAS  Google Scholar 

  31. Helferich, B., Moog, L., and Jünger, A.: Ber. 58, 872 (1925).

    Google Scholar 

  32. Hopkins, H. H.: J. Am. Chem. Soc. 45, 541 (1923).

    Article  CAS  Google Scholar 

  33. Meadoe, J. R., and Reid, E. E.: J. Am. Chem. Soc. 65, 457 (1943).

    Article  Google Scholar 

  34. Böhme, H., and Opfer, H.: Z. anal Chem. 139, 255 (1953).

    Article  Google Scholar 

  35. Wienhaus, H.: Ber. 47, 322 (1914).

    CAS  Google Scholar 

  36. Wienhaus, H., and Treibs, W.: Ber, 56, 1648 (1923).

    Google Scholar 

  37. Agulhon, H.: Bull. Soc. chim. France (4) 9, 881 (1911).

    Google Scholar 

  38. Kellett, E. G.: Analyst 62, 728 (1937).

    Article  CAS  Google Scholar 

  39. Webb, D. A.: Sci. Proc. Roy. Dublin Soc. 21, 281 (1936).

    CAS  Google Scholar 

  40. Henry, L.: Bull. Acad. Belgique 1906, 45, 424

    Google Scholar 

  41. Henry, L.: Rec. tray chim 26, 116 (1907).

    CAS  Google Scholar 

  42. Hell, C., and Urech, F.: Ber. 15, 1249 (1882).

    Google Scholar 

  43. Doeuvre, J.: Bull. Soc. chim. France 39, (4) 1102 (1926).

    Google Scholar 

  44. Rosenthaler, L.: Pharm. Acta Helv. 27, 272 (1952).

    CAS  Google Scholar 

  45. Hartough, H. D.: Anal. Chem. 20, 860 (1948).

    Article  CAS  Google Scholar 

  46. Bielig, H. J., and Bayer, E.: Ann. 584, 96 (1953).

    Google Scholar 

  47. Deniges, G.: Compt. rend. 126, 1145 (1898)

    Google Scholar 

  48. Gasparic, J., and Boreckÿ, J.: J. Chromatog. 4, 138 (1960).

    Article  CAS  Google Scholar 

  49. Siegel, A., and Schlögl, K.: Mikrochim. Acta 40, 383 (1953).

    Article  CAS  Google Scholar 

  50. Woolfolk, E. O., Beach, F. E., and McPherson, S. P.: J. Org. Chem. 20, 391 (1955).

    Article  CAS  Google Scholar 

  51. Hecker, E.: Ber. 88, 1666 (1955).

    Article  CAS  Google Scholar 

  52. Freytag, W., and Baustian, M.: J. Chromatog. 13, 558 (1964).

    Article  CAS  Google Scholar 

  53. Boreckÿ, J., and Gasparic, J.: Collection Czech. Chem. Commun. 25, 1287 (1960).

    Google Scholar 

  54. Peyrot, P.: Chim. et Industrie 78, 3 (1957).

    CAS  Google Scholar 

  55. Tenney, H. M.: Proceedings of the Symp. Advances in Gas-Chromatog. Am. Chem. Soc., New York 1957.

    Google Scholar 

  56. Cropper, F. R., and Heywood, A.: Nature (London) 174, 1063 (1954).

    Article  CAS  Google Scholar 

  57. Ambrose, D., and Purnell, J. H.: Gas-Chromatography; Desty, D. H. (ed). Butter-worths Sci. Publ., London 1958.

    Google Scholar 

  58. Peyrot, P.: Chim. et Industrie 78, 3 (1957).

    CAS  Google Scholar 

  59. Haskin, J. F., Warken, G. W., Pristley, L. J., and Yarborough, V. A.: Proceedings of the Symp. Advances in Gas-Chromatog. Am. Chem. Soc., New York 1957.

    Google Scholar 

  60. Bayer, E.: Gas-Chromatographie. Springer, Berlin-Göttingen-Heidelberg 1959.

    Google Scholar 

  61. Bober, H.: Beckman Ref. 2, 17 (1965).

    Google Scholar 

  62. Smith, G. F.: Analytical Applications of Periodic Acid and Iodic Acid and Their Salts, 5th Ed. Smith Chemical Comp., Columbus, Ohio, 1950.

    Google Scholar 

  63. Fleury, P. F.: Chim. anal. 35, 197 (1953).

    CAS  Google Scholar 

  64. McCasland, G. E., and Smith, D. A.: J. Am. Chem. Soc. 73, 5164 (1951).

    Article  CAS  Google Scholar 

  65. Criegee, R.: Ber. 64, 260 (1931)

    Google Scholar 

  66. Criegee, R.: Angew. Chem. 53, 321 (1940).

    Article  CAS  Google Scholar 

  67. Criegee, R., Büchner, E., and Walther, W.: Ber. 73, 571 (1940).

    Google Scholar 

Download references

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© 1971 Miroslav Večeřa and Jiří Gasparič

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Večeřa, M., Gasparič, J. (1971). Alcohols. In: Detection and Identification of Organic Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1833-0_9

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  • DOI: https://doi.org/10.1007/978-1-4684-1833-0_9

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