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Thermodynamic Properties of Bi2Te3, Bi2Se3, Sb2Te3, and Sb2Se3

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Chemical Bonds in Solids

Abstract

The liquid-electrolyte emf method was used to determine the values of ΔGT, ΔHT, and ΔST of Bi2Te3, Bi2Se3, Sb2Te3, and Sb2Se3 at temperatures of 503–533, 553–583, 530–560, and 430–485°K, respectively. The published (Se, Te, Bi, Sb, and Bi2Te3) and calculated (Bi2Se3, Sb2Se3, Sb2Te3) temperature dependences of the specific heat were employed to calculate the changes in the isobaric-isothermal potential, enthalpy, and entropy associated with the formation of Bi2Te3, Bi2Se3, Sb2Te3, and Sb2Se3 from their components. The Karapet’yants-Lauthier comparative calculation method was used to estimate the enthalpies of formation of BiTes (−8 kcal/mole), BiSes (−14.7 kcal/mole), and SbTes (−5.8 kcal/mole).

“Crystals,” pp. 277–281 (see page 3).

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Authors
  1. S. A. Semenkovich
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  2. B. T. Melekh
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Editor information

Editors and Affiliations

  1. Institute of Solids and Semiconductors, Academy of Sciences of the Belorussian SSR, Minsk, USSR

    N. N. Sirota

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© 1972 Consultants Bureau, New York

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Semenkovich, S.A., Melekh, B.T. (1972). Thermodynamic Properties of Bi2Te3, Bi2Se3, Sb2Te3, and Sb2Se3 . In: Sirota, N.N. (eds) Chemical Bonds in Solids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1686-2_27

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  • DOI: https://doi.org/10.1007/978-1-4684-1686-2_27

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-1688-6

  • Online ISBN: 978-1-4684-1686-2

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