Layered Cuprates with Double Copper Layers: Relationships Between Structure, Nonstoichiometry and Superconductivity

  • B. Raveau
  • C. Michel
  • J. Provost
  • M. Hervieu
  • D. Groult
Part of the NATO ASI Series book series (NSSB, volume 253)

Abstract

Layered cuprates with double copper layers form a rather large family which appears as very promising for superconductivity at high temperature. The structure of those phases, the nonstoichiometry phenomena, especially extended defects observed by high resolution electron microscopy and oxygen nonstoichiometry are presented here. The relationships between those structural features and the superconducting properties of those materials are discussed.

Many superconductive layered cuprates have been synthesized since the beginning of 1987. In spite of the variety of their chemical compositions, all those materials belong to the same structural family. They consist of an intergrowth of multiple oxygen deficient perovskite layers (p) with multiple rock salt-type layers (r.s) according to the general formula (ACuO3-x) m p (AO) n r.s where m and n are the number of Cu-O and AO planes respectively. They can also be represented by the symbol [m,n]. The rock salt slabs are, in fact, built up from n + 1 planes: (n — 1) AO planes sandwiched by 2 AIIO planes (AII = Ba, Sr) which ensure the junction between the two structures. Thus, the structural principles which allow these phases to be synthesized appear as very simple, taking into consideration the fact that besides the two-dimensional character of the structure, the mixed valency of copper Cu(II)-Cu(III), should be introduced in order to create hole carriers on the copper-oxygen framework. In reality, the physics and chemistry of those materials are more complex than expected. We present here some recent issues dealing with oxygen nonstoichiometry, extended defects, in connection with superconductivity and new structures in the m = 2-members, involving single rock salt layers.

Keywords

Vortex Zirconium Argon Barium Hull 

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References

  1. 1.
    N. Nguyen, L. Er-Rakho, C. Michel, J. Choisnet and B. Raveau, Mat. Res. Bull., 15: 891 (1980)CrossRefGoogle Scholar
  2. 2.
    F. Izumi, E. Takayama-Muromachi, Y. Nakai and H. Asano, Physica C., 157: 89 (1989)CrossRefGoogle Scholar
  3. 3.
    V. Caignaert, N. Nguyen and B. Raveau, Mat. Res. Bull., 25: 199 (1990)CrossRefGoogle Scholar
  4. 4.
    N. Nguyen, J. Choisnet and B. Raveau, Mat. Res. Bull., 17: 567 (1982)CrossRefGoogle Scholar
  5. 5.
    D.M. de Leeuw, C.A.H.A. Mutsaers, G.P.J. Geelen and C. Langereis, J. Solid State Chem., 80: 276 (1989)CrossRefGoogle Scholar
  6. 6.
    V. Caignaert, R. Retoux, M. Hervieu, C. Michel and B. Raveau, J. Solid State Chem., in pressGoogle Scholar
  7. 7.
    R.A. Steeman, D.M. de Leeuw, G.P.J. Geelen and E. Frikkee, Physica C., 162-164: 542 (1989)CrossRefGoogle Scholar
  8. 8.
    V. Caignaert, R. Retoux, C. Michel, M. Hervieu and B. Raveau, Physica C., 167: 483 (1990)CrossRefGoogle Scholar
  9. 9.
    S.S.P. Parkin, V.F. Lee, A.I. Nazzal, R. Savoy, T.C. Huang, G. Gorman and R. Beyers, Phys. Rev. B, 38: 6531 (1988)CrossRefGoogle Scholar
  10. 10.
    M. Hervieu, A. Maignan, C. Martin, C. Michel, J. Provost and B. Raveau, J. Solid State Chem., 75: 213 (1988)CrossRefGoogle Scholar
  11. 11.
    M.A. Subramanian, C.C. Torardi, J. Gopalakrishnan, P.L. Gai, J.C. Calabrese, T.R. Askew, R.B. Flippen and A.W. Sleight, Science, 242: 249 (1988)CrossRefGoogle Scholar
  12. 12.
    C. Martin, J. Provost, D. Bourgault, B. Domenges, C. Michel, M. Hervieu and B. Raveau, Physica C, 157: 460 (1989)CrossRefGoogle Scholar
  13. 13.
    C. Martin, D. Bourgault, C. Michel, M. Hervieu and B. Raveau, Modern Phys. Lett. B, 3: 93 (1989)CrossRefGoogle Scholar
  14. 14.
    A.K. Ganguli, R. Nagarajan, K.S. Nanjun Daswamy and C.N.R. Rao, Mat. Res. Bull., 24: 103 (1989)CrossRefGoogle Scholar
  15. 15.
    S. Nakajima, M. Kikuchi, N. Kobayashi, H. Iwasaki, D. Shindo, Y. Syono and Y. Mato, 2nd Int. Symp. on Superconductivity, Nov. 14-17, Tsukuba, Ibaraki, Japan (1989)Google Scholar
  16. 16.
    C.N.R. Rao, A.K. Ganguli and R. Vijayaraghavan, Phys. Rev. B, 40: 2565 (1989)CrossRefGoogle Scholar
  17. 17.
    R. Vijayaraghavan, A.K. Ganguli, N.Y. Vasanthacharya, M.K. Rajumon, G.V. Kulkarni, G. Sankar, D. Sarma, A.K. Sood, N. Chandrabhas and C.N.R. Rao, Supercond. Sci. Techno1., 2: 195 (1989)CrossRefGoogle Scholar
  18. 18.
    R.M. Hazen, D.W. Finger, R.J. Angel, C.T. Prewitt, N.L. Ross, C.G. Adidiacos, P.J. Heaney, D.R. Veblen, Z.Z. Sheng, A. El Ali and A.M. Hermann, Phys. Rev. Lett., 60: 1657 (1988)CrossRefGoogle Scholar
  19. 19.
    M.A. Subramanian, J.C. Calabrese, C.C. Torardi, J. Gopalakrishnan, T.R. Askew, R.B. Flippen, K.J. Morrissey, U. Chowdhry and A.W. Sleight, Nature, 332: 420 (1988)CrossRefGoogle Scholar
  20. 20.
    S.S.P. Parkin, V.Y. Lee, E.M. Engler, A.I. Nazzal, T.C. Huang, G. Gorman, R. Savoy and R. Beyers, Phys. Rev. Lett., 60: 1539 (1988)CrossRefGoogle Scholar
  21. 21.
    C. Politis and H. Luo, Modern Physics Lett. B, 2: 793 (1988)CrossRefGoogle Scholar
  22. 22.
    A. Maignan, C. Michel, M. Hervieu, C. Martin, D. Groult and B. Raveau, Modern Physics Lett. B, 2: 681 (1988)CrossRefGoogle Scholar
  23. 23.
    E.A. Hayri and M. Greenblatt, Physica C., 156: 775 (1988)CrossRefGoogle Scholar
  24. 24.
    D. Bourgault, C. Martin, C. Michel, M. Hervieu and B. Raveau, Physica C., 158: 511 (1989)CrossRefGoogle Scholar
  25. 25.
    T. Rouillon, J. Provost, M. Hervieu, D. Groult, C. Michel and B. Raveau, Physica C, 159: 201 (1989)CrossRefGoogle Scholar
  26. 26.
    T. Rouillon, J. Provost, M. Hervieu, D. Groult, C. Michel and B. Raveau, J. Solid State Chem., 84: 375 (1990)CrossRefGoogle Scholar
  27. 27.
    T. Rouillon, A. Maignan, M. Hervieu, C. Michel and B. Raveau, Physica C., in pressGoogle Scholar
  28. 28.
    M. Maeda, Y. Tanaka, M. Fukutoni and T. Asano, Jpn. J. Appl. Phys. Lett., 27: L209, L548 (1988)CrossRefGoogle Scholar
  29. 29.
    R.M. Hazen, C.T. Prewitt, R.J. Angel, N.L. Ross, L.W. Finger, C.G. Hadidiacos, D.R. Veblen, P.J. Heaney, P.H. Hor, R.L. Meng, N.Y. Sun, Y.Q. Wang, Y.Y. Sue, Z.J. Huang, L. Gao, J. Bechtold and C.W. Chu, Phys. Rev. Lett., 60: 1174 (1988)CrossRefGoogle Scholar
  30. 30.
    M.A. Subramanian, C.C. Torardi, J.C. Calabrese, J. Gopalakrishnan, T.R. Askew, R.B. Flippen, K.J. Morrissey, U. Chowdhry and A.W. Sleight, Science, 239: 1015 (1988)CrossRefGoogle Scholar
  31. 31.
    S.A. Sunshine, T. Siegrist, L.F. Schneemeyer, D.W. Murphy, R.J. Cava, B. Batlogg, R.B. Van Dover, R.M. Fleming, S.H. Glarum, S. Nakara, R. Farrow, J.J. Krajewski, S.M. Zahurak, J.V. Vaszczak, J.H. Marshall, P. Marsh, L.W. Rupp and W.F. Peck, Phys. Rev. B, 38: 893 (1988)CrossRefGoogle Scholar
  32. 32.
    J.M. Tarascon, Y. Lepage, P. Bardoux, B.G. Bagley, L.H. Greene, W.R. McKinnon, G.W. Hull, M. Giroud and D.M. Hwang, Phys. Rev. B, 37: 9382 (1988)CrossRefGoogle Scholar
  33. 33.
    M. Hervieu, C. Michel, B. Domenges, Y. Laligant, A. Lebail, G. Ferey and B. Raveau, Modern Phys. Lett. B, 2: 491 (1988)CrossRefGoogle Scholar
  34. 34.
    P. Bordet, J.J. Capponi, C. Chaillout, J. Chenavas, A.W. Hewat, E.A. Hewat, J.L. Hodeau, M. Marezio, J.L. Tholence and D. Tranqui, Physica C, 153-155: 623 (1988)CrossRefGoogle Scholar
  35. 35.
    T. Kajitani, K. Kusaba, M. Kibuchi, N. Kobayashi, Y. Syono, T.B. Williams and M. Hirabayashi, Jpn. J. Appl. Phys. Lett., 27: L587 (1988)CrossRefGoogle Scholar
  36. 36.
    H.G. von Schnering, L. Walz, M. Schwartz, W. Beker, M. Hartweg, T. Popp, B. Hettlich, P. Müller and G. Kämpf. Angew. Chem., 27: 574 (1988)CrossRefGoogle Scholar
  37. 37.
    R. Retoux, V. Caignaert, J. Provost, C. Michel, M. Hervieu and B. Raveau, J. Solid State Chem., 75: 157 (1989)CrossRefGoogle Scholar
  38. 38.
    M. Hervieu, C. Michel, A. Maignan, C. Martin and B. Raveau, J. Solid State Chem., 74: 428 (1988)CrossRefGoogle Scholar
  39. 39.
    M. Hervieu, C. Martin, J. Provost and B. Raveau, J. Solid State Chem., 76: 419 (1988)CrossRefGoogle Scholar
  40. 40.
    M. Hervieu, B. Domenges, C. Michel and B. Raveau, Modern Phys. Lett. B, 2: 835 (1988)CrossRefGoogle Scholar
  41. 41.
    G. van Tandeloo, H.W. Zandbergen, J. van Landuyt and S. Amelinckx, Appl. Phys. A, 46: 233 (1988)CrossRefGoogle Scholar
  42. 42.
    T. Kijima, J. Tamaka, Y. Bando, M. Onoda and F. Izuni, Jpn. J. Appl. Phys., 27: L369 (1988)CrossRefGoogle Scholar
  43. 43.
    E.A. Hewat, P. Bordet, J.J. Capponi, C. Chaillout, J.L. Hodeau and M. Marezio, Physica C., 153-155: 619 (1988)CrossRefGoogle Scholar
  44. 44.
    M. Hervieu, C. Michel, N. Nguyen, R. Retoux and B. Raveau, Europ. J. solid State Inorg. Chem., 25: 375 (1988)Google Scholar
  45. 45.
    R. Retoux, C. Michel, M. Hervieu, N. Nguyen and B. Raveau, Solid State Comm., 69: 599 (1989)CrossRefGoogle Scholar
  46. 46.
    B. Morosin, R.J. Banghman, D.S. Ginley, J.E. Schirberand and E.L. Venturini, Physica C, 161: 115 (1990)CrossRefGoogle Scholar
  47. 47.
    Y. Kubo, Y. Shimikawa, T. Manako, T. Sato, S. Ijima, T. Ichihashi and H. Igarashi, Physica C, 162-164: 991 (1989)CrossRefGoogle Scholar
  48. 48.
    K.V. Ramanujachary, S. Li and M. Greenblatt, Physica C., 165: 377 (1990)CrossRefGoogle Scholar
  49. 49.
    I.K. Gopalakrishnan, P. Sastry, H. Rajagpal, A. Saqueira, J.V. Yakümi and R.M. Iyer, Physica C, 159: 811 (1989)CrossRefGoogle Scholar
  50. 50.
    A. Schilling, H.R. Ott and F. Hulliger, Physica C, 157: 144 (1989)CrossRefGoogle Scholar
  51. 51.
    C. Martin, A. Maignan, J. Provost, C. Michel, M. Hervieu, R. Tournier and B. Raveau, Physica C, 168: 8 (1990)CrossRefGoogle Scholar
  52. 52.
    Y. Shimikawa, Y. Kubo, T. Manako, T. Satoh, S. Ijima, T. Ichiashi and H. Igarashi, Pysica C, 157: 279 (1989)CrossRefGoogle Scholar
  53. 53.
    A. Sulpice, B. Giordamengo, R. Tournier, M. Hervieu, A. Maignan, C. Martin, C. Michel and J. Provost, Physica C., 156: 243 (1988)CrossRefGoogle Scholar
  54. 54.
    J.J. Capponi, C. Chaillout, A.W. Hewat, P. Lejay, M. Marezio, N. Nguyen, B. Raveau, J.L. Tholence and R. Tournier, Europhysics Lett., 3: 1301 (1987)CrossRefGoogle Scholar
  55. 55.
    R.J. Cava, B. Batlogg, R.B. van Dover, J.J. Krakewski, J.V. Waszczak, R.M. Fleming, W.F. Peck Jr., L.W. Ruppo Jr., P. Marsh, A.C.W.P. James, L.F. Schneemeyer, Nature, 345: 602 (1990)CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1991

Authors and Affiliations

  • B. Raveau
    • 1
  • C. Michel
    • 1
  • J. Provost
    • 1
  • M. Hervieu
    • 1
  • D. Groult
    • 1
  1. 1.Laboratoire de Cristallographie et Sciences des Matériaux, CRISMAT, ISMRAUniversité de CaenCaen CedexFrance

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