Abstract
Tunneling spectroscopy is a sensitive technique for measuring the vibrational spectra of molecules. It was discovered by Jaklevic and Lambe(1, 2) in 1966.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Similar content being viewed by others
References
R. C. Jaklevic and J. Lambe, Molecular vibration spectra by electron tunneling, Phys. Rev. Lett. 17, 1139–1140 (1966).
J. Lambe and R. C. Jaklevic, Molecular vibration spectra by inelastic electron tunneling, Phys. Rev. 165, 821–832.
See, for example, C. J. Pouchert, The Aldrich Library of Infrared Spectra, Aldrich Chemical Co., Milwaukee (1970).
I. Shimanouchi, Tables of Molecular Vibrational Frequencies, Consolidated Volume I. National Standard Reference Data Series, National Bureau of Standards, U.S., No. 39 (1972).
M. Avram and GH. D. Mateescu, Infrared Spectroscopy, Wiley-Interscience, New York (1972).
L. J. Bellamy, The Infrared Spectra of Complex Molecules, John Wiley and Sons, New York (1975).
E. Maslowsky, Jr., Vibrational Spectra of Organometallic Compounds, Wiley-Interscience, New York (1977).
S. Colley and P. Hansma, Bridge for differential tunneling spectroscopy, Reu. Sci. Instrum. 48, 1192–1195 (1977).
J. Adler and R. Magno, unpublished.
J. D. Langan and P. K. Hansma, Can the concentration of surface species be measured with inelastic electron tunneling?, Surf. Sci. 52, 211–216 (1975).
A. A. Cederberg, Inelastic electron tunneling spectroscopy intensity as a function of surface coverage, Surf Sci. 103, 148–176 (1981).
R. M. Kroeker and P. K. Hansma, A measurement of the sensitivity of inelastic electron tunneling spectroscopy, Surf. Sci. 67, 362–366 (1977).
D. G. Walmsley, R. B. Floyd, and S. F. J. Read, Inelastic electron tunneling spectra lineshapes below 100 mK, J. Phys. C 11, L107 - L110 (1978).
N. I. Bogatina, Selection rules in tunnel spectroscopy for highly symmetrical molecules, Opt. Spectrosc. 38, 43–44 (1975).
N. I. Bogatina, I. K. Yanson, B. I. Verkin, and A. G. Batrak, Tunnel spectra of organic solvents, Soy. Phys.-JETP 38, 1162–1165 (1974).
O. I. Shklyarevskii, A. A. Lysykh, and I. K. Yanson, Tunnel spectra of carboxylic acids: The transition from physical absorption to chemisorption, Sov. J. Low Temp. Phys. 2. 328–333 (1976).
J. Kirtley, D. J. Scalapino, and P. K. Hansma, Theory of vibrational mode intensities in inelastic electron tunneling spectroscopy, Phys. Rec. B 14, 3177–3184 (1976).
N. M. D. Brown, R. B. Floyd, and D. G. Walmsley, Inelastic electron tunneling spectroscopy (IETS) of carboxylic acids and related systems chemisorbed on plasma-grown aluminum oxide-Part 1, J. Chem. Soc., Faraday Trans. 2 75, 17–31 (1979)
N. M. D. Brown, W. J. Nelson, and D. G. Walmsley, Inelastic electron tunneling spectroscopy (IETS) of carboxylic acids and related systems chemisorbed on plasma-grown aluminum oxide-Part 2, J. Chem. Soc., Faraday Trans. 2 75, 32–37 (1979).
J. T. Hall and P. K. Hansma, Chemisorption of monocarboxylic acids on alumina: A tunneling spectroscopy study, Surf. Sci. 76, 61–76 (1978).
J. T. Hall and P. K. Hansma, Adsorption and orientation of sulfonic acids on aluminum oxide: A tunneling spectroscopy study, Surf. Sci. 71, 1–14 (1978).
P. K. Hansma, D. A. Hickson, and J. A. Schwartz, Chemisorption and catalysis on oxidized aluminum metal, J. Catal. 48, 237–242 (1977).
A. F. Diaz, U. Hetler, and E. Kay, Inelastic electron tunneling spectroscopy of a chemically modified surface, J. Am. Chem. Soc. 99, 6780–6781 (1977).
N. K. Eib, A. N. Gent, and P. N. Henriksen, Formation of SiH bonds when SiO is deposited on alumina, J. Chem. Phys. 70, 4288–4290 (1979).
R. Kroeker, previously unpublished observation.
J. R. Kirtley and P. K. Hansma, Effect of the second metal electrode on vibrational spectra in inelastic-electron-tunneling spectroscopy, Phys. Rev. B 12, 531–536 (1975).
J. R. Kirtley and P. K. Hansma, Vibrational-mode shifts in inelastic electron tunneling spectroscopy: Effects due to superconductivity and surface interactions, Phys. Rev B 13, 2910–2917 (1976).
A. Bayman and P. K. Hansma, Shifts and dips in inelastic electron tunneling spectra due to the tunnel junction environment, Phys. Rev. Abst. 12, (1981).
K. W. Hipps and U. Mazur, An inelastic electron tunneling spectroscopy study of sonie iron cyanide complexes, J. Phys. Chem. 84, 3162–3172 (1980).
R. J. Jennings and J. R. Merrill, The temperature dependence of impurity-assisted tunneling, J. Phys. Chem. Solids 33, 1261 (1972).
J. Giaever, Electron tunneling and superconductivity, Rev. Mod. Phys. 46 245–250 (1974) (his Nobel Prize acceptance speech).
W. L. McMilland and J. Rowell, in Superconductivity (R. D. Parks, ed.), p. 561, Marcel Dekker, New York (1969).
R. V. Coleman, R. C. Morris, and J. E. Christopher, Methods of Experimental Physics VII. Solid State Physics (R. V. Coleman, ed. ), Academic Press (1974).
J. L. Miles and P. H. Smith, The formation of metal oxide films using gaseous and solid electrolytes, J. Electrochem. Soc. 110, 1240–1245 (1963).
R. Magno and J. G. Adler, Inelastic electron-tunneling study of barriers grown on aluminum, Phys. Rev. B 13, 2262–2269 (1976).
M. G. Simonsen and R. V. Coleman, Inelastic-tunneling spectra of organic compounds, Phys. Rev. B 8, 5875–5887 (1973).
P. K. Hansma and R. V. Coleman, Spectroscopy of biological compounds with inelastic electron tunneling, Science, 184, 1369–1371 (1974).
M. G. Simonsen, R. V. Coleman, and P. K. Hansma, High-resolution inelastic tunneling spectroscopy of macromolecules and adsorbed species with liquid-phase doping, J. Chem. Phys. 61, 3789–3799 (1974).
Y. Skarlatos, R. C. Barker, G. L. Haller, and A. Yelon, Detection of dilute organic acids in water by inelastic tunneling spectroscopy, Surf. Sci. 43, 353–368 (1974).
A. Bayman and P. K. Hansma, Inelastic electron tunneling spectroscopic study of lubrication, Nature 285, 97–99 (1980).
R. C. Jaklevic and M. R. Gaerttner, Electron tunneling spectroscopy-external doping with organic molecules, Appl. Phys. Lett. 30, 646–648 (1977).
R. C. Jaklevic and M. R. Gaerttner, Inelastic electron tunneling spectroscopy. Experiments on external doping of tunnel junctions by an infusion technique, Appl. Surf. Sci. 1, 479–502 (1978).
B. D. Wallace, Low power at ohmmeter’s probes allows safe usage on most sensitive components, Electron. Des. 14, 110 (1974).
D. E. Thomas and J. M. Rowell, Low-level second-harmonic detection system, Rev. Sci. Instrum. 36, 1301–1306 (1965).
J. G. Adler and J. E. Jackson, System for observing small nonlinearities in tunnel junctions. Rev. Sci. Instrum. 37, 1049–1054 (1966).
A. F. Hebard and P. W. Shumate, A new approach to high resolution measurements of structure in superconducting tunneling currents, Rev. Sci. Instrum. 45, 529–533 (1974).
S. Colley and P. K. Hansma, Bridge for differential tunneling spectroscopy, Rev. Sci. Instrum. 48, 1192–1195 (1977).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1982 Plenum Press, New York
About this chapter
Cite this chapter
Hansma, P.K. (1982). Introduction. In: Hansma, P.K. (eds) Tunneling Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1152-2_1
Download citation
DOI: https://doi.org/10.1007/978-1-4684-1152-2_1
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-1154-6
Online ISBN: 978-1-4684-1152-2
eBook Packages: Springer Book Archive