Skip to main content

Intermolecular Energy Transfer as a Means for the Characterization of Polymeric Lanthanide Complexes in Solution

  • Chapter
Metal-Containing Polymeric Systems

Abstract

A variety of physical methods exist for the characterization of polymeric materials in the solid state, but the range of techniques suited for the solution phase is more limited. A major consideration associated with inorganic or organometallic compounds in fluid solutions concerns the possible oligomerization of these species. Clear and unequivocal proof for the existence of a monomeric (or polymeric) species is definitely a desirable goal in any study which seeks to correlate solution phase structures with some experimental observable. In addition, any procedure which is capable of indicating the onset of polynuclear association will be of great value in characterization studies.

Teacher-Scholar of the Camille and Henry Dreyfus Foundation, 1980–85.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R. Prados, L. G. Stadtherr, H Donato Jr., and R. B. Martin, J. Inorg. Nucl. Chem., 36, 689 (1974).

    Article  CAS  Google Scholar 

  2. T. Forster, Ann. Phys., 2, 55 (1948).

    Article  CAS  Google Scholar 

  3. T. Forster, Z. Naturforsch., A4, 321 (1949).

    Google Scholar 

  4. D. L. Dexter, J. Chem. Phys., 21, 836 (1953).

    Article  CAS  Google Scholar 

  5. R. C. Powell and G. Blasse, Structure and Bonding, 42, 43 (1980).

    CAS  Google Scholar 

  6. R. Reisfeld, Structure and Bonding, 13, 53 (1973).

    CAS  Google Scholar 

  7. R. Reisfeld, Structure and Bonding, 30, 65 (1976).

    CAS  Google Scholar 

  8. R. Reisfeld and C. K. Jorgensen, “Lasers and Excited States of Rare Earths”, Springer-Verlag, New York, 1977, ch. 4.

    Book  Google Scholar 

  9. G. Blasse, Philips Res. Repts., 24, 131 (1969).

    CAS  Google Scholar 

  10. G. E. Peterson and P. M. Bridenbaugh, J. Opt. Sci. Am., 53., 494 (1963).

    Article  CAS  Google Scholar 

  11. P. K. Gallagher, A. Heller, and E. Wasserman, J. Chem. Phys., 41, 3921 (1964).

    Article  CAS  Google Scholar 

  12. W W. Holloway Jr. and M. Kestigan, J. Chem, Phys., 47, 1826 (1967).

    Article  CAS  Google Scholar 

  13. F. S. Quiring, J. Chem. Phys., 49, 2448 (1968).

    Article  CAS  Google Scholar 

  14. C. K. Luk and F. S. Richardson, J. Am. Chem. Soc, 97, 6666 (1975).

    Article  CAS  Google Scholar 

  15. H. G. Brittain and F. S. Richardson, Inorg. Chem., 15, 1507 (1976).

    Article  CAS  Google Scholar 

  16. G. D. R. Napier, J. D. Neilson, and T. M. Shepherd, J. Chem. Soc. Far. II, 71, 1487 (1975).

    Article  CAS  Google Scholar 

  17. J. D. Neilson and T. M. Shepherd, J. Chem. Soc. Far. II, 72, 557 (1976).

    Article  CAS  Google Scholar 

  18. H. G. Brittain and F. S. Richardson, J. Chem. Soc. Far. II, 73, 545 (1977).

    Article  CAS  Google Scholar 

  19. O. Stem and M. Volmer, Phys. Z., 20, 183 (1919).

    Google Scholar 

  20. J. N. Demas, J. Chem. Ed., 53, 657 (1976).

    Article  CAS  Google Scholar 

  21. H. Boaz and G. K. Rollefson, J. Am. Chem. Soc, 72, 3435 (1950).

    Article  CAS  Google Scholar 

  22. E. J. Bowen and W. S. Metcalf, Proc. Royal Soc. London Ser. A, 206, 437 (1951).

    Article  CAS  Google Scholar 

  23. J. Keizer, J. Am. Chem. Soc, 105, 1494 (1983).

    Article  CAS  Google Scholar 

  24. W. DeW. Horrocks Jr., and W. E. Collier, J. Am. Chem. Soc, 103, 2856 (1981).

    Article  CAS  Google Scholar 

  25. H. Donato Jr. and R. B. Martin, J. Am. Chem. Soc, 94, 4129 (1972)

    Article  CAS  Google Scholar 

  26. J. F. Desreux and C. N. Reilley, J. Am. Chem. Soc, 98, 2105 (1976).

    Article  CAS  Google Scholar 

  27. H. G. Brittain, Inorg. Chem., 17, 2762 (1978).

    Article  CAS  Google Scholar 

  28. H. G. Brittain, J. Inorg. Nucl. Chem., 41, 561, 567 (1979).

    Article  CAS  Google Scholar 

  29. H. G. Brittain and F. S. Richardson, Bioinorg. Chem., 7, 233 (1977).

    Article  CAS  Google Scholar 

  30. H. G. Brittain, Inorg. Chem., 18, 1740 (1979).

    Article  CAS  Google Scholar 

  31. H. G. Brittain and F. S. Richardson, Inorg. Chem., 15, 1507 (1976).

    Article  CAS  Google Scholar 

  32. H. G. Brittain, J. Inorg. Nucl. Chem., 41, 721 (1979).

    Article  CAS  Google Scholar 

  33. H. G. Brittain, J. Inorg. Nucl. Chem., 41, 1775 (1979).

    Article  CAS  Google Scholar 

  34. H. G. Brittain, J. Lumin., 21, 43 (1979).

    Article  CAS  Google Scholar 

  35. L. Spaulding and H. G. Brittain, J. Lumin., in press.

    Google Scholar 

  36. G. A. Elgavish and J. Reuben, J. Am. Chem. Soc, 98, 4755 (1976).

    Article  CAS  Google Scholar 

  37. L. Spaulding and H. G. Brittain, Inorg. Chem., 22, 3486 (1983).

    Article  CAS  Google Scholar 

  38. H. G. Brittain, Inorg. Chim. Acta, 70, 91 (1983).

    Article  CAS  Google Scholar 

  39. W. DeW. Horrocks Jr., B. Holmquist, and B. L. Vallee, Proc. Nat. Acad. Sci. USA, 72, 4764 (1975).

    Article  CAS  Google Scholar 

  40. V. G. Berner, D. W. Darnall, and E. R. Birnbaum, Biochem. Biophys. Res. Comm., 66, 763 (1975).

    Article  CAS  Google Scholar 

  41. P. M. Colman, J. N. Jansonius, and B. W. Matthews, J. Mol. Biol., 70, 701 (1972).

    Article  CAS  Google Scholar 

  42. B. W. Matthews, L. H. Weaver, and W. R. Kester, J. Biol. Chem., 249, 8030 (1974).

    CAS  Google Scholar 

  43. W. DeW. Horrocks Jr., M.-J. Rhee, A. P. Snyder, and D. R. Sudnick, J. Am. Chem. Soc, 102, 3650 (1980).

    Article  CAS  Google Scholar 

  44. M.-J. Rhee, D. R. Sudnick, V. K. Arkle, and W. DeW. Horrocks Jr., Biochem., 20, 3328 (1981).

    Article  CAS  Google Scholar 

  45. A. P. Snyder, D. R. Sudnick, V. K. Arkle, and W. DeW. Horrocks Jr., Biochem., 20, 3334 (1981).

    Article  CAS  Google Scholar 

  46. E. Banks, Y. Ueba, and Y. Okamoto, Ann. NY Acad. Sci., 366, 356 (1981).

    Article  CAS  Google Scholar 

  47. Y. Okamoto, Y. Ueba, N. F. Dzhanibekov, and E. Banks, Macromolecules, 14, 17 (1981).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1985 Plenum Press, New York

About this chapter

Cite this chapter

Brittain, H.G. (1985). Intermolecular Energy Transfer as a Means for the Characterization of Polymeric Lanthanide Complexes in Solution. In: Sheats, J.E., Carraher, C.E., Pittman, C.U. (eds) Metal-Containing Polymeric Systems. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-9415-4_25

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-9415-4_25

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-9417-8

  • Online ISBN: 978-1-4615-9415-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics