Abstract
There are various kinds of crystals which undergo structural phase transitions upon change of any external circumstances, especially of temperature. These structural transitions are understood in terms of the instability of the lattice against some particular atomic displacement field, or phonon mode. Since it is obvious that a harmonic phonon system can not become unstable by change of temperature, some sort of interaction of harmonic phonons with some physical variables would be needed to trigger the phase transition.
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Yamada, Y. (1977). Electron Phonon Interactions and Charge Ordering in Insulators. In: Riste, T. (eds) Electron-Phonon Interactions and Phase Transitions. NATO Advanced Study Institutes Series, vol 29. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8921-1_26
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DOI: https://doi.org/10.1007/978-1-4615-8921-1_26
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