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Magnetic Excitations in Mixed Valent Materials

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Abstract

The spin dynamics of a number of mixed valent materials have now been extensively studied using varied experimental probes including EPR, Raman scattering, infrared spectroscopy and inelastic neutron scattering. In this paper we review briefly photon and neutron spectroscopic studies of the 7F07F1 excitation dynamics in semiconducting SmS, SmSe and SmTe. New results for the phonon dispersion relations in SmS are presented. We also discuss recent neutron scattering experiments by Axe, Lawrence, Parks and ourselves on the γ-α transition in Ce.74Th.26. It is found that the spin fluctuation energy evolves from ~20 to >70 meV in going from the γ to the α phase.

Work at Brookhaven performed under the auspices of the U.S. Energy Research and Development Agency

Work at M.I.T. supported by the National Science Foundation

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© 1977 Plenum Press, New York

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Birgeneau, R.J., Shapiro, S.M. (1977). Magnetic Excitations in Mixed Valent Materials. In: Parks, R.D. (eds) Valence Instabilities and Related Narrow-Band Phenomena. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8816-0_5

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  • DOI: https://doi.org/10.1007/978-1-4615-8816-0_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-8818-4

  • Online ISBN: 978-1-4615-8816-0

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