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Crystal Fields and Dynamic Jahn Teller Coupling of an Electronic Quartet to Γ5 Lattice Modes in the Fine Structure of Er3+ in Pd-Er

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Abstract

The angular variation of the field for resonance H, for Er3+ in Pd-Er, has been investigated theoretically without introducing static lattice distortions from cubic symmetry and couplings to excited electronic states. In the limit of strong anharmonicity, using a dynamic lattice model, it is possible to reproduce the splittings of one of the E.P.R. lines in the regime of both strong and weak inversion splitting.

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References

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© 1977 Plenum Press, New York

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Dixon, J.M. (1977). Crystal Fields and Dynamic Jahn Teller Coupling of an Electronic Quartet to Γ5 Lattice Modes in the Fine Structure of Er3+ in Pd-Er. In: Furrer, A. (eds) Crystal Field Effects in Metals and Alloys. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8801-6_15

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  • DOI: https://doi.org/10.1007/978-1-4615-8801-6_15

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-8803-0

  • Online ISBN: 978-1-4615-8801-6

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