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Ammonium Ion Reorientation in NH4 + β-Alumina

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Superionic Conductors

Part of the book series: Physics of Solids and Liquids ((PSLI))

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Abstract

Neutron inelastic scattering techniques have been used to study the motion of NH4 + ions in NH4 + β-Alumina. The results strongly suggest jump rotational reorientation of the NH4 + ion between equivalent configurations. The translational diffusion coefficient of the NH4 + ion appears to be less than 2.5 × 10−6 cm2/sec at 473 K.

Research at Brookhaven National Laboratory performed under the auspices of the U.S. Energy Research and Dev. Admin.

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© 1976 Plenum Press, New York

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Axe, J.D., Corliss, L.M., Hastings, J.M., Muller, O., Roth, W.L. (1976). Ammonium Ion Reorientation in NH4 + β-Alumina. In: Mahan, G.D., Roth, W.L. (eds) Superionic Conductors. Physics of Solids and Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8789-7_53

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  • DOI: https://doi.org/10.1007/978-1-4615-8789-7_53

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-8791-0

  • Online ISBN: 978-1-4615-8789-7

  • eBook Packages: Springer Book Archive

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