Abstract
The solid state properties of perovskite-type compounds of transition metals which are of importance in NO catalytic chemistry are: (1) the presence of mixed valence ions (e.g., Mn3+/Mn4+), (2) the binding of oxygen in the lattice, and (3) the binding of N-containing fragments to the surface. On the surface, both molecular and dissociative chemisorption of NO contribute to the reduction of NO. The importance of the mixed valence and of the binding of lattice oxygen is linked to the simultaneous presence of cation vacancies and oxygen vacancies. Systematic substitution of cations in the dodecahedral and octahedral positions of the perovskite structure is used to demonstrate the importance of the solid-state chemistry for the catalytic activity and selectivity.
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Voorhoeve, R.J.H., Remeika, J.P., Trimble, L.E. (1975). Nitric Oxide and Perovskite-Type Catalysts: Solid State and Catalytic Chemistry. In: Klimisch, R.L., Larson, J.G. (eds) The Catalytic Chemistry of Nitrogen Oxides. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8741-5_12
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DOI: https://doi.org/10.1007/978-1-4615-8741-5_12
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