Abstract
One of the most important problems of present-day chemistry is the creation of new substances and materials possessing a series of valuable properties. Particularly great prospects have been opened up in the synthesis and study of organic compounds possessing delocalized electrons because of the presence in them of conjugated bonds or the formation of charge-transfer complexes. Such compounds have acquired the name of organic semiconductors. Starting in 1960, the volume of investigations on the chemistry and physics of these materials has risen to such an extent that the possibility has appeared of generalizing some basic achievements in this field [1, 2]. At the present time organic semiconductors include both low-molecular-weight compounds and polymers with a large number of conjugated bonds, charge-transfer complexes in which, owing to a definite structure, conditions are created for the delocalization of an electron, stable free radicals, and also some biopolymers (including proteins) the conductivity of which can be explained by a nonionic mechanism.
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Boguslavskii, L.I., Vannikov, A.V. (1970). Preparation, Constructive Properties, and Main Electrical Characteristics of Organic Semiconductors. In: Organic Semiconductors and Biopolymers. Monographs in Semiconductor Physics, vol 6. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8630-2_1
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