Abstract
There have been many e.s.r. studies of the ClO3 radical. A survey of the literature (1) shows that the exact value of g-tensor and the chlorine hyperfine tensors vary slightly depending on the host and the physical, conditions but the electronic structure of the radical is well understood: the 25-electron tetra-atomic species is tetrahedral and the unpaired electron occupies an orbital of A1 symmetry.
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References
Landolt-Bornstein: “Numerical Data and Functional Relationships in Science and Technology”, (K.H. Hellwege editor-in-chief), Group II, Vol.9, Part a, Springer Verlag, Berlin, 1977.
D.L. Sastry and K.V.S.R. Rao, Phys.Stat.Solidi B112, 133 (1982).
N.M. Atherton and C.A. Humphreys, J.Chem.Soc. Faraday II 80, 499 (1984).
N.V. Mani and S. Ramaseshan, Z. Krystallogr. 114, 200 (1960).
see, e.g. N.M. Atherton and A.J. Horsewill, Mol.Phys. 37, 1349 (1979).
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© 1986 Birkhäuser Boston, Inc.
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Atherton, N.M., Blackford, R.D.S. (1986). Proton Endor of γ-Irradiated Barium Perchlorate Trihydrate Crystals. In: Niccolai, N., Valensin, G. (eds) Advanced Magnetic Resonance Techniques in Systems of High Molecular Complexity. Progress in Inorganic Biochemistry and Biophysics, vol 2. Birkhäuser Boston. https://doi.org/10.1007/978-1-4615-8521-3_38
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DOI: https://doi.org/10.1007/978-1-4615-8521-3_38
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